From colloidal particles to photonic crystals: advances in self-assembly and their emerging applications.

Over the last three decades, photonic crystals (PhCs) have attracted intense interests thanks to their broad potential applications in optics and photonics. Generally, these structures can be fabricated via either "top-down" lithographic or "bottom-up" self-assembly approaches. The self-assembly approaches have attracted particular attention due to their low cost, simple fabrication processes, relative convenience of scaling up, and the ease of creating complex structures with nanometer precision. The self-assembled colloidal crystals (CCs), which are good candidates for PhCs, have offered unprecedented opportunities for photonics, optics, optoelectronics, sensing, energy harvesting, environmental remediation, pigments, and many other applications. The creation of high-quality CCs and their mass fabrication over large areas are the critical limiting factors for real-world applications. This paper reviews the state-of-the-art techniques in the self-assembly of colloidal particles for the fabrication of large-area high-quality CCs and CCs with unique symmetries. The first part of this review summarizes the types of defects commonly encountered in the fabrication process and their effects on the optical properties of the resultant CCs. Next, the mechanisms of the formation of cracks/defects are discussed, and a range of versatile fabrication methods to create large-area crack/defect-free two-dimensional and three-dimensional CCs are described. Meanwhile, we also shed light on both the advantages and limitations of these advanced approaches developed to fabricate high-quality CCs. The self-assembly routes and achievements in the fabrication of CCs with the ability to open a complete photonic bandgap, such as cubic diamond and pyrochlore structure CCs, are discussed as well. Then emerging applications of large-area high-quality CCs and unique photonic structures enabled by the advanced self-assembly methods are illustrated. At the end of this review, we outlook the future approaches in the fabrication of perfect CCs and highlight their novel real-world applications.

Tunable index metamaterials made by bottom-up approaches.

Despite the exciting optical properties metamaterials exhibit, their implementation in technology is being hampered nowadays by the inherent losses of their metal constituents and the expensive and low-throughput procedures used. As an alternative, we present a new design of double fishnet metamaterials that can be easily realized combining two inexpensive and up-scalable techniques: nanosphere lithography and metallic electrodeposition. A monolayer of polystyrene spheres is used as a template for the infiltration of two symmetric gold layers separated by an air gap. The effective refractive index of the metamaterial can be easily tuned by the appropriate choice of the diameter of the spheres and the gap width between the metallic layers, varying its value from positive to negative. The good agreement between optical measurements and finite-difference time-domain simulations confirms the success of our process. Fishnet metamaterials with refractive index going from 1.5 until -1.0 in the near infrared range are demonstrated and the key parameters for these architectures provided.