RESUMO
We demonstrate a dual-comb spectrometer using stabilized frequency combs spanning 177 to 220 THz (1360 to 1690 nm) in the near infrared. Comb-tooth-resolved measurements of amplitude and phase generate over 4×10(5) individually resolved spectral elements at 100 MHz point spacing and kilohertz-level resolution and accuracy. The signal-to-noise ratio is 100 to 3000 per comb tooth. Doppler-broadened phase and amplitude spectra of CO(2), CH(4), C(2)H(2), and H(2)O in a 30 m multipass cell agree with established spectral parameters, achieving high-resolution measurements with optical bandwidth generally associated with blackbody sources.
RESUMO
State-to-state reaction dynamics of the reaction F+HCl-->HF(v,J)+Cl have been studied under single-collision conditions using an intense discharge F atom source in crossed supersonic molecular beams at Ecom=4.3(1.3) kcal/mol. Nascent HF product is monitored by shot-noise limited direct infrared laser absorption, providing quantum state distributions as well as additional information on kinetic energy release from high resolution Dopplerimetry. The vibrational distributions are highly inverted, with 34(4)%, 44(2)%, and 8(1)% of the total population in vHF=1, 2, and 3, respectively, consistent with predominant energy release into the newly formed bond. However, there is a small [14(1)%] but significant formation channel into the vHF=0 ground state, which is directly detectable for the first time via direct absorption methods. Of particular dynamical interest, both the HF(v=2,J) and HF(v=1,J) populations exhibit strongly bimodal J distributions. These results differ significantly from previous flow and arrested-relaxation studies and may signal the presence of microscopic branching in the reaction dynamics.
