[Influence of the Classification of Municipal Solid Wastes on the Reduction of Greenhouse Gas Emissions: A Case Study of Qingdao City, China].

The municipal solid waste (MSW) sector is an important source of greenhouse gas (GHG) emissions. MSW classification can achieve waste reduction and improve resource utilization. However, few studies have investigated the effects of MSW classification on GHG emission reduction. Therefore, the GHG emissions under different MSW disposal modes before and after classification were studied based on the life cycle assessment method in the four districts of Qingdao City. The results showed that MSW classification could significantly reduce the GHG emissions during the whole MSW treatment process. The net carbon emissions(in CO2/MSW)during the whole process of waste treatment for mode 1 (mixed collection+landfill), mode 2 (mixed collection+incineration), mode 3 (waste classification+anaerobic digestion of food waste and other incineration), and mode 4 (waste classification+anaerobic digestion of food waste, recycling of recyclable waste, and other incineration) were 686.39, -130.12, -61.88, and -230.17 kg·t-1, respectively. Improving the classification efficiency of food waste had no significant impact on carbon emissions. The reduction in carbon emissions increased linearly with the improvement of waste recycling efficiency. For every 10% increase in the recovery efficiency of recyclable waste, the net carbon emission decreased by 26.6%(16.5 kg·t-1). Appropriate separation of food waste, improving the recycling efficiency of recyclable waste, and reducing the leakage rate of biogas from anaerobic digestion are feasible strategies to reduce carbon emissions from MSW disposal units through the classification of MSW.

Impact of incineration slag co-disposed with municipal solid waste on methane production and methanogens ecology in landfills.

Co-landfill of incineration slag and municipal solid waste (MSW) is a main method for disposal of slag, and it has the potential of promoting methane (CH4) production and accelerating landfill stabilization. Four simulated MSW landfill columns loaded with different amount of slag (A, 0%; B, 5%; C, 10%; D, 20%) were established, and the CH4 production characteristics and methanogenic mechanisms were investigated. The maximum CH4 concentration in columns A, B, C and D was 10.8%, 23.3%, 36.3% and 34.3%, respectively. Leachate pH and refuse pH were positively correlated with CH4 concentration. Methanosarcina was the dominant genus with abundance of 35.1%∼75.2% and it was positively correlated with CH4 concentration. CO2-reducing and acetoclastic methanogenesis were the main types of methanogenesis pathway, and the methanogenesis functional abundance increased with slag proportion during stable methanogenesis process. This research can help understanding the impact of slag on CH4 production characteristics and microbiological mechanisms in landfills.

Effective removal of refractory organic contaminants from reverse osmosis concentrated leachate using PFS-nZVI/PMS/O3 process.

Reverse osmosis concentrated leachate (ROCL) from landfill leachate treatment contains high amounts of refractory organics. In this study, a combination of polymerized ferric sulfate (PFS) and nanoscale zero-valent iron/peroxymonosulfate/ozone (nZVI/PMS/O3) approach was adopted to remove refractory pollutants in ROCL. The effects of coagulant species, dosage and initial pH on the pre-treatment of organics from ROCL during coagulation process were investigated. Moreover, the influences of experimental factors, including initial pH, ozone doses, PMS, and nZVI on the removal of refractory organics in ROCL from coagulation effluent were systematically studied. The characteristics of organics were determined by using microscopic, spectroscopic and electron paramagnetic resonance (EPR) analyses. The batch experimental results indicated that the refractory organic contaminants in ROCL were effectively removed through PFS-nZVI/PMS/O3 treatment. The maximum removal efficiencies of COD and TOC were 89.1% and 83.2% under the optimum conditions: PFS of 8 g/L, ozone dose of 100 mg/min, PMS dose of 1.5 mM and nZVI dose of 10 mM, and at these conditions, the biodegradability index (BOD5/COD) was enhanced from 0.02 to 0.32. The excitation-emission matrix fluorescence spectroscopy (EEM) analysis indicated that humic-like and fulvic-like substances in ROCL were effectively removed. According to EPR analysis, hydroxyl and sulfate radicals were the dominant reactive species for the degradation of organics in nZVI/PMS/O3 system. Overall, the environmental and economic analysis suggested that the PFS-nZVI/PMS/O3 system was a cost-effective method for cleaning refractory organics from ROCL.

Insights into the stabilization of landfill by assessing the diversity and dynamic succession of bacterial community and its associated bio-metabolic process.

The distribution of bacterial community in an actual landfill was analyzed and the bioprocess involved in refuse degradation was clarified. The results showed that the degradation degree of refuse showed great differences with the landfill age, in which the contents of organic matter (OM) and total Kjeldahl nitrogen (TKN) in refuse as well as the chemical oxygen demand (COD) in leachate presented decreasing trends with increasing landfill age. The diversity of bacterial community increased first and then decreased with increasing landfill age. The main bacterial phyla involved in refuse degradation were Proteobacteria, Firmicutes and Bacteroidetes, among which, Proteobacteria had an absolute advantage with a relative abundance ranging of 66-78%. With increasing landfill age, the abundance of Firmicutes decreased gradually, while that of Bacteroidetes increased. Pseudomonas, Thiopseudomonas, Psychrobacter and Desemzia were the main genera. The distribution of bacterial community in samples with landfill ages of 0-1 and 1-3 years were greatly influenced by TKN and pH, respectively. Amino acid and carbohydrate metabolism were the main biological pathways according to the Kyoto Encyclopedia of Genes and Genomes (KEGG) database, and the biodegradation of xenobiotics as well as terpenoids and polyketides also accounted relatively high frequencies in the landfill. These results provide a better understanding of landfill microbiology and bioprocesses for landfill stabilization.

Evaluating the physicochemical properties of refuse with a short-term landfill age and odorous pollutants emission during landfill mining: A case study.

A field excavation of refusewitha short-termlandfillage from the Qingdao Xiaojianxi municipal solid waste (MSW) landfill was conducted. The physical composition and chemical properties of refuse with landfill ages of 1-4 years were studied, and the emission characteristics of odorous pollutants during the excavation period were monitored. The refuse aged 1-2 years has a higher proportion of combustible material than that the refuse aged 3-4 years, and the volatile content and calorific value in refuse aged 1-2 years were also higher than those in refuse aged 3-4 years, indicating that the refuse with a short-term landfill age was more suitable for incineration than refuse with a long-term landfill age. The pH and availablephosphorus (AP) gradually increased with increasing landfill age, while the total Kjeldahlnitrogen (TKN) and organic matter (OM) decreased. The contents of the heavy metals Cu, Zn, Ni, Pb and As generally decreased with landfill age, especially in refuse aged 2-4 years, whereas the Cr content showed no significant differences in refuse aged 1-4 years. The main odorous pollutants emitted during the excavation and screening periods were ammonia (NH3) and carbon disulfide (CS2), and the odor intensity of excavated refuse aged 1-3 years was higher than that of refuse aged 4 years. Under the condition of a small excavation area and continuous deodorization, the pollution intensity can meet the discharge standards of the factory boundary.

Comparative leaching of six toxic metals from raw and chemically stabilized MSWI fly ash using citric acid.

The leaching behavior of six typical toxic metals (Pb, Zn, Cr, Cd, Cu and Ni) from raw and chemically stabilized (phosphate and chelating agent) municipal solid waste incineration (MSWI) fly ash were investigated using citric acid. Leaching tests indicated that phosphate stabilization can effectively decrease the leaching of Zn, Cd and Cr; whereas chelating agent stabilization shows a strong ability to lower the release of Pb, Cd and Cu, but instead increases the solubility of Zn and Cr at low pH conditions. Sequential extraction results suggested that the leaching of Pb, Zn and Cd in both the stabilized MSWI fly ash samples led to the decrease in Fe/Mn oxide fraction and the increase in exchangeable and carbonate fractions. The leaching of Cr was due to the decrease in exchangeable, carbonate and Fe/Mn oxide fractions in phosphate-stabilized and chelating agent-stabilized MSWI fly ash. The leaching of Cu in both stabilized MSWI fly ash was greatly ascribed to the decrease in Fe/Mn oxide and oxidisable fractions. Moreover, predicted curves by geochemical model indicated that both stabilized MSWI fly ash have the risk of releasing toxic metals under strong acid environment.