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1.
Small ; 19(24): e2300631, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-36897000

RESUMO

As an emerging two-dimensional semiconductor, rhenium disulfide (ReS2 ) is renowned for its strong in-plane anisotropy in electrical, optical, and thermal properties. In contrast to the electrical, optical, optoelectrical, and thermal anisotropies that are extensively studied in ReS2 , experimental characterization of mechanical properties has largely remained elusive. Here, it is demonstrated that the dynamic response in ReS2 nanomechanical resonators can be leveraged to unambiguously resolve such disputes. Using anisotropic modal analysis, the parameter space for ReS2 resonators in which mechanical anisotropy is best manifested in resonant responses is determined. By measuring their dynamic response in both spectral and spatial domains using resonant nanomechanical spectromicroscopy, it is clearly shown that ReS2 crystal is mechanically anisotropic. Through fitting numerical models to experimental results, it is quantitatively determined that the in-plane Young's moduli are 127 and 201 GPa along the two orthogonal mechanical axes. In combination with polarized reflectance measurements, it is shown that the mechanical soft axis aligns with the Re-Re chain in the ReS2 crystal. These results demonstrate that dynamic responses in nanomechanical devices can offer important insights into intrinsic properties in 2D crystals and provide design guidelines for future nanodevices with anisotropic resonant responses.

2.
ACS Nano ; 16(12): 20229-20237, 2022 Dec 27.
Artigo em Inglês | MEDLINE | ID: mdl-36508311

RESUMO

As an emerging class of two-dimensional (2D) layered nanomaterial, MXene exhibits a number of intriguing properties, such as good electrical conductivity and high elastic modulus, and has witnessed continued growth in related device research. However, nanoscale MXene devices which leverage both the intrinsic electrical and mechanical properties of these 2D crystals have not been experimentally studied. Here we demonstrate nanoelectromechanical resonators based on 2D MXene crystals, where Ti3C2Tx drumheads with a wide range of thickness, from more than 50 layers all the way down to a monolayer, exhibit robust nanomechanical vibrations with fundamental-mode frequency f0 up to >70 MHz in the very high frequency (VHF) band, a displacement noise density down to 52 fm/Hz1/2, and a fundamental-mode frequency-quality factor product up to f0 × Q ≈ 6.85 × 109 Hz. By combining experimental results with theoretical calculations, we independently derive the Young's modulus of 2D Ti3C2Tx crystals to be 270-360 GPa, in excellent agreement with nanoindentation measurements, based on which we elucidate frequency scaling pathways toward microwave frequencies. We further demonstrate electrical tuning of resonance frequency in MXene resonators and frequency-shift-based MXene vacuum gauges with responsivity of 736%/Torr and detection range down to 10-4 Torr. Our study can lead to the design and creation of nanoscale vibratory devices that exploit the intrinsic electrical and mechanical properties in 2D MXene crystals.

3.
Sensors (Basel) ; 22(22)2022 Nov 16.
Artigo em Inglês | MEDLINE | ID: mdl-36433456

RESUMO

Forest fire prevention is very important for the protection of the ecological environment, which requires effective prevention and timely suppression. The opening of the firebreaks barrier contributes significantly to forest fire prevention. The development of an artificial intelligence algorithm makes it possible for an intelligent belt opener to create the opening of the firebreak barrier. This paper introduces an innovative vision system of an intelligent belt opener to monitor the environment during the creation of the opening of the firebreak barrier. It can provide precise geometric and location information on trees through the combination of LIDAR data and deep learning methods. Four deep learning networks including PointRCNN, PointPillars, SECOND, and PV-RCNN were investigated in this paper, and we train each of the four networks using our stand tree detection dataset which is built on the KITTI point cloud dataset. Among them, the PointRCNN showed the highest detection accuracy followed by PV-RCNN and PV-RCNN. SECOND showed less detection accuracy but can detect the most targets.


Assuntos
Aprendizado Profundo , Algoritmos , Inteligência Artificial
4.
ACS Nano ; 16(10): 15545-15585, 2022 Oct 25.
Artigo em Inglês | MEDLINE | ID: mdl-36054880

RESUMO

The quest for realizing and manipulating ever smaller man-made movable structures and dynamical machines has spurred tremendous endeavors, led to important discoveries, and inspired researchers to venture to previously unexplored grounds. Scientific feats and technological milestones of miniaturization of mechanical structures have been widely accomplished by advances in machining and sculpturing ever shrinking features out of bulk materials such as silicon. With the flourishing multidisciplinary field of low-dimensional nanomaterials, including one-dimensional (1D) nanowires/nanotubes and two-dimensional (2D) atomic layers such as graphene/phosphorene, growing interests and sustained effort have been devoted to creating mechanical devices toward the ultimate limit of miniaturization─genuinely down to the molecular or even atomic scale. These ultrasmall movable structures, particularly nanomechanical resonators that exploit the vibratory motion in these 1D and 2D nano-to-atomic-scale structures, offer exceptional device-level attributes, such as ultralow mass, ultrawide frequency tuning range, broad dynamic range, and ultralow power consumption, thus holding strong promises for both fundamental studies and engineering applications. In this Review, we offer a comprehensive overview and summary of this vibrant field, present the state-of-the-art devices and evaluate their specifications and performance, outline important achievements, and postulate future directions for studying these miniscule yet intriguing molecular-scale machines.

5.
Nano Lett ; 22(13): 5107-5113, 2022 Jul 13.
Artigo em Inglês | MEDLINE | ID: mdl-35522819

RESUMO

Nanomechanical resonators based on atomic layers of tungsten diselenide (WSe2) offer intriguing prospects for enabling novel sensing and signal processing functions. The frequency scaling law of such resonant devices is critical for designing and realizing these high-frequency circuit components. Here, we elucidate the frequency scaling law for WSe2 nanomechanical resonators by studying devices of one-, two-, three-, to more than 100-layer thicknesses and different diameters. We observe resonant responses in both mechanical limits and clear elastic transition in between, revealing intrinsic material properties and devices parameters such as Young's modulus and pretension. We further demonstrate a broad frequency tuning range (up to 230%) with a high tuning efficiency (up to 23% V-1). Such tuning efficiency is among the highest in resonators based on two-dimensional (2D) layered materials. Our findings can offer important guidelines for designing high-frequency WSe2 resonant devices.

6.
Sensors (Basel) ; 19(5)2019 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-30857160

RESUMO

This study proposes a highly sensitive refractive-index (RI) sensor based on a TM0 waveguide mode resonance excited in an asymmetric metal-cladding dielectric waveguide structure, where the analyte serves as the guiding layer. By scanning the wavelength at fixed angles of incidence, the reflection spectra of the sensor were obtained. The results showed that the resonance wavelength redshifted dramatically with increases in the analyte RI, which indicates that this approach can be used to sense both the resonance wavelength and the analyte RI. Based on this approach, we investigated the sensing properties, including the sensitivity and figure of merit, at fixed incident angles of 60° and 45°, at which the sensitivity of the sensor reached 7724.9 nm/RIU (refractive index units) and 1339 nm/RIU, respectively. Compared with surface plasmon resonance sensors, which are based on a similar structure, the proposed sensor can accept a more flexible range of incident angles and a wider sensing range of analyte RI. This approach thus has tremendous potential for use in numerous sensing domains, such as biochemical and medical analyses.

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