Enhancing pollutant removal efficiency in urban domestic wastewater treatment through the hybrid multi-soil-layering (MSL) system: A case study in Morocco.

This paper evaluates the performance and potential of a full-scale hybrid multi-soil-layering (MSL) system for the treatment of domestic wastewater for landscape irrigation reuse. The system integrates a solar septic tank and sequential vertical flow MSL and horizontal flow MSL components with alternating layers of gravel and soil-based material. It operates at a hydraulic loading rate of 250 L/m2/day. Results show significant removal of pollutants and pathogens, including total suspended solids (TSS) (97%), chemical oxygen demand (COD) (88.57%), total phosphorus (TP) (79.93%), and total nitrogen (TN) (88.49%), along with significant reductions in fecal bacteria indicators (4.21 log for fecal coliforms and 3.90 log for fecal streptococci) and the pathogen Staphylococcus sp. (2.43 log). The principal component analysis confirms the effectiveness of the system in reducing the concentrations of NH4, COD, TP, PO4, fecal coliforms, fecal streptococci, and fecal staphylococci, thus supporting the reliability of the study. This work highlights the promising potential of the hybrid MSL technology for the treatment of domestic wastewater, especially in arid regions such as North Africa and the Middle East, to support efforts to protect the environment and facilitate the reuse of wastewater for landscape irrigation and agriculture.

Electrochemically produced nano-TiO2-coated SiC membranes for photocatalytic water treatment: Preparation, characterization, and hydroxyl radical formation.

Photocatalytically active ceramic flat sheet membranes based on a nanostructured titanium dioxide (TiO2) coating were produced for photocatalytic water treatment. The nano-TiO2 layer was produced by a novel combination of magnetron sputtering of a thin titanium layer on silicon carbide (SiC) membranes, followed by electrochemical oxidation (anodization) and subsequent heat treatment (HT). Characterization by Raman spectra and field emission scanning electron microscopy proved the presence of a nanostructured anatase layer on the membranes. The influence of the titanium layer thickness on the TiO2 formation process and the photocatalytic properties were investigated using anodization curves, by using cyclovoltammetry measurements, and by quantifying the generated hydroxyl radicals (OH•) under UV-A irradiation in water. Promising photocatalytic activity and permeability of the nano-TiO2-coated membranes could be demonstrated. A titanium layer of at least 2 µm was necessary for significant photocatalytic effects. The membrane sample with a 10 µm Ti/TiO2 layer had the highest photocatalytic activity showing a formation rate of 1.26 × 10-6 mmol OH• s-1. Furthermore, the membranes were tested several times, and a decrease in radical formation was observed. Assuming that these can be attributed to adsorption processes of the reactants, initial experiments were carried out to reactivate the photocatalyzer.

Investigation of Doehlert matrix conception in novel intrinsically conducting polymers based on selenium nanoparticles for wastewater treatment: Synthesis, characterization, kinetic and chemometric study.

The synthesis of robust intrinsically conducting polymers (ICPs) based on nanoparticles is becoming increasingly attractive to the research community due to the unique properties of these nanocomposites. Indeed, as organic semiconductors, ICPs combine both polymer and metal properties in a single structure. This study presents an innovative approach in which the Doehlert Matrix (DM) is applied to a novel ICP nanocomposite based on polyaniline (Pani) coupled with selenium (Se) loaded mesoporous titania (TiO2) for wastewater treatment by photocatalysis. It includes both the elaboration routes of ICP nanocomposites, characterization of materials by X-ray diffraction (XRD), BET analysis, thermogravimetric analysis (TGA), RAMAN spectroscopy and Fourier transform infrared spectroscopy (FTIR) and photodegradation of methylene blue (MB) as a representative of dye pollutant. In addition, the photocatalytic process has been optimized by a novel DM conception. The effect of the pH of the solution, the catalyst dosage and the initial pollutant concentration was investigated. The optimum conditions were found to be: initial MB concentration of 15 mg/L, the catalyst dosage of 69 mg and pH of 9.6 with an operating time of 75 min, with a coefficient of determination R2 equal to 0.9985. The removal efficiency of BM was close to 97 %. The study shows that the new ICP nanocomposites improve the photocatalytic efficiency compared to pure titania and/or pure Pani. In addition, as the ternary Pani-Se-TiO2 nanocomposite could be obtained from a low-cost synthesis, it is a very promising material for use in wastewater treatment.

Synthesis of magnetic layered double hydroxide (Fe3O4@CuCr-LDH) decorated with ZIF-8 for efficient sonocatalytic degradation of tetracycline.

A series of Fe3O4@CuCr-LDH hybrids decorated with different amount of ZIF-8 (FLZ, 10-40 wt%) was prepared using simple methods and characterized with different techniques. The activity of the synthesized nanocomposites was investigated in the sonocatalytic degradation of tetracycline (TC) antibiotic from wastewater. When the content of ZIF-8 in the nanocomposite structure was 20 wt%, the FLZ-20 sonocatalyst exhibited the high performance in the sonocatalytic removal of TC. At optimum conditions (0.7 g/L catalyst dosage, pH of 7, 50 mg/L initial concentration of antibiotic, and 15 min sonication time) of the sonocatalytic removal of TC approached to 91.4% under ultrasonic irradiation (USI) using FLZ-20. This efficiency was much higher than those of obtained results by Fe3O4@CuCr-LDH and pristine ZIF-8. The formed ●OH and ●O2- exhibited the major roles in the sonocatalytic TC degradation process. The excellent performance of FLZ-20 can be attributed to the heterojunctions created between composite components, which could improve the electron transfer ability and effectively separate e-/h+ pairs. In addition, FLZ-20 showed the superior reusability and stability during three successive recycling. Moreover, the facile magnetically separation of the sonocatalyst from the aqueous solution was another outstanding feature, which prevents the formation of secondary pollutants. It can be concluded that the fabrication of heterojunctions is an efficient procedure to promote the sonocatalytic acting of the catalyst.

Microplastics in wastewater and sludge from centralized and decentralized wastewater treatment plants: Effects of treatment systems and microplastic characteristics.

Domestic wastewater treatment plants (WWTPs) play a vital role in limiting the release of microplastics (MP) into the environment. This study examined MP removal efficiency from five centralized and four decentralized domestic WWTPs in Bangkok, Thailand. MP concentrations in wastewater and sludge were comparable between centralized and decentralized WWTPs, despite these decentralized WWTPs serving smaller populations and having limited treatment capacity. The elimination of MPs ranged from 50 to 96.8% in centralized WWTPs and 14.2-53.6% in decentralized WWTPs. It is noted that the retained MPs concentrations in sludge ranged from 20,000 to 228,100 MP/kg dry weight. The prevalence of synthetic fibers and fragments could be attributed to their pathways from laundry or car tires, and the accidental release of a variety of plastic wastes ended up in investigated domestic WWTPs. Removal of MPs between the centralized and decentralized WWTPs was influenced by several impact factors including initial MP concentrations, longer retention times, MP fragmentation, and variations of MP concentrations in sludge leading to different activated sludge process configurations. Sewage sludge has become a primary location for the accumulation of incoming microplastics in WWTPs. The MPs entering and leaving each unit process were varied due to the unique characteristics of MPs, and their different treatment efficiencies. While the extended hydraulic retention period in decentralized WWTPs decreased the MP removal efficacy, the centralized WWTP with the two-stage activated sludge process achieved the highest MP removal efficiency.

Recent development of substrates for immobilization of bimetallic nanoparticles for wastewater treatment: a review.

Bimetallic nanoparticles (BMNPs) have gained considerable attention due to their remarkable catalytic properties, making them invaluable in wastewater treatment applications. One of these challenges lies in the propensity of BMNPs to aggregate due to Van der Waals interactions, which can reduce their overall performance. Additionally, retrieving exhausted NPs from the treated solution for subsequent reuse remains a significant hurdle. Moreover, the leaching of NPs into the discharged wastewater can have harmful effects on humans as well as aquatic life. To overcome these issues, various substrates have been researched to maximize the efficiency and stability of the NPs. This review paper delves into the pivotal role of various substrates in immobilizing BMNPs, providing a comprehensive analysis of their performances, advantages, and drawbacks. The substrates encompass a diverse range of materials, including organic, inorganic, organic-inorganic, beads, fibers, and membranes. Each substrate type offers unique attributes, influencing the stability, efficiency, and recyclability of BMNPs. This review paper aims to provide an up-to-date and detailed analysis and comparison of the substrates used for the immobilization of BMNPs. This work further reviews the underlying mechanisms of the composites involved in treating pollutants from wastewater and how these mechanisms are enhanced by the synergistic effects produced by the substrate and BMNPs. Furthermore, the reusability and sustainability of these composites are discussed. Also, high-performing substrates are highlighted to give direction to future research focusing on the immobilization of BMNPs in the application of wastewater treatment.

Potential for curdlan recovery from aerobic granular sludge wastewater treatment systems - A review.

The aerobic granular sludge (AGS) biotechnology has been explored for wastewater treatment for over two decades. AGS is gaining increased interest due to its enhanced treatment performance ability and the potential for resource recovery from AGS-based wastewater treatment systems. Resource recovery from AGS is a promising approach to sustainable wastewater treatment and attaining a circular economy in the wastewater management industry. Currently, research is at an advanced stage on recovering value-added resources such as phosphorus, polyhydroxyalkanoates, alginate-like exopolysaccharides, and tryptophan from waste aerobic granules. Recently, other value-added resources, including curdlan, have been identified in the aerobic granule matrix, and this may increase the sustainability of biotechnology in the wastewater industry. This paper provides an overview of current AGS biosolids management practices and resource recovery potential. In particular, the potential for enhanced curdlan biosynthesis in the granule matrix and its recovery from AGS wastewater treatment systems is outlined.

Produced water treatment by semi-continuous sequential bioreactor and microalgae photobioreactor.

Produced water (PW) from oil and gas exploration adversely affects aquatic life and living organisms, necessitating treatment before discharge to meet effluent permissible limits. This study first used activated sludge to pretreat PW in a sequential batch reactor (SBR). The pretreated PW then entered a 13 L photobioreactor (PBR) containing Scenedesmus obliquus microalgae culture. Initially, 10% of the PW mixed with 90% microalgae culture in the PBR. After the exponential growth of the microalgae, an additional 25% of PW was added to the PBR without extra nutrients. This study reported the growth performance of microalgae in the PBR as well as the reduction in effluent's total organic carbon (TOC), total dissolved solids (TDS), electrical conductivity (EC), and heavy metals content. The results demonstrated removal efficiencies of 64% for TOC, 49.8% for TDS, and 49.1% for EC. The results also showed reductions in barium, iron, and manganese in the effluent by 95, 76, and 52%, respectively.

High-performance activation of ozone by sonocavitation for BTEX degradation in water.

This work presents a novel advanced oxidation process (AOP) for degradation of emerging organic pollutants - benzene, toluene, ethylbenzene and xylenes (BTEXs) in water. A comparative study was performed for sonocavitation assisted ozonation under 40-120 kHz and 80-200 kHz dual frequency ultrasounds (DFUS). Based on the obtained results, the combination of 40-120 kHz i.e., low-frequency US (LFDUS) with O3 exhibited excellent oxidation capacity degrading 99.37-99.69% of BTEXs in 40 min, while 86.09-91.76% of BTEX degradation was achieved after 60 min in 80-200 kHz i.e., high-frequency US (HFDUS) combined with O3. The synergistic indexes determined using degradation rate constants were found as 7.86 and 2.9 for LFDUS/O3 and HFDUS/O3 processes, respectively. The higher extend of BTEX degradation in both processes was observed at pH 6.5 and 10. Among the reactive oxygen species (ROSs), hydroxyl radicals (HO•) were found predominant according to scavenging tests, singlet oxygen also importantly contributed in degradation, while O2•- radicals had a minor contribution. Sulfate (SO42-) ions demonstrated higher inhibitory effect compared to chloride (Cl-) and carbonate (CO32-) ions in both processes. Degradation pathways of BTEX was proposed based on the intermediates identified using GC-MS technique.

Animal waste as a valuable biosorbent in the removal of heavy metals from aquatic ecosystem-an eco-friendly approach.

Toxic pollutants in the form of heavy metals are added through various anthropogenic activities daily into the aquatic ecosystem beyond their permissible limits, and their bioaccumulation capacity makes them hazardous substances for the survival of all organisms. Thus, their removal from aquatic ecosystems is the need of the hour. Treatment of wastewater containing heavy metals through biosorption is gaining popularity and is being explored all around the world due to its various advantages over conventional methods of treatment. Utilization of animal waste as a biomaterial could be the best solution to remove it from the ecosystem. Such treatment methods are a blessing for developing and underdeveloped countries due to their low cost. This paper provides in-depth details about heavy metals, their health implications, mechanisms of toxicity, modes of transportation, and conventional treatment approaches. A comprehensive understanding of the biosorption process, encompassing its world scenario, evolution, mechanisms, factors affecting the process, and advantages, will also be covered. Finally, animal wastes and their applicability in the removal of heavy metal pollutants from wastewater shall also be thoroughly reviewed, followed by their future utility and recommendations.

A fast microbial nitrogen-assimilation technology enhances nitrogen migration and single-cell-protein production in high-ammonia piggery wastewater.

Conventional methods, such as freshwater dilution and ammonia stripping, have been widely employed for microalgae-based piggery wastewater (PW) treatment, but they cause high freshwater consumption and intensive ammonia loss, respectively. This present work developed a novel fast microbial nitrogen-assimilation technology by integrating nitrogen starvation, zeolite-based adsorption, pH control, and co-culture of microalgae-yeast for the PW treatment. Among them, the nitrogen starvation accelerated the nitrogen removal and shortened the treatment period, but it could not improve the tolerance level of microalgal cells to ammonia toxicity based on oxidative stress. Therefore, zeolite was added to reduce the initial total ammonia-nitrogen concentration to around 300 mg/L by ammonia adsorption. Slowly releasing ammonia at the later phase maintained the total ammonia-nitrogen concentration in the PW. However, the pH increase could cause lots of ammonia loss air and pollution and inhibit the desorption of ammonia from zeolite and the growth and metabolism of microalgae during the microalgae cultivation. Thus, the highest biomass yield (3.25 g/L) and nitrogen recovery ratio (40.31%) were achieved when the pH of PW was controlled at 6.0. After combining the co-cultivation of microalgae-yeast, the carbon-nitrogen co-assimilation and the alleviation of pH fluctuation further enhanced the nutrient removal and nitrogen migration to high-protein biomass. Consequently, the fast microbial nitrogen-assimilation technology can help update the industrial system for high-ammonia wastewater treatment by improving the treatment and nitrogen recovery rates.

Sequential high-recovery nanofiltration and electrochemical degradation for the treatment of pharmaceutical wastewater.

The presence of antibiotics in aquatic ecosystems poses a significant concern for public health and aquatic life, owing to their contribution to the proliferation of antibiotic-resistant bacteria. Effective wastewater treatment strategies are needed to ensure that discharges from pharmaceutical manufacturing facilities are adequately controlled. Here we propose the sequential use of nanofiltration (NF) for concentrating a real pharmaceutical effluent derived from azithromycin production, followed by electrochemical oxidation for thorough removal of pharmaceutical compounds. The NF membrane demonstrated its capability to concentrate wastewater at a high recovery value of 95 % and 99.7 ± 0.2 % rejection to azithromycin. The subsequent electrochemical oxidation process completely degraded azithromycin in the concentrate within 30 min and reduced total organic carbon by 95 % in 180 min. Such integrated treatment approach minimized the electrochemically-treated volume through a low-energy membrane approach and enhanced mass transfer towards the electrodes, therefore driving the process toward zero-liquid-discharge objectives. Overall, our integrated approach holds promises for cost-effective and sustainable removal of trace pharmaceutical compounds and other organics in pharmaceutical wastewater.

Performance of magnetic nanocomposite based on Xanthan gum- grafted -poly(acrylamide) crosslinked borax for the effective elimination of amoxicillin from an aquatic environment.

This study evaluated the effectiveness of using nanocomposite (NCs) of xanthan gum grafted polyacrylamide crosslinked Borax - iron oxide nanoparticle (XG-g-pAAm-CL-Borax-IONP) to remove the amoxicillin antibiotic (AMX) from an aquatic environment. To confirm the structural characteristics of the prepared XG-g-pAAm-CL-Borax-IONP NCs, unique characterization methods (XRD, FT-IR, FE-SEM, EDX, BET, TGA, Zeta, and VSM) were used. Adsorption experimental setups were performed with the influence of solution pH (4-9), the effect of adsorbent dose (0.003-0.02 g), the effect of contact time (5-45 min), and the effect of initial AMX concentration (50-400 mg/L) to achieve the most efficient adsorption conditions. Based on the Freundlich isotherm model, XG-g-pAAm-CL-Borax-IONP NCs provided the maximum AMX adsorption capacity of 1183.639 mg/g. This research on adsorption kinetics also established that the pseudo-second-order model (R2= 0.991) is outstanding compatibility with the experimental results. AMX adsorption on the NCs may occur through intermolecular hydrogen bonding, diffusion, and trapping into the polymer network. Even after five cycles, these NCs still displayed the best performance. Based on these results, XG-g-pAAm-CL-Borax-IONP NCs may be a viable material for the purification of AMX from contaminated water.

Chlorella vulgaris-mediated bioremediation of food and beverage wastewater from industries in Mexico: Results and perspectives towards sustainability and circular economy.

The food and beverage industries in Mexico generate substantial effluents, including nejayote, cheese-whey, and tequila vinasses, which pose significant environmental challenges due to their extreme physicochemical characteristics and excessive organic load. This study aimed to assess the potential of Chlorella vulgaris in bioremediating these complex wastewaters while also producing added-value compounds. A UV mutagenesis treatment (40 min) enhanced C. vulgaris adaptability to grow in the effluent conditions. Robust growth was observed in all three effluents, with nejayote identified as the optimal medium. Physicochemical measurements conducted pre- and post-cultivation revealed notable reductions of pollutants in nejayote, including complete removal of nitrogen and phosphates, and an 85 % reduction in COD. Tequila vinasses exhibited promise with a 66 % reduction in nitrogen and a 70 % reduction in COD, while cheese-whey showed a 17 % reduction in phosphates. Regarding valuable compounds, nejayote yielded the highest pigment (1.62 mg·g-1) and phenolic compound (3.67 mg·g-1) content, while tequila vinasses had the highest protein content (16.83 %). The main highlight of this study is that C. vulgaris successfully grew in 100 % of the three effluents (without additional water or nutrients), demonstrating its potential for sustainable bioremediation and added-value compound production. When grown in 100 % of the effluents, they become a sustainable option since they don't require an input of fresh water and therefore do not contribute to water scarcity. These findings offer a practical solution for addressing environmental challenges in the food and beverage industries within a circular economy framework.

Assessing nitrous oxide emissions from algal-bacterial photobioreactors devoted to biogas upgrading and digestate treatment.

Nitrous oxide (N2O) emissions in High Rate Algal Ponds (HRAP) can negatively affect the sustainability of algal-bacterial processes. N2O emissions from a pilot HRAP devoted to biogas upgrading and digestate treatment were herein monitored for 73 days. The influence of the pH (7.5, 8.5, and 9.5), nitrogen sources (100 mg/L of N-NO2-, N-NO3-, and N-NH4+) and illumination on N2O emissions from the algal-bacterial biomass of the HRAP was also assessed in batch tests. Significantly higher N2O gas concentrations of 311.8 ± 101.1 ppmv were recorded in the dark compared to the illuminated period (236.9 ± 82.6 ppmv) in the HRAP. The batch tests revealed that the highest N2O emission rates (49.4 mmol g-1 TSS·h-1) occurred at pH 8.5 in the presence of 100 mg N-NO2-/L under dark conditions. This study revealed significant N2O emissions in HRAPs during darkness.

Carbon performance analysis of upgraded wastewater treatment plants in key control areas of the Ziya River Basin in China.

Wastewater treatment plants (WWTPs) are one of the largest sources of greenhouse gas (GHG) emissions, and they are also one of the largest energy consumption industries in urban systems. With the progression of upgrading and standard-rising, WWTPs both directly and indirectly increase carbon emissions from the increased investments in facilities and usages in electricity as well as chemical agents. Here, we collected operational data from 15 WWTPs in the key control areas of the Ziya River Basin in North China and accounted for the changes in carbon performance at different technical upgrade methods. Results showed that the average carbon emission performance increased by 0.487 kg CO2/m3 after the upgrade. Carbon emissions from electricity consumption, chemical usage, biochemical process and sludge treatment accounted for 42%, 17%, 24%, and 17% of the total improvement in carbon emission performance, respectively. Reducing energy consumption, regulating chemical use and sludge comprehensive utilization are the key to carbon emission reduction. It further proposes that the development of wastewater treatment discharge standards should fully consider the comprehensive utilization of water quality classification. Regions with favorable natural conditions should make full use of their advantages by adopting economically feasible, low-energy-consuming technologies such as constructed wetlands, which offer carbon sequestration and landscaping benefits. This study provides guidance on the selection of technological pathways for pollution reduction and carbon mitigation in the wastewater treatment industry and on achieving sustainable water resource utilization.

Use of recycled construction and demolition waste as substrate in constructed wetlands for the wastewater treatment of cheese production.

Recycled building debris has recently emerged as a suitable wetland infill substrate due to its low density, exceptional water absorption capabilities, and high porosity. This study investigated, for the first time, the use of construction demolition wastes (CDW), and rock processing residues (RPR) as substrate materials in vertical-horizontal flow hybrid constructed wetlands for the treatment of cheese production wastewater. Results showed that the use of both CDW as well as RPR, as substrate material, provided an equal or even better quality of treated wastewater compared to the conventional use of gravel as a substrate. High removal efficiencies were recorded for turbidity (CDW: 91-92%, RPR: 97%), solids (CDW: 85-88%, RPR: 96-97%), organic matter (CDW: 79-84%, RPR: 96-98%), and total phosphorus (CDW: 72-76%, RPR: 87%) for both examined recycled materials. During the experiment, different loadings rates (HLR) were tested: 25 mm d-1 and 37.5 mm d-1. Radiological measurements indicate that, their use did not cause toxic effects on the environment, as the amounts of radioactivity found in the effluent of the systems are not significant. Increasing the hydraulic loading rate appeared to have no negative effect on pollutant removal, as the systems and plants were fully acclimated and mature. This approach offers several advantages, including the use of readily available and abundant waste material, potential cost savings, and the environmental benefits of recycling CDW and RPR instead of disposing of them in landfills.

Effect of microalgae and bacteria inoculation on the startup of bioreactors for paper pulp wastewater and biofuel production.

The use of microalgae and bacteria as a strategy for the startup of bioreactors for the treatment of industrial wastewater can be a sustainable and economically viable alternative. This technology model provides satisfactory results in the nitrification and denitrification process for nitrogen removal, organic matter removal, biomass growth, sedimentation, and byproducts recovery for added-value product production. The objective of this work was to evaluate the performance of microalgae and bacteria in their symbiotic process when used in the treatment of paper pulp industry wastewater. The experiment, lasting fourteen days, utilized four bioreactors with varying concentrations in mgVSS/L of microalgae to bacteria ratio (R1-100:100, R2-100:300, R3-100:500, R4-300:100) in the startup process. Regarding the sludge volumetric index (SVI), the results show that the R1 and R2 reactors developed SVI30/SVI10 biomass in the range of 85.57 ± 7.33% and 84.72 ± 8.19%, respectively. The lipid content in the biomass of reactors R1, R2, R3 e R4 was 13%, 7%, 19%, and 22%, respectively. This high oil content at the end of the batch, may be related to the nutritional stress that the species underwent during this feeding regime. In terms of chlorophyll, the bioreactor with an initial inoculation of 100:100 showed better symbiotic growth of microalgae and bacteria, allowing exponential growth of microalgae. The total chlorophyll value for this bioreactor was 801.46 ± 196.96 µg/L. Biological removal of nitrogen from wastewater from the paper pulp industry is a challenge due to the characteristics of the effluent, but the four reactors operated in a single batch obtained good nitrogen removal. Ammonia nitrogen removal performances were 91.55 ± 9.99%, 72.13 ± 19.18%, 64.04 ± 21.34%, and 86.15 ± 30.10% in R1, R2, R3, and R4, respectively.

Novel polyarylether nitrile/layered bimetallic oxide/2-Methylimidazole composite membrane for efficient synergistic adsorption and degradation of organic pollutants under visible light.

The difficulty of recycling and the finite photocatalytic performance of primitive nano-photocatalysts restrict their application in wastewater purification. In this study, a multifunctional membrane with efficient synergistic adsorption and degradation performance was constructed. The nano-photocatalyst layered bimetallic oxide (LDO) was combined with the matrix membrane polyarylether nitrile (PEN) by delayed phase transition technology. The introduced 2-Methylimidazole (2-MeIm) provided a virtual electron transfer pathway between PEN and LDO and enhanced the photocatalytic performance. The results suggested that PEN/LDO/2-MeIm has outstanding removal performance to organic dyes methylene blue (MB). After three consecutive cycles, the reacted membrane can be readily recovered from the system. The MB removal rate remained high at 89.38%, suggesting that the functional membrane is eligible for recycling and reuse. Finally, based on liquid chromatography-mass spectrometry (LC-MS) analysis and density functional theory (DFT) calculations, the mechanism and pathway of MB photodegradation by the PEN/LDO/2-MeIm system were proposed. Therefore, constructing PEN/LDO/2-MeIm membranes in this study may offer a novel perspective on creating eco-friendly and functional PEN-based membranes for practical use in wastewater purification.

Comprehensive study on the selection and performance of the best electrode pair for electrocoagulation of textile wastewater using multi-criteria decision-making methods (TOPSIS, VIKOR and PROMETHEE II).

The accelerating environmental impact of the textile industry, especially in water management, requires efficient wastewater treatment strategies. This study examines the effectiveness of various electrode pairs in the Electrocoagulation (EC) process for treating textile wastewater, focusing on removing of Total Suspended Solids (TSS), turbidity, Chemical Oxygen Demand (COD), and Total Organic Carbon (TOC). A comprehensive analysis was conducted using thirty-six electrode pair combinations, consisting of six materials: Aluminium (Al), Zinc (Zn), Carbon (C), Copper (Cu), Mild Steel (MS), and Stainless Steel (SS). The results demonstrated that different electrode pairs yielded varying removal efficiencies for various pollutants, with the highest efficiencies being 92.09% for COD (Al-C pair), 99.66% for TSS (Al-Cu pair), 99.17% for turbidity (Al-MS pair), and 70.99% for TOC (SS-SS pair). However, no single electrode pair excelled in removing all pollutant categories. To address this, three Multi-Criteria Decision Making (MCDM) methods such as TOPSIS, VIKOR, and PROMETHEE II were used to assess the most effective electrode pair. The results indicated that the Al-Zn combination was the most efficient, exhibiting high removal efficiencies for various pollutants (99.32% for TSS, 98.88% for turbidity, 68.62% for COD, and 57.96% for TOC). This study demonstrates that the EC process can effectively treat textile effluent and emphasizes the importance of selecting suitable electrode materials. Furthermore, pollutant removal was optimal with the Al-Zn electrode pair, offering a balanced and efficient approach to textile wastewater treatment. Thus, MCDM methods offer a robust framework for assessing and optimizing electrode selection, providing valuable insights for sustainable environmental management practices.