Two-photon-absorption enhanced terahertz generation from KTP optically pumped in the visible-to-UV range.

By generating terahertz pulses in KTP crystals through optical rectification with a pump photon energy varying from below to above the bandgap, we observe a peak of the THz signal at the bandgap energy but also a second one around half the bandgap. This later one is attributed to a two-photon absorption enhanced nonlinearity, which is validated by the similarity of the two-photon absorption coefficient and THz peak amplitude data versus the pump photon energy. A careful analysis of the KTP sample absorption spectral dependence nearby the bandgap demonstrates that KTP is an indirect bandgap crystal, whose absorption below the bandgap involves emission of a phonon related to the symmetric Ti-O stretching vibration, i.e. the ν1 (A1g) mode.

Terahertz generation from ZnTe optically pumped above and below the bandgap.

We report on the generation of THz waves through optical rectification in ZnTe of femtosecond laser pulses whose photon energy is tuned from below to above the ZnTe bandgap energy. The THz signal exhibits a pronounced peak at the bandgap energy, at THz frequencies for which losses in ZnTe remain small. This peak is likely due to the resonance of the ZnTe nonlinear susceptibility in the vicinity of the bandgap.