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1.
BMJ Open Diabetes Res Care ; 12(1)2024 Jan 12.
Artigo em Inglês | MEDLINE | ID: mdl-38216296

RESUMO

INTRODUCTION: Diabetic foot ulcer (DFU) is a disabling complication of diabetes mellitus. Here, we attempted to assess whether long-term intrafemoral artery infusion of low-dose urokinase therapy improved DFUs and decreased cardiovascular events in patients with DFUs. RESEARCH DESIGN AND METHODS: This trial was a single-center, randomized, parallel study. A total of 195 patients with DFU were randomized to continuous intrafemoral thrombolysis or conventional therapy groups. The continuous intrafemoral thrombolysis group received continuous intrafemoral urokinase injection for 7 days, and conventional therapy just received wound debridement and dressing change. Then, a follow-up of average 6.5 years was performed. RESULTS: Compared with conventional therapy, at the first 1 month of intervention stage, the ulcers achieved a significant improvement in continuous intrafemoral thrombolysis group including a complete closure (72.4% vs 17.5%), an improved ulcer (27.6% vs 25.8%), unchanged or impaired ulcer (0% vs 56.7%). During the 6.5-year follow-up, for the primary outcome of ulcer closure rate, continuous intrafemoral thrombolysis therapy obtained a better complete healing rate (HR 3.42 (95% CI 2.35 to 4.98, p<0.0001)). For the secondary outcome of cardiovascular disease events, continuous intrafemoral thrombolysis therapy had a lower incidence of cardiovascular events (HR 0.50 (95% CI 0.34 to 0.74, p<0.0001)). Importantly, intrafemoral thrombolysis therapy decreased the incidence of cardiovascular death (HR 0.42 (95%CI 0.20 to 0.89, p=0.0241)). Additionally, continuous intrafemoral thrombolysis therapy improved local skin oxygenation and peripheral neuropathy as well as glycolipid metabolic profiles when compared with conventional therapy group (p<0.05). CONCLUSIONS: Continuous intrafemoral thrombolysis therapy has a better therapeutic efficacy to improve DFUs and decrease cardiovascular events. TRIAL REGISTRATION NUMBER: NCT01108120.


Assuntos
Diabetes Mellitus , Pé Diabético , Humanos , Pé Diabético/tratamento farmacológico , Seguimentos , Ativador de Plasminogênio Tipo Uroquinase/uso terapêutico , Cicatrização , Artérias
2.
Risk Manag Healthc Policy ; 16: 337-346, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-36883054

RESUMO

Background: The Fangcang shelter hospital has gradually become the primary management mode in China's fight against this Corona Virus Disease 2019 (COVID-19) in 2020. In early 2022, the Fangcang shelter hospital management model was successfully applied to the new outbreak of COVID-19 in Shanghai also. Although Fangcang shelter hospitals are no longer the prevailing mode of prevention of COVID-19, the management experience of Shanghai makeshift hospitals is worthy of reference for public health. Methods: The authors conducted a descriptive statistical analysis of Hall 6-2 of the Shanghai National Convention and Exhibition Center Fangcang shelter hospital. The whole hall of the Fangcang shelter hospital was managed by the one hospital, and the inclusion of third-party management personnel alleviated the shortage of medical personnel human resources. Through practice, a new procedure for treating batch infected people was introduced. Results: By optimizing ward management, 72 on-duty doctors, 360 on-duty nurses, 3 sense-control administrators, and 15 administrators cured 18,574 infected people in 40 days, and created a record of a doctor managing 700 infected people without compromising the quality of treatment. There have been no deaths and no complaints from the infected people located in Hall 6-2 of the Shanghai National Convention and Exhibition Center Fangcang shelter hospital. Conclusion: Compared with previous data, the new management mode of Fangcang shelter hospitals provides a reference for the management of the new infectious diseases for public health.

3.
Nanomaterials (Basel) ; 13(2)2023 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-36678104

RESUMO

Phosphors with a longer excitation wavelength exhibit higher energy conversion efficiency. Herein, quantum cutting KGd(CO3)2:Tb3+ phosphors excited by middle-wave ultraviolet were synthesized via a hydrothermal method. All the KGd(CO3)2:xTb3+ phosphors remain in monoclinic structures in a large Tb3+ doping range. In the KGd(CO3)2 host, 6D3/2 and 6I17/2 of Gd3+ were employed for quantum cutting in sensitizing levels. The excited state electrons could easily transfer from Gd3+ to Tb3+ with high efficiency. There are three efficient excited bands for quantum cutting. The excited wavelengths of 244, 273, and 283 nm correspond to the transition processes of 8S7/2→6D3/2 (Gd3+), 8S7/2→6I17/2 (Gd3+), and 7F6→5F4 (Tb3+), and the maximum quantum yields of KGd(CO3)2:Tb3+ can reach 163.5, 119, and 143%, respectively. The continuous and efficient excitation band of 273-283 nm can well match the commercial 275 nm LED chip to expand the usage of solid-state light sources. Meanwhile, the phosphor also shows good excitation efficiency at 365 nm in a high Tb3+ doping concentration. Therefore, KGd(CO3)2:Tb3+ is an efficient green-emitting phosphor for ultraviolet-excited solid-state light sources.

4.
Materials (Basel) ; 15(17)2022 Sep 05.
Artigo em Inglês | MEDLINE | ID: mdl-36079538

RESUMO

Highly efficient quantum cutting KY(CO3)2:Tb3+ phosphors excited by ultraviolet B (UVB) and ultraviolet C (UVC) were investigated. The structural and spectroscopic properties were characterized by XRD analysis and fluorescence spectrophotometry, respectively. The results showed that the monoclinic crystal structure of KY(CO3)2:Tb3+ remained in the Tb3+ doping range of 0~100%. In the excitation spectrum, two intense excitation peaks were observed in the ultraviolet range. Under the excitation of 283 nm, the maximum quantum efficiency of KY(CO3)2:0.7Tb3+ could reach 119%. However, the most efficient quantum cutting occurred at the 5K8 excited state in the cross-relaxation of 5K8 + 7F65D4 + 5D4. The Tb3+ content could be selected arbitrarily in the KY(CO3)2 host without any concentration quenching. Optimal quantum cutting concentrations of Tb3+ in KY(CO3)2 were 0.7 and 0.3 for the excitation of UVB and UVC, respectively. UVB-excited phosphors are more popular with high transparency in products such as glass or resin. A quick response code was fabricated by resin to show the hidden information clearly. Therefore, the highly efficient phosphor could be a candidate material for the application in information identification technology.

5.
J Acoust Soc Am ; 151(6): 4140, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35778193

RESUMO

Underwater source localization by deep neural networks (DNNs) is challenging since training these DNNs generally requires a large amount of experimental data and is computationally expensive. In this paper, label distribution-guided transfer learning (LD-TL) for underwater source localization is proposed, where a one-dimensional convolutional neural network (1D-CNN) is pre-trained with the simulation data generated by an underwater acoustic propagation model and then fine-tuned with a very limited amount of experimental data. In particular, the experimental data for fine-tuning the pre-trained 1D-CNN are labeled with label distribution vectors instead of one-hot encoded vectors. Experimental results show that the performance of underwater source localization with a very limited amount of experimental data is significantly improved by the proposed LD-TL.

6.
Acta Biochim Pol ; 69(3): 619-623, 2022 Apr 28.
Artigo em Inglês | MEDLINE | ID: mdl-35485096

RESUMO

Diabetes mellitus is the syndrome associated with metabolism having complicated pathogenesis and its morbidity rate is rapidly increasing every year. The present study investigated the preventive effect of salicin ether against type-2 diabetes and explored the underlying mechanism. Salicin ether reduced PPARγ-LBD level and transcriptional property of RXRα-PPARγ in 293T cells. The rosiglitazone significantly (p<0.01) increased grease droplet accumulation in adipocytes in comparison to control adipocytes. Increased grease droplet accumulation by rosiglitazone in adipocytes was reversed on treatment with salicin ether in dose-dependent manner. Salicin ether treatment of the adipocytes effectively suppressed rosiglitazone induced expression of FAS, C/EBPα, aP2, and HMG-CoA genes. Treatment of the adipocytes with salicin ether led to a prominent decrease in rosiglitazone mediated increase in aP2, CHIP, and C/EBPα protein expression. The inhibitory effect of rosiglitazone on expression of p-Akt/t-Akt, PPARa, p-FoxO1/t-FoxO1, and p-AMPK/t-AMPK was significantly (p<0.01) alleviated in the adipocytes by salicin ether. In summary, the present study demonstrated that salicin ether suppressed PPARγ activity and adipocyte differentiation. Moreover, the activation of FoxO1/Akt/AMPK was up-regulated and FAS/EBPα/aP2/HMG-CoA level inhibited by salicin ether in the adipocytes. Thus, salicin ether may be studied further for possible role in the treatment of diabetes.


Assuntos
Diabetes Mellitus Tipo 2 , PPAR gama , Proteínas Quinases Ativadas por AMP , Álcoois Benzílicos , Proteína alfa Estimuladora de Ligação a CCAAT/genética , Proteína alfa Estimuladora de Ligação a CCAAT/metabolismo , Proteína alfa Estimuladora de Ligação a CCAAT/farmacologia , Diferenciação Celular , Diabetes Mellitus Tipo 2/tratamento farmacológico , Éter/farmacologia , Expressão Gênica , Glucosídeos , Humanos , PPAR gama/genética , PPAR gama/metabolismo , PPAR gama/farmacologia , Proteínas Proto-Oncogênicas c-akt/metabolismo , Rosiglitazona/farmacologia
7.
RSC Adv ; 11(27): 16608-16618, 2021 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-35479132

RESUMO

One-dimensional (1D) hierarchical WO3/BiOI p-n (WB) heterojunctions with different mass percentages of WO3 were fabricated through a precipitation process. Various analytical techniques were employed to characterize the resulting WB composites, and their photocatalytic properties were measured by the degradation of rhodamine B (RhB) and methylene blue (MB) under irradiation of visible light. The WB heterojunctions showed largely enhanced photocatalytic performance as compared to the pure photocatalysts. Notably, the degradation rate constant of RhB by WB-10 was 3.3 and 33.6 times higher than those of pure BiOI and WO3, respectively. The enhanced activity could be attributed to the hierarchical p-n heterostructures, which can supply more reaction sites and effectively promote the separation of photogenerated charge carriers, as confirmed by PL and photocurrent. Trapping experiments implied that holes (h+) and superoxide anion radicals (˙O2 -) were the dominant active species for organic pollutants decomposition on the WB composites. This work may benefit the construction of hierarchical heterostructures with high photocatalytic efficiency.

8.
Journal of Preventive Medicine ; (12): 1086-1090, 2021.
Artigo em Chinês | WPRIM (Pacífico Ocidental) | ID: wpr-905046

RESUMO

Objective@#To establish a fluorescence method based on turncated aptamer for the determination of bisphenol A in water.@*Methods@#The bisphenol A truncated aptamer containing 38 bases was selected as a recognition module, and was modified with the fluorophore 6-FAM at the 5'end. The 3'end of the complementary sequence cDNA was modified with the quencher DABCYL. The standard solutions of bisphenol A and interfering compounds were configured. The detection system was established after optimizing the number of bases in cDNA, the concentration ratio of truncated aptamer to cDNA, the incubation temperature and time, and the pH of the buffer. The specificity and recovery experiments were carried out. @*Results@#When the complementary sequence cDNA included 9 bases, the concentration ratio of the truncated aptamer to cDNA was 1:1.5, the pH value of the buffer solution was 7.5, the cDNA was incubated at 55 ℃ for 60 minutes, in the concentration range of 10-75 pmol/L, the linear regression equation was y=2 230.7x+110 825, the correlation coefficient was 0.926. The limits of detection was 3.3 pmol/L. The difference values of fluorescence intensity between tetrabromobisphenol A, estradiol, estriol, bisphenol S and bisphenol A were obviously different, so there was no significant interference to the test result. The recovery rates were 97.8%, 98.8% and 102.3% with the spiked concentrations of 20.0, 40.0 and 60.0 pmol/L. The relative standard deviations were 4.4%, 2.1% and 2.6% (n=5), respectively. @*Conclusion@#The fluorescence method based on turncated aptamer has the advantages of easy operation, high sensitivity and specificity, which can be used for the determination of bisphenol A in water.

9.
RSC Adv ; 10(18): 10921-10931, 2020 Mar 11.
Artigo em Inglês | MEDLINE | ID: mdl-35492917

RESUMO

In this study, a series of BiOI/KTaO3 p-n heterojunctions were prepared via a facile in situ chemical bath strategy. The photocatalytic properties of the catalysts was tested by the degradation of Rhodamine B (RhB) and phenol under visible light irradiation. The BiOI/KTaO3 composites exhibited improved photocatalytic efficiency compared to the individual catalysts. In particular, 54 wt% BiOI/KTaO3 displayed the highest photocatalytic activity since it degraded 98.6% RhB within 30 minutes, while only 68.1% RhB was degraded over pure BiOI under identical conditions. In addition, the reaction kinetic constant of RhB degradation over 54 wt% BiOI/KTaO3 was approximately 2.56 and 115-fold larger than those of pure BiOI and KTaO3, respectively. The results of PL, photocurrent and EIS indicated that the improved photocatalytic efficiency could root in the p-n junction formed between BiOI and KTaO3, which was conducive to the separation and migration of photo-generated carriers. Furthermore, a free-radical capture experiment illustrated that h+ and ˙O2 - were the key factors in the photodegradation of RhB.

10.
Dalton Trans ; 48(3): 1067-1074, 2019 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-30601532

RESUMO

Recently, cadmium selenide (CdSe) has been deeply studied because of its excellent photocatalytic hydrogen (H2) production performance. However, pure CdSe has poor stability and severe photocorrosion, which seriously affect its application prospect. In this work, we successfully deposit Bi2MoO6 on an inorganic-organic CdSe-diethylenetriamine (DETA) hybrid to design Bi2MoO6/CdSe-DETA composites by an in situ solvothermal method. The morphology, crystal structure, electrochemical properties, H2 evolution performance and the photostability of Bi2MoO6/CdSe-DETA composites are explored using various techniques. The results show that the as-prepared Bi2MoO6/CdSe-DETA composites exhibit excellent photocatalytic performance and photostability under visible light irradiation. Among them, the Bi2MoO6/CdSe-DETA hybrid system exhibits excellent photocatalytic H2 production performance (5.92 mmol g-1 h-1), which is approximately 3.6 and 1.8 times higher than that of pure CdSe and CdSe-DETA, respectively. After 4 cycles, the photocatalyst still maintains high H2 production. This study develops a new type of photocatalyst that can respond to visible light. This provides an effective way to solve the energy problem by using solar energy.

11.
J Acoust Soc Am ; 146(6): 4324, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31893745

RESUMO

The underwater surveillance of harbors is challenging, as the reverberation-limited environment means that intruders with a weak target strength, such as autonomous underwater vehicles and frogmen, may be overlapped or even overwhelmed by reverberations. In recent years, developments in low-rank and sparsity theory have presented an innovative idea for intruder detection. This paper describes a method in which multi-frame data containing echoes of an intruder and reverberations are arranged in a matrix, and then the data matrix is decomposed to achieve detection. Based on this idea, the alternating direction method of multipliers (ADMM) is applied to the problem of intruder detection. The key parameters of ADMM are discussed and recommended values are given. The proposed method is validated and evaluated through a series of experiments.

12.
Dalton Trans ; 47(42): 15009-15016, 2018 Oct 30.
Artigo em Inglês | MEDLINE | ID: mdl-30302455

RESUMO

Hierarchical micro/nanostructures manifest attractive prospects for photocatalytic application. Nevertheless, large-scale hierarchical micro/nanostructures for industrial application with facile, low-cost and eco-friendly routes remain difficult. Herein, nanowire-assembled hierarchical CuO microspheres (HCMAW) are synthesized for the first time by CO32- ions induced synthesis route. The time-dependent SEM images reveal that the growth mechanism for HCMAW is the well-known Ostwald ripening with self-assembly. The specific surface area of the HCMAW is 7.265 m2 g-1, which is higher than that of hierarchical CuO microspheres assembled with nanosheets (HCMAS) (4.952 m2 g-1) prepared by direct self-assembly scheme without the introduction of CO32- ions. Meanwhile, the HCMAW possess strong light absorption around a broadband wavelength from 300 nm to 800 nm. As a result, the photodegradation activity test demonstrates that the HCMAW shows the degradation efficiency of 98.8% for rhodamine B (RhB) under white light irradiation for 30 min in the presence of H2O2 higher than those of HCMAS (66.3%) and commercial CuO (48.3%) under the same condition, which is one of the highest reported till date related to CuO nanomaterials for the degradation of RhB. The novel HCMAW synthesized by the ion-induced protocol is worth being generalized to more assembled hierarchical micro/nanostructures for versatile applications.

13.
Sensors (Basel) ; 18(10)2018 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-30326571

RESUMO

It is challenging to detect a moving target in the reverberant environment for a long time. In recent years, a kind of method based on low-rank and sparse theory was developed to study this problem. The multiframe data containing the target echo and reverberation are arranged in a matrix, and then, the detection is achieved by low-rank and sparse decomposition of the data matrix. In this paper, we introduce a new method for the matrix decomposition using dynamic mode decomposition (DMD). DMD is usually used to calculate eigenmodes of an approximate linear model. We divided the eigenmodes into two categories to realize low-rank and sparse decomposition such that we detected the target from the sparse component. Compared with the previous methods based on low-rank and sparse theory, our method improves the computation speed by approximately 4⁻90-times at the expense of a slight loss of detection gain. The efficient method has a big advantage for real-time processing. This method can spare time for other stages of processing to improve the detection performance. We have validated the method with three sets of underwater acoustic data.

14.
J Colloid Interface Sci ; 512: 77-85, 2018 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-29054009

RESUMO

The design and control of effective, sustainable, cheap, and reusable photocatalysts are crucial to the development of solar energy conversion to hydrogen (H2) for solving environmental problems. The cadmium sulfide/diethylenetriamine (CdS/DETA) hybrid in a single crystalline structure was achieved by a solvothermal approach. The organic-inorganic CdS/DETA hybrid shows high performance and satisfactory stability for H2 production under visible-light irradiation. The synergetic chemical coupling effect between CdS and DETA leads to a marked increase in the H2 generation rate and the apparent quantum yield. H2-production rate of CdS/DETA24 under visible light illumination are 31.7% and 8059.5µmolg-1h-1, respectively, which is 3.5 times more than CdS nanorods without DETA. Our findings may give a promising method to improve CdS for efficient electron-hole separation, electron transferring and anticorrosion in photocatalytic process, which reforms the conventional organic-inorganic hybrid system.

15.
Dalton Trans ; 46(34): 11335-11343, 2017 Aug 29.
Artigo em Inglês | MEDLINE | ID: mdl-28809983

RESUMO

Sustainable photocatalytic hydrogen evolution (PHE) of water splitting has been utilized to solve the serious environmental pollution and energy shortage problems over the last decade. Inorganic-organic hybrid materials could combine the organic molecules and functional inorganic blocks into unique materials through complicated physical and chemical interactions. In this paper, diethylenetriamine (DETA) was used as an organic molecule template for the synthesis of inorganic-organic Zn1-xCdxS-DETA solid solution nanoflowers (NFs) at very low temperature. The obtained Zn0.2Cd0.8S-DETA NFs exhibited the highest H2 production rate (12 718 µmol g-1 h-1), which is 1.75 times as high as that of CdS-DETA. The suitable conduction band potential and excellent visible-light absorption of Zn0.2Cd0.8S-DETA solid solution NFs are closely related to the excellent PHE activity. Furthermore, the calculation on the electronic structure provides a new understanding of the band-gap shifts of the Zn1-xCdxS-DETA solid solution hybrids and the design of novel structural photocatalysts.

16.
Zhonghua Nan Ke Xue ; 22(3): 212-8, 2016 Mar.
Artigo em Chinês | MEDLINE | ID: mdl-27172659

RESUMO

UNLABELLED: OCTOBER: To explore the effects of the glucagon-like peptide 1 (GLP-1) liraglutide on the penile erectile function of rats with diabetic erectile dysfunction (DED) by observing the impact of liraglutide on the expression of eNOS in the corpus cavernosum of diabetic rats. METHODS: We randomly divided 30 six-week-old male SD rats into a normal control (n = 10) and an experimental group (n = 20) , established models of diabetes mellitus (DM) in the experimental rats, and subdivided them into a DM (n = 8) and a GLP-1 group (n = 8) to receive intramuscular injection of normal saline and liraglutide at 5 mg per kg of the body weight per day, respectively. After 12 weeks of intervention, we obtained the levels of FPG, FINS, TG, TC, HDL-C, LDL-C, testosterone, and IL-6 and the indexes of Homa-IR and Homa-ß, detected the expressions of Akt/p-Akt and eNOS/p-eNOS in the corpus cavernosum by Western blot, and compared the erectile function between different groups. RESULTS: The frequency and rate of penile erection were significantly lower in the DM group than in the GLP-1 and normal control groups (P < 0.05) and also lower in the GLP-1 group than in the normal controls (P < 0.05). Immunofluorescence staining showed the expression of eNOS mainly in the cytoplasm of the cavernosal vessels and sinusoidal endothelial cells, markedly lower in the DM and GLP-1 groups than in the normal rats (P < 0.05), but higher in the GLP-1 than in the DM group (P < 0.05). The level of eNOS/p-eNOS in the penile tissue was significantly decreased in the DM and GLP-1 groups in comparison with the normal controls (P < 0.01 or P < 0.05), while that of p-eNOS was markedly increased in the GLP-1 group as compared with the DM group (P < 0.05). No statistically significant differences were observed in the Akt level among the three groups of animals (P > 0.05). The expression of p-Akt was remarkably reduced in the DM and GLP-1 groups in comparison with the control rats (P < 0.01 or P < 0.05), but higher in the GLP-1 than in the DM group (P < 0.05). CONCLUSION: GLP-1 can protect the function of endothelial cells in the corpus cavernosum and improve the erectile function of DED rats by regulating the Akt/ eNOS signaling pathway, which indicates that GLP-1 could be an important option for the treatment and prevention of DED.


Assuntos
Hipoglicemiantes/farmacologia , Liraglutida/farmacologia , Óxido Nítrico Sintase Tipo III/metabolismo , Ereção Peniana/efeitos dos fármacos , Pênis/efeitos dos fármacos , Animais , Western Blotting , Diabetes Mellitus Experimental , Disfunção Erétil/tratamento farmacológico , Disfunção Erétil/enzimologia , Masculino , Pênis/enzimologia , Pênis/fisiopatologia , Distribuição Aleatória , Ratos , Ratos Sprague-Dawley , Testosterona/sangue
17.
Dalton Trans ; 44(17): 7903-10, 2015 May 07.
Artigo em Inglês | MEDLINE | ID: mdl-25823711

RESUMO

It is important to reduce the recombination of electrons and holes and enhance charge transfer through fine controlled interfaces for advanced catalyst design. In this work, graphene oxide (GO) was composited with graphitic-C3N4 (g-C3N4) and BiOI forming GO/g-C3N4 and GO/BiOI heterostructural interfaces, respectively. GO, which has a work function between the conducting bands of g-C3N4 and BiOI, is used as a buffer material to enhance electron transfer from g-C3N4 to BiOI through the GO/g-C3N4 and GO/BiOI interfaces. The increased photocurrent and reduced photoluminescence indicate efficient reduction of electron and hole recombination under the successful heterostructure design. Accordingly, the introduction of GO as a charge transfer buffer material has largely enhanced the photocatalytic performance of the composite. Thus, introducing charge transfer buffer materials for photocatalytic performance enhancement has proved to be a new strategy for advanced photocatalyst design.

18.
Dalton Trans ; 43(17): 6295-9, 2014 May 07.
Artigo em Inglês | MEDLINE | ID: mdl-24626428

RESUMO

Graphitic C3N4 (g-C3N4), as an advanced metal free photocatalyst, is known to be poorly exfoliated and dispersed in water from its powder form which has a layered structure, the intrinsic plane structure is not destroyed, and this has largely limited its application. In this work, we report our progress on successful sonication exfoliation of g-C3N4 nanosheets in graphene oxide (GO) aqueous solution. By making use of the substrate character of GO, g-C3N4 nanosheets of unvaried intrinsic structure were exfoliated and anchored on the GO surface, resulting in a GO/g-C3N4 hybrid. Moreover, the photocurrent of the hybrid was largely reinforced at the optimal weight fraction of GO. As a result, the corresponding photocatalytic performance of the hybrid with optimized photocurrent character was largely improved.

19.
Dalton Trans ; 43(5): 2202-10, 2014 Feb 07.
Artigo em Inglês | MEDLINE | ID: mdl-24292253

RESUMO

Surface-fluorinated TiO2 (F-TiO2) nanosheets with exposed (001) facets were synthesized from a scalable hydrothermal treatment assisted by a specific stabilization effect of fluorine ions on the (001) facets. Assembly of F-TiO2 on graphene oxide (GO) sheets into GO/F-TiO2 hybrid in aqueous solution was further achieved by making use of the surfactant role of GO. Photocatalytic properties of GO/F-TiO2 hybrid were evaluated under 365 nm UV light irradiation for photodegradation of methylene blue (MB). An optimal GO content has been determined to be 3 wt%, and the corresponding apparent pseudo-first-order rate constant Kapp is 0.0493 min(-1), 3 times and 4 times more than that of pure TiO2 nanosheets and commercial P25 photocatalyst, respectively. To reveal the synergism reinforce mechanism of GO/F-TiO2 hybrid, photo absorption, surface absorption, and the photoelectrochemical current properties have been intensively studied. We found that enhanced electron-hole separation has been the key issue for the reinforcement of photocatalytic performance. F-TiO2 with exposed (001) facet has stronger electron-hole separation resulting in a higher photoelectrochemical current than that of P25 photocatalyst. Moreover, hybridization of F-TiO2 with GO could further increase the photoelectrochemical current and the largest current for the optimal weight fraction of GO is in good accordance with the photocatalysis performance. The GO/F-TiO2 interface junction that favors the electron-hole separation was attributed to the photoelectrochemical current enhancement.

20.
Dalton Trans ; 42(13): 4657-62, 2013 Apr 07.
Artigo em Inglês | MEDLINE | ID: mdl-23361100

RESUMO

In this paper, a plasmonic Ag/AgBr heterostructure was reduced by AgBr, which was successfully synthesized by a facile hydrothermal process at a temperature as low as 90 °C. The morphological and structural observation, crystallinity and optical performance of the products grown were carried out by using scanning electron microscopy, X-ray diffraction, energy dispersive spectrometry and UV-vis diffuse reflectance spectroscopy. The photocatalytic activities of Ag/AgBr heterostructures were evaluated by the degradation of methylene blue under 450 nm LED arrays. The results revealed that the plasmonic Ag/AgBr heterostructures exhibited much higher photocatalytic activities than pure AgBr and commercial Degussa P25. The visible-light photocatalytic activity enhancement of Ag/AgBr heterostructures could be attributed to the surface plasmon resonance and its synergistic effect on the photosensitive AgBr. Furthermore, a mechanism of the plasmon synergistically enhanced photocatalytic process was proposed.

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