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BACKGROUND: Although COVID-19 has brought serious disasters to all mankind, it has also accelerated the innovation and application of educational science and technology. China is the first to bear in COVID-19, and in order to minimize the impact of the field of education and teaching involving a large number of students, educational technology has entered a stage of continuous innovation and large-scale application, especially in higher education institutions. PURPOSE: Firstly, it introduces the progress and achievements of China's educational science and technology innovation during the COVID-19 epidemic, as well as the in-depth application of it in education for studying abroad in China. Secondly, the problems and gaps of STI in education for studying abroad in China are analyzed. Once again, it puts forward the solution countermeasures and future development strategies for the science and technology innovation of education abroad in China. METHODS: A cross-sectional survey of 258 international students from 20 universities was conducted using a self-administered questionnaire entitled "Research on Innovation and Application of Science and Technology in China's International Education under the Situation of Conventional COVID-19 Epidemic Prevention and Control". RESULTS: It will put forward opinions and suggestions to promote the deepening and improvement of China's education science and technology innovation and application, as well as to provide a commentary and theoretical contribution to similar issues and phenomena around the world. CONCLUSION: Through in-depth research and analysis, it is found that the application of science, technology and innovation has played a great role in China's study abroad education, which not only improves the quality and effect of teaching, but also enriches the means and methods of teaching.
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COVID-19 , Estudantes , COVID-19/epidemiologia , COVID-19/prevenção & controle , China/epidemiologia , Humanos , Estudos Transversais , Universidades , Inquéritos e Questionários , Invenções , Masculino , Feminino , SARS-CoV-2 , Tecnologia Educacional , Ciência/educação , Tecnologia/educação , Adulto Jovem , População do Leste AsiáticoRESUMO
Low-cost thermoelectric materials with simultaneous high performance and superior plasticity at room temperature are urgently demanded due to the lack of ever-lasting power supply for flexible electronics. However, the inherent brittleness in conventional thermoelectric semiconductors and the inferior thermoelectric performance in plastic organics/inorganics severely limit such applications. Here, we report low-cost inorganic polycrystalline Mg3Sb0.5Bi1.498Te0.002, which demonstrates a remarkable combination of large strain (~ 43%) and high figure of merit zT (~ 0.72) at room temperature, surpassing both brittle Bi2(Te,Se)3 (strain ≤ 5%) and plastic Ag2(Te,Se,S) and organics (zT ≤ 0.4). By revealing the inherent high plasticity in Mg3Sb2 and Mg3Bi2, capable of sustaining over 30% compressive strain in polycrystalline form, and the remarkable deformability of single-crystalline Mg3Bi2 under bending, cutting, and twisting, we optimize the Bi contents in Mg3Sb2-xBix (x = 0 to 1) to simultaneously boost its room-temperature thermoelectric performance and plasticity. The exceptional plasticity of Mg3Sb2-xBix is further revealed to be brought by the presence of a dense dislocation network and the persistent Mg-Sb/Bi bonds during slipping. Leveraging its high plasticity and strength, polycrystalline Mg3Sb2-xBix can be easily processed into micro-scale dimensions. As a result, we successfully fabricate both in-plane and out-of-plane flexible Mg3Sb2-xBix thermoelectric modules, demonstrating promising power density. The inherent remarkable plasticity and high thermoelectric performance of Mg3Sb2-xBix hold the potential for significant advancements in flexible electronics and also inspire further exploration of plastic inorganic semiconductors.
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The rapid development of the Internet of Things has triggered a huge demand for self-sustained technology that can provide a continuous electricity supply for low-power electronics. Here, a self-sustained power supply solution is demonstrated that can produce a 24 h continuous and unipolar electricity output based on thermoelectric devices by harvesting the environmental temperature difference, which is ingeniously established utilizing radiation cooling and selective photothermal conversion. The developed prototype system can stably maintain a large temperature difference of about 1.8 K for a full day despite the real-time changes in environmental temperature and solar radiation, thereby driving continuous electricity output using the built-in thermoelectric device. Specifically, the large output voltage of >102 mV and the power density of >4.4 mW m-2 could be achieved for a full day, which are outstanding among the 24 h self-sustained thermoelectric devices and far higher than the start-up values of the wireless temperature sensor and also the light-emitting diode, enabling the 24 h remote data transmission and lighting, respectively. This work highlights the application prospects of self-sustained thermoelectric devices for low-power electronics.
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To propose improved and innovative visual-tactile interaction design for visually impaired children, multi-modal combination approaches have been applied, such as voice interaction, touch interaction, and multi-modal systems, what's more, aided cognitive approaches help them deepen their understanding of objects, improve their cognitive level, and increase their interest. METHODS: To improve the amount of information in the visual-haptic interface by integrating multiple sensory information, based on the cognitive patterns of visually impaired children, a questionnaire was used to design a tactile-visual UI for the main content objects of visually impaired children when using the Internet, from which difficulties and problems in the design of visual-haptic for visually impaired children were found, and design improvements were proposed based on the principles and methods of accessible design. RESULTS: The personalized and humanized design activities enhance the confidence and improve the quality of life of the visually impaired children group and produce positive effects, improving the cognitive clarity of visually impaired children while increasing their level of understanding, imagination, learning interest and aesthetic experience. CONCLUSION: The physical and mental characteristics and visual and tactile characteristics of visually impaired children are analyzed, and the application of UI interaction design is based on these characteristics. The essence of interaction design is outlined through experiments, and it is found that with the development of the Internet, big data and artificial intelligence, visually impaired children have many difficulties in the use of the Internet, and through the improved practice of immersive interaction design, the humanized design approach is used to enhance visually impaired children's experience of using network interfaces. Through the improved practice of immersive interaction design, we improve the way of visually impaired children using the Internet, narrow the gap between them and normal children in the interaction, and give humanistic care.
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To explore the visual experience characteristics and influencing factors of college students' visual attention intervention in the interface of mobile learning platform by using eye-tracking technology, and to summarize and summarize the visual experience pattern of platform interface design and its design inspiration. METHODS: Using the head-mounted eye-tracking technology, 28 images from 6 groups of typical elements in the interface layout of CGTN learning platform were selected as the test samples, and the eye-movement indexes of the subjects browsing the interface were recorded. RESULTS: There were significant differences in the attention time, number of times of attention, visual attention rate and visual recall rate of different areas and topics of the interface (P < 0. 001). CONCLUSION: In the platform interface design, the analysis of the factors influencing visual attention can be found that people's attention and visual experience is mainly influenced by color, text, and typography, and secondary areas and layout also play an important role in visual communication. The color and text areas in the interface design, as well as the innovative design of typography can effectively enhance the visual attention of college students and better communicate the information of the platform.
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Aprendizagem , Envio de Mensagens de Texto , Humanos , Estudantes , Movimentos Oculares , Rememoração MentalRESUMO
Half-Heusler compounds with semiconducting behavior have been developed as high-performance thermoelectric materials for power generation. Many half-Heusler compounds also exhibit metallic behavior without a bandgap and thus inferior thermoelectric performance. Here, taking metallic half-Heusler MgNiSb as an example, a bandgap opening strategy is proposed by introducing the d-d orbital interactions, which enables the opening of the bandgap and the improvement of the thermoelectric performance. The width of the bandgap can be engineered by tuning the strength of the d-d orbital interactions. The conduction type and the carrier density can also be modulated in the Mg1- x Tix NiSb system. Both improved n-type and p-type thermoelectric properties are realized, which are much higher than that of the metallic MgNiSb. The proposed bandgap opening strategy can be employed to design and develop new half-Heusler semiconductors for functional and energy applications.
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The recently developed defective 19-electron half-Heusler (HH) compounds, represented by Nb1- δ CoSb, possess massive intrinsic vacancies at the cation site and thus intrinsically low lattice thermal conductivity that is desirable for thermoelectric (TE) applications. Yet the TE performance of defective HHs with a maximum figure of merit (zT) <1.0 is still inferior to that of the conventional 18-electron ones. Here, a peak zT exceeding unity is obtained at 1123 K for both Nb0.7 Ta0.13 CoSb and Nb0.6 Ta0.23 CoSb, a benchmark value for defective 19-electron HHs. The improved zT results from the achievement of selective scatterings of phonons and electrons in defective Nb0.83 CoSb, using lanthanide contraction as a design factor to select alloying elements that can strongly impede the phonon propagation but weakly disturb the periodic potential. Despite the massive vacancies induced strong point defect scattering of phonons in Nb0.83 CoSb, Ta alloying is still found effective in suppressing lattice thermal conductivity while maintaining the carrier mobility almost unchanged. In comparison, V alloying significantly deteriorates the carrier transport and thus the TE performance. These results enlarge the category of high-performance HH TE materials beyond the conventional 18-electron ones and highlight the effectiveness of selective scatterings of phonons and electrons in developing TE materials even with massive vacancies.
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Wearable thermoelectric generators (TEGs), which can convert human body heat to electricity, provide a promising solution for self-powered wearable electronics. However, their power densities still need to be improved aiming at broad practical applications. Here, a stretchable TEG that achieves comfortable wearability and outstanding output performance simultaneously is reported. When worn on the forehead at an ambient temperature of 15 °C, the stretchable TEG exhibits excellent power densities with a maximum value of 13.8 µW cm-2 under the breezeless condition, and even as high as 71.8 µW cm-2 at an air speed of 2 m s-1 , being one of the highest values for wearable TEGs. Furthermore, this study demonstrates that this stretchable TEG can effectively power a commercial light-emitting diode and stably drive an electrocardiogram module in real-time without the assistance of any additional power supply. These results highlight the great potential of these stretchable TEGs for power generation applications.
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Due to the urgent demand for lithium-ion batteries (LIBs) with a high energy density, silicon (Si) possessing an ultrahigh capacity has aroused wide attention. However, its practical application is seriously hindered by enormous volume changes of the Si anode during cycling. Developing novel binders suitable for the Si anode has proven to be an effective strategy to improve its electrochemical performance. Herein, we constructed a three-dimensional network binder, in which the polyacrylic acid (PAA) long chains are cross-linked with one kind of amino acid, lysine (Lys). The abundant polar groups in PAA/Lys enable it to tightly adhere to the Si particles via hydrogen bonds, and the cross-linked structure prevents irreversible slipping of the PAA chains upon volume variation of the particles. The Si used was obtained from a sustainable route by recycling photovoltaic waste silicon. With high elasticity and strong adhesion, the PAA/Lys binder can effectively keep the structural integrity of the Si electrode and improve its electrochemical performance. The Si electrode using the PAA/Lys binder exhibits a good cycling stability (1008 mAh g-1 at 2 A g-1 after 250 cycles). Even with a high mass loading of 3.03 mg cm-2, the Si anode can remain stable for 100 cycles at a high fixed areal capacity of 3.03 mAh cm-2. This work gives a practical method to make stable Si electrodes using sustainable Si source and environmentally friendly amino acid-based binders.
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Inorganic semiconductor Ag2Te1-x S x has been recently found to exhibit unexpected plastic deformation with compressive strain up to 30%. However, the origin of the abnormal plasticity and how to simultaneously achieve superb ductility and high mobility are still elusive. Here, we demonstrate that crystalline/amorphous Ag2Te1-x S x (x = 0.3, 0.4, and 0.5) composites can exhibit excellent compressive strain up to 70% if the monoclinic Ag2Te phase, which commonly exists in the matrix, is eliminated. Significantly, an ultra-high tensile elongation reaching 107.3% was found in Ag2Te0.7S0.3, which is the highest one yet reported in the system and even surpasses those achieved in some metals and high-entropy alloys. Moreover, high mobility of above 1000 cm2 V-1 s-1 at room temperature and good thermoelectric performance are simultaneously maintained. A modified Ashby plot with ductility factor versus carrier mobility is thereby proposed to highlight the potential of solid materials for applications in flexible/wearable electronics.
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Wearable thermoelectrics has attracted significant interest in recent years. Among them, rigid-structure thermoelectric generators (TEGs) were seldomly employed for wearable applications, although those exhibit significant advantages of high device output performance and impact resistance. Here, we report a type of rigid wearable TEGs (w-TEGs) without ceramic substrates made using a simple cutting-and-bonding method. Owing to the small contact area, the w-TEGs comprising 48-n/p-pairs can be well attached to the human body. The lack of ceramic substrates leaves more space in the height direction, which benefits the wearability in practical applications and high power density. We demonstrated that increasing the height of w-TEGs from 1.38 to 3.14 mm significantly improves the power density by a factor of 10. As a result, the maximum power densities of 7.9 µW cm-2 and 43.6 µW cm-2 for the w-TEGs were realized under the breezeless condition and a wind speed for normal walking, respectively. This work provides a feasible design solution for rigid-structure free-substrate w-TEGs with very high power density, which will speed up the research of wearable thermoelectrics.
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Temperatura Alta , Dispositivos Eletrônicos Vestíveis , Fontes de Energia Elétrica , Corpo Humano , Humanos , CaminhadaRESUMO
Wearable thermoelectric generators (w-TEGs) can incessantly convert body heat into electricity to power electronics. However, the low efficiency of thermoelectric materials, tiny terminal temperature difference, rigidity, and negligence of lateral heat transfer preclude broad utilization of w-TEGs. In this work, we employ finite element simulation to find the key factors for simultaneous realization of flexibility and ultrahigh normalized power density. Using melamine foam with an ultralow thermal conductivity (0.03 W/m K) as the encapsulation material, a novel lightweight π-type w-TEG with no heatsink and excellent stretchability, comfortability, processability, and cost efficiency has been fabricated. At an ambient temperature of 24 °C, the maximum power density of the w-TEG reached 7 µW/cm2 (sitting) and 29 µW/cm2 (walking). Under suitable heat exchange conditions (heatsink with 1 m/s air velocity), 32 pairs of w-TEGs can generate 66 mV voltage and 60 µW/cm2 power density. The output performance of our TEG is remarkably superior to that of previously reported w-TEGs. Besides, the practicality of our w-TEG was showcased by successfully driving a quartz watch at room temperature.
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Valley anisotropy is a favorable electronic structure feature that could be utilized for good thermoelectric performance. Here, taking advantage of the single anisotropic Fermi pocket in p-type Mg3Sb2, a feasible strategy utilizing the valley anisotropy to enhance the thermoelectric power factor is demonstrated by synergistic studies on both single crystals and textured polycrystalline samples. Compared to the heavy-band direction, a higher carrier mobility by a factor of 3 is observed along the light-band direction, while the Seebeck coefficient remains similar. Together with lower lattice thermal conductivity, an increased room-temperature zT by a factor of 3.6 is found. Moreover, the first-principles calculations of 66 isostructural Zintl phase compounds are conducted and 9 of them are screened out displaying a pz-orbital-dominated valence band, similar to Mg3Sb2. In this work, we experimentally demonstrate that valley anisotropy is an effective strategy for the enhancement of thermoelectric performance in materials with anisotropic Fermi pockets.
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The configurational entropy is an emerging descriptor in the functional materials genome. In thermoelectric materials, the configurational entropy helps tune the delicate trade-off between carrier mobility and lattice thermal conductivity, as well as the structural phase transition, if any. Taking GeTe as an example, low-entropy GeTe generally have high carrier mobility and distinguished zT > 2, but the rhombohedral-cubic phase transition restricts the applications. In contrast, despite cubic structure and ultralow lattice thermal conductivity, the degraded carrier mobility leads to a low zT in high-entropy GeTe. Herein, medium-entropy alloying is implemented to suppress the phase transition and achieve the cubic GeTe with ultralow lattice thermal conductivity yet decent carrier mobility. In addition, co-alloying of (Mn, Pb, Sb, Cd) facilitates multivalence bands convergence and band flattening, thereby yielding good Seebeck coefficients and compensating for decreased carrier mobility. For the first time, a state-of-the-art zT of 2.1 at 873 K and average zT ave of 1.3 between 300 and 873 K are attained in cubic phased Ge0.63Mn0.15Pb0.1Sb0.06Cd0.06Te. Moreover, a record-high Vickers hardness of 270 is attained. These results not only promote GeTe materials for practical applications, but also present a breakthrough in the burgeoning field of entropy engineering.
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Although crystalline solids are characterized by their periodic structures, some are only periodic on average and deviate on a local scale. Such disordered crystals with distinct local structures have unique properties arising from both collective and localized behaviour. Different local orderings can exist with identical average structures, making their differences hidden to Bragg diffraction methods. Using high-quality single-crystal X-ray diffuse scattering the local order in thermoelectric half-Heusler Nb1-x CoSb is investigated, for which different local orderings are observed. It is shown that the vacancy distribution follows a vacancy repulsion model and the crystal composition is found always to be close to x = 1/6 irrespective of nominal sample composition. However, the specific synthesis method controls the local order and thereby the thermoelectric properties thus providing a new frontier for tuning material properties.
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Poor cycling stability and rate capability are two key issues needing to be solved for Li- and Mn-rich oxide cathode material for lithium-ion batteries (LIBs). Herein, a novel perovskite electron-ion mixed conductor Nd0.6 Sr0.4 CoO3 (NSCO) is used as the coating layer on Li1.2 Ni0.13 Co0.13 Mn0.54 O2 (LNCMO) to simultaneously enhance its cycling stability and rate capability. By coating 3 wt% NSCO, LNCMO-3NSCO exhibits an optimal cycling performance with a capacity retention of 99% at 0.1C (1C = 200 mA g-1 ) after 60 cycles, 91% at 1C after 300 cycles, and 54% at 20C after 1000 cycles, much better than 78%, 63%, and 3% of LNCMO, respectively. Even at a high charge and discharge rate of 50C, LNCMO-3NSCO exhibits a discharge capacity of 53 mAh g-1 and a mid-point discharge voltage of 2.88 V, much higher than those of LNCMO (24 mA h g-1 and 2.40 V, respectively). Benefiting from the high electronic conductivity (1.46 S cm-1 ) and ionic conductivity (1.48 × 10-7 S cm-1 ), NSCO coating not only suppresses transition metals dissolution and structure transformation, but also significantly enhances electronic conductivity and Li+ diffusion coefficient of LNCMO by an order of magnitude.
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In recent years, high-performance half-Heusler compounds have been developed as promising thermoelectric materials for power generation. Aiming at practical device applications, one key step is to seek suitable metal electrodes so that low interfacial resistivity is guaranteed under long-term thermal aging. In the previous work, the fresh Mo/Nb0.8Ti0.2FeSb junction was found exhibiting low contact resistivity below 1 µΩ cm2; however, it increased by tens of times under long-term thermal aging, mainly originating from the formation of the high-resistivity FeSb2 phase and the appearance of cracks. Here, the Mo-Fe electrodes are employed to build the junctions with Nb0.8Ti0.2FeSb. The interfacial behavior and contact resistance in these junctions were investigated both before and after the thermal aging. Interestingly, no obvious formation of FeSb2 phase and cracks were observed. As a result, the contact resistivity was below â¼1 µΩ cm2 after 15 days' thermal aging, indicating better connection reliability and lower contact resistivity compared to the Mo/Nb0.8Ti0.2FeSb junction. These findings highlight the applicability of Mo-Fe electrodes and pave the way for NbFeSb-based half-Heusler thermoelectric materials for device applications.
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Whether the atomic arrangement has a long-range order bifurcates solid-state matter into two major categories: crystalline and amorphous, between which lies a short-range order, a frontier research topic of fundamental and application implications. To date, it is still challenging to extract the details of short-range order from the corresponding diffuse diffraction pattern due to the phase problem. Here, we employed the high-angle annular dark field (HAADF) imaging technique to pinpoint the short-range order encoded in the one-of-a-kind diffuse the diffraction bands of defective half-Heusler Nb0.8CoSb. Utilizing a protocol based on two limiting cases, we found that the native Nb vacancies up to 20% are dominantly displacive short-range ordered yet spatially correlated. To the best of our knowledge, this is the first time that a dominantly displacive short-range order is reported at the atomic scale. These results are vital for an in-depth understanding and engineering of the thermodynamics and transport properties of the materials with abundant native defects, including but not limited to defective half-Heusler compounds.
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Bi2 Te3 -based solid solutions, which have been widely used as thermoelectric (TE) materials for the room temperature TE refrigeration, are also the potential candidates for the power generators with medium and low-temperature heat sources. Therefore, depending on the applications, Bi2 Te3 -based materials are expected to exhibit excellent TE properties in different temperature ranges. Manipulating the point defects in Bi2 Te3 -based materials is an effective and important method to realize this purpose. In this review, we focus on how to optimize the TE properties of Bi2 Te3 -based TE materials in different temperature ranges by defect engineering. Our calculation results of two-band model revel that tuning the carrier concentration and band gap, which is easily realized by defects engineering, can obtain better TE properties at different temperatures. Then, the typical paradigms about optimizing the TE properties at different temperatures for n-type and p-type Bi2 Te3 -based ZM ingots and polycrystals are discussed in the perspective of defects engineering. This review can provide the guidance to improve the TE properties of Bi2 Te3 -based materials at different temperatures by defects engineering.
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Defective half-Heusler systems X 1-x YZ with large amounts of intrinsic vacancies, such as Nb1-x CoSb, Ti1-x NiSb and V1-x CoSb, are a group of promising thermoelectric materials. Even with high vacancy concentrations they maintain the average half-Heusler crystal structure. These systems show high electrical conductivity but low thermal conductivity arising from an ordered YZ substructure, which conducts electrons, while the large amounts of vacancies in the X substructure effectively scatters phonons. Using electron scattering, it was recently observed that, in addition to Bragg diffraction from the average cubic half-Heusler structure, some of these samples show broad diffuse scattering indicating short-range vacancy order, while other samples show sharp additional peaks indicating long-range vacancy ordering. Here it is shown that both the short- and long-range ordering can be explained using the same simple model, which assumes that vacancies in the X substructure avoid each other. The samples showing long-range vacancy order are in agreement with the predicted ground state of the model, while short-range order samples are quenched high-temperature states of the system. A previous study showed that changes in sample stoichiometry affect whether the short- or long-range vacancy structure is obtained, but the present model suggests that thermal treatment of samples should allow controlling the degree of vacancy order, and thereby the thermal conductivity, without changes in composition. This is important as the composition also dictates the amount of electrical carriers. Independent control of electrical carrier concentration and degree of vacancy order should allow further improvements in the thermoelectric properties of these systems.