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1.
Nanotechnology ; 34(20)2023 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-36780666

RESUMO

Low quantum efficiency and serious photogenerated carrier recombination have been urgent bottleneck problems for photocatalytic materials. Herein, we prepared Nb, Se-codoped ZnIn2S4/NbSe2composites through a facile solvothermal method. The synergetic effect of codoping and cocatalyst was investigated on the photodegradation performance towards tetracycline under visible-light irradiation. By adjusting the final composition, the comprehensive characterization revealed that the optimum degradation efficiency of NS/ZIS-1.6 catalyst arrived at 75% in 70 min, which was 5.8 times higher than that of pure ZnIn2S4. Deep analysis indicated that the enhanced photocatalytic performance could be attributed to higher light absorption, more efficient electron/hole separation, faster charge transport, and lower carrier recombination. This work may offer novel viewpoint for design of high-performance catalysts towards the visible-light-driven photodegradation system.

2.
Bioengineered ; 13(1): 876-883, 2022 01.
Artigo em Inglês | MEDLINE | ID: mdl-34968171

RESUMO

This research has developed a method for rapid detection of SARS-CoV-2 N protein on a paper-based microfluidic chip. The chitosan-glutaraldehyde cross-linking method is used to fix the coated antibody, and the sandwich enzyme-linked immunosorbent method is used to achieve the specific detection of the target antigen. The system studied the influence of coating antibody concentration and enzyme-labeled antibody concentration on target antigen detection. According to the average gray value measured under different N protein concentrations, the standard curve of the method was established and the sensitivity was tested, and its linear regression was obtained. The equation is y = 9.8286x+137.6, R2 = 0.9772 > 0.90, which shows a high degree of fit. When the concentration of coating antibody and enzyme-labeled antibody were 1 µg/mL and 2 µg/mL, P > 0.05, the difference was not statistically significant, so the lower concentration of 1 µg/mL was chosen as the coating antibody concentration. The results show that the minimum concentration of N protein that can be detected by this method is 8 µg/mL, and the minimum concentration of coating antibody and enzyme-labeled antibody is 1 µg/mL, which has the characteristics of high sensitivity and good repeatability.


Assuntos
Antígenos Virais/análise , Teste Sorológico para COVID-19/instrumentação , Proteínas do Nucleocapsídeo de Coronavírus/análise , Proteínas do Nucleocapsídeo de Coronavírus/imunologia , Dispositivos Lab-On-A-Chip , SARS-CoV-2/química , SARS-CoV-2/imunologia , Anticorpos Antivirais/imunologia , Engenharia Biomédica , COVID-19/diagnóstico , COVID-19/imunologia , COVID-19/virologia , Teste Sorológico para COVID-19/métodos , Teste Sorológico para COVID-19/normas , Proteínas do Nucleocapsídeo de Coronavírus/normas , Ensaio de Imunoadsorção Enzimática/instrumentação , Ensaio de Imunoadsorção Enzimática/métodos , Ensaio de Imunoadsorção Enzimática/normas , Humanos , Dispositivos Lab-On-A-Chip/normas , Dispositivos Lab-On-A-Chip/estatística & dados numéricos , Procedimentos Analíticos em Microchip/métodos , Procedimentos Analíticos em Microchip/normas , Procedimentos Analíticos em Microchip/estatística & dados numéricos , Papel , Fosfoproteínas/análise , Fosfoproteínas/imunologia , Fosfoproteínas/normas
3.
Chem Rec ; 20(11): 1236-1256, 2020 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-32767665

RESUMO

With increasing interest in developing biodegradable polymers to replace fossil-based products globally, lactic acid (LA) has been paid extensive attention due to the high environment-compatibility of its downstream products. The mainstream efforts have been put in developing energy-efficient conversion technologies through biological and chemical routes to synthesize LA. However, to our best knowledge, there is a lack of sufficient attention in developing effective separation technologies with high atom economics for purifying LA and derivatives. In this review, the most recent advances in purifying LA using precipitation, reactive extraction, emulsion liquid membrane, reactive distillation, molecular distillation, and membrane techniques will be discussed critically with respect to the fundamentals, flow scheme, energy efficiency, and equipment. The outcome of this article is to offer insights into implementing more atomic and energy-efficient technologies for upgrading LA.


Assuntos
Ácido Láctico/isolamento & purificação , Diálise , Destilação , Filtração
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