Recent advances in nanomaterial-stabilized pickering foam: Mechanism, classification, properties, and applications.

Pickering foam is a type of foam stabilized by solid particles known as Pickering stabilizers. These solid stabilizers adsorb at the liquid-gas interface, providing superior stability to the foam. Because of its high stability, controllability, versatility, and minimal environmental impact, nanomaterial-stabilized Pickering foam has opened up new possibilities and development prospects for foam applications. This review provides an overview of the current state of development of Pickering foam stabilized by a wide range of nanomaterials, including cellulose nanomaterials, chitin nanomaterials, silica nanoparticles, protein nanoparticles, clay mineral, carbon nanotubes, calcium carbonate nanoparticles, MXene, and graphene oxide nanosheets. Particularly, the preparation and surface modification methods of various nanoparticles, the fundamental properties of nanomaterial-stabilized Pickering foam, and the synergistic effects between nanoparticles and surfactants, functional polymers, and other additives are systematically introduced. In addition, the latest progress in the application of nanomaterial-stabilized Pickering foam in the oil industry, food industry, porous functional material, and foam flotation field is highlighted. Finally, the future prospects of nanomaterial-stabilized Pickering foam in different fields, along with directions for further research and development directions, are outlined.

Fabrication of porous adsorbent by quinoa husk stabilized foam templates for dye adsorption and carbonization for soil remediation.

In this study, a novel adsorbent with a sufficient porous structure was fabricated using a green and highly stable water-based foam template. This template was stabilized with agricultural waste quinoa husk (QH) and applied to remove dye pollutants in wastewater. The porous adsorbent exhibited a high adsorption capacity of 740.95 mg/g for methylene blue and 1022.1 mg/g for methyl violet. The adsorption process was well described by the Langmuir-Freundlich model and the pseudo second-order kinetic model. A sustainable concept for handling the spent adsorbent was also proposed, involving its conversion into biochar and safe return to the soil. An additional benefit was observed, as the biochar effectively adjusted the physicochemical properties of the soil and improved crop growth with the addition of 1 wt%. The potential application of porous adsorbent in wastewater treatment and the reference of sustainable strategy for disposing of other adsorbents are both noteworthy.

Fabrication porous adsorbents templated from aqueous foams using astragalus membranaceus and attapulgite as stabilizer for efficient removal of cationic dyes.

The water-based foam stabilized by the natural surfactant applied in the fabrication of porous materials has attracted extensive attention, as the advantages of cleanness, convenience and low cost. Particularly, the development of a green preparation method has became the main research focus and frontier. In this work, a green liquid foam with high stability was prepared by synergistic stabilization of natural plant astragalus membranaceus (AMS) and attapulgite (APT), and then a novel porous material with sufficient hierarchical pore structure was templated from the foam via a simple free radical polymerization of acrylamide (AM). The characterization results revealed that the amphiphilic molecules from AMS adsorbed onto the water-air interface and formed a protective shell to prevent the bubble breakup, and APT gathered in the plateau border and formed a three-dimensional network structure, which greatly slowed down the drainage rate. The porous material polyacrylamide/astragalus membranaceus/attapulgite (PAM/AMS/APT) showed the excellent adsorption performance for cationic dyes of Methyl Violet (MV) and Methylene Blue (MB) in water, and the maximum adsorption capacity could reach to 709.13 and 703.30 mg/g, respectively. Furthermore, the polymer material enabled to regenerate and cycle via a convenient calcination process, and the adsorption capacity was still higher than 200 mg/g after five cycles. In short, this research provided a new idea for the green preparation of porous materials and the treatment of water pollution.

Pickering foams and parameters influencing their characteristics.

Pickering foams are available in many applications and have been continually gaining interest in the last two decades. Pickering foams are multifaceted, and their characteristics are highly dependent on many factors, such as particle size, charge, hydrophobicity and concentration as well as the charge and concentration of surfactants and salts available in the system. A literature review of these individual studies at first might seem confusing and somewhat contradictory, particularly in multi-component systems with particles and surfactants with different charges in the presence of salts. This paper provides a comprehensive overview of particle-stabilized foams, also known as Pickering foams and froths. Underlying mechanisms of foam stabilization by particles with different morphology, surface chemistry, size and type are reviewed and clarified. This paper also outlines the role of salts and different factors such as pH, temperature and gas type on Pickering foams. Further, we highlight recent developments in Pickering foams in different applications such as food, mining, oil and gas, and wastewater treatment industries, where Pickering foams are abundant. We conclude this overview by presenting important research avenues based on the gaps identified here. The focus of this review is limited to Pickering foams of surfactants with added salts and does not include studies on polymers, proteins, or other macromolecules.

Shape-recoverable, piezoresistive, and thermally insulated xerogels based on nanochitin-stabilized Pickering foams.

Biomass-derived porous materials are promising for various fields and preferred for sustainable development. In this work, shape-recoverable nanochitin-based xerogels with porous structure and excellent mechanical strength, thermal insulation (43.23 ± 0.17 mW/m·k) and piezoresistive properties were prepared by nanochitin-stabilized Pickering foams with chemical crosslinking for the first time through simple air-drying. At the optimized ingredients of nanochitin, surfactant (T80) and crosslinker (glutaraldehyde), the Pickering foams exhibited no significant collapse after one week, and the xerogels prepared thereof achieved a mechanical strength of 0.5-2.7 MPa at 80% strain and considerable structural stability after 100 cycles at 60% strain. Moreover, the resistance of the xerogel had a high linearity in the strain range (0-10%) and could recover to the initial value after 20 cycles. Notably, this is the first time that pure bio-based conductive xerogel has been obtained. These features make nanochitin a promising candidate for biodegradable and sustainable 3D porous materials.

MFC/NFC-Based Foam/Aerogel for Production of Porous Materials: Preparation, Properties and Applications.

Nanofibrillated cellulose and microfibrillated cellulose are potential raw materials separated from plant fibers with a high aspect ratio and excellent mechanical properties, which can be applied in various fields (packaging, medicine, etc.). They have unique advantages in the preparation of aerogels and foams, and have attracted widespread attention in recent years. Cellulose-based porous materials have good biodegradability and biocompatibility, while high porosity and high specific surface area endow them with strong mechanical properties and liquid retention performance, which can be used in wall construction, sewage treatment and other fields. At present, the preparation method of this material has been widely reported, however, due to various process problems, the actual production has not been realized. In this paper, we summarize the existing technical problems and main solutions; in the meantime, two stable systems and several drying processes are described, and the application potential of cellulose-based porous materials in the future is described, which provides a reference for subsequent research.

Fabrication porous adsorbents templated from modified sepiolite-stabilized aqueous foams for high-efficient removal of cationic dyes.

High internal phase emulsions (HIPEs) as template for fabrication of porous materials has attracted much attention, due to the high porosity and tunable porous structure. But the enormous consumption of organic solvents is still a nightmare for the practical application. In comparison, the aqueous foam without need any organic solvent and hence has greater advantages in the porous materials preparation. In this study, a novel Pickering foam which was stabilized by modified sepiolite (Sep) was prepared and applied as the template for preparation of the porous material via thermal-initiated polymerization. The Pickering foam had excellent ability and stability in the pH of 4-11 and the obtained porous adsorbent possess sufficient and tuned pore structure. The porous materials as adsorbent has favorable performance for adsorption and selective removal of cationic dyes, and the understanding adsorption capacities for Methylene blue (MB) and Methyl green (MG) can be achieved with 1421.18 mg/g and 638.81 mg/g within 60 and 45 min at 25 °C, respectively. This porous material can be as the potential adsorbent for adsorption or separation of organic pollutants.

Occurrence and prevention of Pickering foams in pharmaceutical nano-milling.

Particle size reduction to sub-micrometer dimensions in stirred media mills is an increasingly common formulation strategy used for improving the bioavailability of poorly aqueous soluble active pharmaceutical ingredients (APIs). Due to their hydrophobic character, the API particles need to be stabilised by a surfactant in order to form a stable nano-suspension. This work is concerned with the understanding of an undesired phenomenon often encountered during the development and scale-up of wet nano-milling processes for hydrophobic APIs - the formation of foams. We investigate the microstructure, rheology and stability of these foams, and find them to be Pickering foams stabilised by solid particles at the gas-liquid interface rather than by a surfactant. By exploring the effect of surfactant concentration on the on-set of foaming in conjunction with the milling kinetics, we find a relationship between the specific surface area of the nano-suspension, the quantity of surfactant present in the formulation and the occurrence of foaming. We propose a mechanistic explanation of foam formation, and find that in order to prevent foaming, a large surfactant excess of approx. 100x above the critical micelle concentration has to be present in the solution in order to ensure a sufficiently rapid coverage of freshly exposed hydrophobic surfaces formed during the wet nano-milling process.