Catalytic Enantioselective [4+2] Cycloadditions of Salicylaldehyde Acetals with Enol Ethers.

A readily accessible conjugate-base-stabilized carboxylic acid (CBSCA) catalyst facilitates highly enantioselective [4+2] cycloaddition reactions of salicylaldehyde-derived acetals and cyclic enol ethers, resulting in the formation of polycyclic chromanes with oxygenation in the 2- and 4-positions. Stereochemically more complex products can be obtained from racemic enol ethers. Spirocyclic products are also accessible.

Freeform mirror array design for concentrating sunlight onto a CPV solar cell.

In a concentrating photovoltaic (CPV) system, realizing an illumination spot consistent with the photosensitive area of the CPV cell while maintaining high optical performances is a challenging but rewarding issue. For instance, uniform irradiance distribution not only reduces the risk of damage to CPV cells due to the local heat accumulation, but also improves photoelectric conversion efficiency; free chromatic aberration ensures that a wide solar spectrum can be regulated; a high concentration ratio helps reduce the usage of CPV cells, and so on. Here, we propose a method to design a freeform mirror array to concentrate sunlight and generate a square light pattern with uniform irradiance distribution on the photovoltaic cell. Each freeform mirror can produce a uniform illumination pattern on the CPV cell. We demonstrate the effectiveness of the proposed method with several design examples, and a series of factors affecting the optical performance is also analyzed.

Divergent Functionalization of Alkynes Enabled by Organic Photoredox Catalysis.

Direct functionalization of alkynes under oxidative conditions is challenging, as alkynes are usually recalcitrant towards typical oxidants. Herein, we communicate a strategy for the divergent functionalization of alkynes with photoexcited acridinium organic dyes, presumably via the formation of vinyl cation radicals as key intermediates. Based on the nature of the nucleophiles, different types of difunctionalized products were obtained in moderate to good yields. Addition of lithium Lewis acids resulted in a surprising reversal of diastereocontrol.

Design and parameter study of banana crown mechanical cutting device.

Banana mechanical crown cutting tool which is a critical component of banana crown cutting machine is designed and studied in this paper. Experiments were designed to optimize parameters of the cutting tool. Indexes are cut surface quality grade of banana crown, maximum cutting force and useful power consumption. For banana preservation, get high grade of cut surface quality is more significant than consume less energy. Results of experiments show that the optimum parameters are as follows: cutting speed is about 50-60 mm/s, number of cut sets are about 4-6, angle between thick cutter and axis of banana rachis is about 5°, width of thick cutter is about 8-14 mm, thickness of thick cutter is about 2-3 mm, edge angle of thick cutter is between 20° and 30°, width of thin cutter is about 10-14 mm and thickness of thin cutter is about 0.2-0.4mm. This study helps to make the completely mechanical postharvest treatments for banana postharvest treatments.

Freeform illumination optics design for extended LED sources through a localized surface control method.

Freeform illumination optics design with extended light sources to realize an accurate light control is very important, but still remains a challenging issue. Here, we propose a new method to design compact and efficient freeform lenses for extended sources. We employ a localized surface control strategy to directly modify the freeform surface to redistribute the light rays emitted from the extended LED source in a desired manner. By the combination of basic radiometry calculation and backward ray tracing, we obtain the irradiance distribution on the target plane and estimate the localized freeform surface to be modified. The optimization function with a Gaussian form is adopted to modify the localized surface. The smoothness of the freeform surface is taken into account in the optimization process to guarantee the processability of the freeform optics. We demonstrate the effectiveness of the proposed method with three design examples.

Compact freeform illumination optics design by deblurring the response of extended sources.

Freeform illumination design for extended sources is a very challenging but rewarding issue that can benefit a wide range of illumination systems. Here, we propose a method that can achieve compact and highly efficient illumination lenses by deconvolving the blur caused by the extent from light sources. We combine the illumination calculation with the mathematical model of spatially variant convolution and develop a direct computational scheme to calculate the blur kernel without approximations. Two design examples with high optical performances are presented to demonstrate the effectiveness of the proposed method.

Freeform illumination optics for 3D targets through a virtual irradiance transport.

Freeform illumination optics design for 3D target surfaces is a challenging and rewarding issue. The current researches on freeform illumination optics are mostly involved in planar targets, especially for the cases where the targets are perpendicular to the optical axis. Here, we propose a general method to design freeform optics for illuminating 3D target surfaces for zero-étendue sources. In this method, we employ a virtual observation plane which is perpendicular to the optical axis and transfer the irradiance on the 3D target surface to this virtual plane. By designing freeform optics to generate the transferred irradiance distribution, the prescribed irradiance distribution on the 3D target can be realized automatically. The influence of the freeform optics size is considered in the optics design process, which makes it possible to design illumination system for near-field configuration where the influence of the freeform optics size cannot be ignored. We demonstrate the robustness and elegance of the proposed method with three design examples.

Least-squares ray mapping method for freeform illumination optics design: erratum.

We provide corrections of the author list as well as Eq. (12) and (13) in our previous publication [Opt. Express28, 38113811 (2020)10.1364/OE.385254].

Design of a high-throughput telescope based on scanning an off-axis three-mirror anastigmat system.

A high-throughput optical system possesses a large field of view (FOV) and high resolution. However, it is a major challenge to design such a telescope with these two conflicting specifications. In this paper, we propose a method to design a high-throughput telescope based on the classical off-axis three-mirror anastigmat (TMA) configuration by introducing a scanning mechanism. We derive the optimum initial design for the TMA system with no primary aberrations through characteristic ray tracing. During the design process, a real exit pupil is necessitated to accommodate the scanning mirror. By gradually increasing the system's FOV during the optimization procedure, we finally obtained a high-throughput telescope design with an F-number of 6, a FOV of 60∘×1.5∘, and a long focal length of 876 mm. In addition, a tolerance analysis is also conducted to demonstrate the instrumentation feasibility. We believe that this kind of large rectangle FOV telescope with high resolution has broad future applications in the optical remote sensing field.

Variable-diameter beam-shaping system design with high zoom ratio containing aspheric optical components.

Recently, the optical design of refractive beam-shaping systems has been extensively studied, although such study remains focused on two optical surfaces. Designing a beam-shaping system with variable output beam sizes and prescribed irradiance profiles remains a challenging but rewarding task. Here, we present a design framework, including calculation of the initial system and optimization process, to achieve variable-diameter beam-shaping systems with high zoom ratios. We introduce the whole process of designing a compact 8× zoom system of superior optical performance by transforming a Gaussian beam into flat-top beams with different magnifications. We also present a design of a zoom beam-shaping system transforming a Gaussian beam into variable beams with inverse Gaussian distributions to demonstrate the robustness and efficiency of the proposed method.