Regulating Chemisorption and Electrosorption Activity for Efficient Uptake of Rare Earth Elements in Low Concentration on Oxygen-Doped Molybdenum Disulfide.

Recovery of rare earth elements (REEs) with trace amount in environmental applications and nuclear energy is becoming an increasingly urgent issue due to their genotoxicity and important role in society. Here, highly efficient recovery of low-concentration REEs from aqueous solutions by an enhanced chemisorption and electrosorption process of oxygen-doped molybdenum disulfide (O-doped MoS2) electrodes is performed. All REEs could be extremely recovered through a chemisorption and electrosorption coupling (CEC) method, and sorption behaviors were related with their outer-shell electrons. Light, medium, and heavy ((La(III), Gd(III), and Y(III)) rare earth elements were chosen for further investigating the adsorption and recovery performances under low-concentration conditions. Recovery of REEs could approach 100% under a low initial concentration condition where different recovery behaviors occurred with variable chemisorption interactions between REEs and O-doped MoS2. Experimental and theoretical results proved that doping O in MoS2 not only reduced the transfer resistance and improved the electrical double layer thickness of ion storage but also enhanced the chemical interaction of REEs and MoS2. Various outer-shell electrons of REEs performed different surficial chemisorption interactions with exposed sulfur and oxygen atoms of O-doped MoS2. Effects of variants including environmental conditions and operating parameters, such as applied voltage, initial concentration, pH condition, and electrode distance on adsorption capacity and recovery of REEs were examined to optimize the recovery process in order to achieve an ideal selective recovery of REEs. The total desorption of REEs from the O-doped MoS2 electrode was realized within 120 min while the electrode demonstrated a good cycling performance. This work presented a prospective way in establishing a CEC process with a two-dimensional metal sulfide electrode through structure engineering for efficient recovery of REEs within a low concentration range.

Microwave-assisted hydrothermal synthesis of MoS2-Ag3PO4 nanocomposites as visible light photocatalyst for the degradation of tetracycline hydrochloride.

In the modern era, industrialization has facilitated the human life but produced several severe pollutants as well that are hazardous in nature. Thus the degradation of these hazardous material has drawn considerable attention. This study deals with the synthesis of MoS2/Ag3PO4 heterojunction nanocomposite with 1-50% wt. using a microwave-assisted hydrothermal process as well as photocatalytic activity of tetracycline hydrochloride (TCH) degradation has been analysed. The compositional properties of nanocomposite catalysts have been studied through X-ray diffraction, Fourier transform infrared, X-ray photoelectron spectroscopy as well as structural and morphological studies were conducted through scanning electron microscopy, transmission electron microscopy, Brunauer-Emmet-Teller, photoluminescence, N2 physical adsorption, UV-vis diffuse reflectance spectroscopy. This provides an excellent and efficient mechanism for the remediation of residual organic contaminants under visible light that could be used to decontaminate the atmosphere.

Multi-edged molybdenite achieved by thermal modification for enhancing Pb(II) adsorption in aqueous solutions.

Thermal modification was simply performed on molybdenite to enhance the adsorption of Pb(II) in aqueous solutions, and the root of this phenomenon was well studied in this work. Various thermal modification temperatures at 300 °C, 400 °C and 500 °C were applied to modify the surface property of molybdenite, producing different degrees of edge defect and surface wettability in molybdenite samples. Contact angle tests, atomic force microscopy (AFM) observations and adsorption tests illustrated that molybdenite thermally modified at 400 °C contained most edge defects and achieved a 147.846 mg/g Pb(II) adsorption, which was almost 10 times of that obtained by natural molybdenite. The adsorption experiment also indicated that the increase of surface hydrophilia of molybdenite would slightly benefit the Pb(II) adsorption. The X-ray photoelectron spectroscope (XPS) exhibited that a strong chemical adsorption existed between Pb(II) and S elements. AFM study further demonstrated that the interaction between Pb(II) and S atoms exposed at the triangular edges of molybdenite were the intrinsic reason for the great enhancement of Pb(II) adsorption. This work provides a new insight to absorb Pb(II) in aqueous solutions using natural molybdenite.

Controllable incorporation of oxygen in MoS2 for efficient adsorption of Hg2+ in aqueous solutions.

Molybdenum disulfide (MoS2) was incorporated controllably by oxygen in order to modify the hydrophobic surfaces and thus to improve the adsorption of Hg2+ on MoS2 in aqueous solutions in this work. The experimental results indicated that the incorporation of oxygen could dramatically improve the adsorption of Hg2+ on MoS2. With 11% oxygen atom incorporation, the adsorption rate and capacity increased over 17 times and 21 folds, respectively, compared with that without oxygen incorporation. This vast improvement was found to be contributed to that the incorporation of oxygen would greatly enhance the complexation between S atoms and Hg2+ on MoS2 surfaces, resulting in the great increase of the Hg2+ adsorption. The increase of the adsorption capacity with increasing incorporated oxygen reached a plateau, which might be due to the saturation of covalent bond. In addition, the incorporation of oxygen atom greatly enhanced the hydrophilicity of MoS2 surfaces, facilitating the hydrated Hg2+ ions to approach to MoS2 surfaces. This finding might provide a highly potential adsorbent for efficiently removing Hg2+ from water.