Effect of Post-Processing Heat Treatment on Micro-Contact Damage of Zirconia-Reinforced Lithium Silicate Dental Materials.

Zirconia-reinforced lithium silicate (ZLS) is utilized as a material for prosthetic tooth crowns, offering enhanced strength compared to other dental glass-ceramics. In this study, we investigate a commercial ZLS material, provided in a fully crystallized form. We examine the effects of an optional post-processing heat treatment on micro-contact damage using controlled indentation tests simulating the primary modes of contact during chewing: axial and sliding. Our findings indicate that the heat treatment does not affect mechanical properties such as the elastic modulus, hardness and indentation fracture toughness. However, it does enhance the resistance to contact damage by fracture and chipping in both axial and sliding modes, as well as the resistance to crack initiation measured from sliding tests. This improvement is attributed to the refinement of the flaw population achieved through the heat treatment. The results are analysed using principles of contact and fracture mechanics theory, discussing their significance in prosthetic dentistry.

Fracture resistance of Ceramic-Polymer hybrid materials using microscopic finite element analysis and experimental validation.

The objective of this paper is to elucidate the response to contact stresses of Polymer Infiltrated Ceramic Network (PICN) using the microscopic viscoplastic finite elements, validated by clinically relevant in vitro tests. A feldspathic ceramic material, namely Vita Mark II, is an interconnected structure infiltrated with the polymer (PMMA). Axisymmetric finite element microstructure models are reconstructed from two-dimensional images of a PICN microstructure. Viscoplastic finite element analysis (FEA) with various degrees of microscopic damages occurring over contact is performed. The force-displacement responses obtained from FEA are validated with Hertzian contact tests. Finite element results for force-displacement, stresses and strains in each phase are discussed. We hypothesize that the resistance to fracture of PICN can be further improved by microstructural tailoring. The experimental evidence suggests that a composite material is both more resistant to displacement under load and more resistant to crack initiation and propagation, as hypothesized. Further parametric study on the effects of various volume fractions of two phases in PICN is done to provide some insight on increased contact damage resistance of PICN as well as potential optimization of microstructures.

Microstructure and Fracture Mechanism Investigation of Porous Silicon Nitride-Zirconia-Graphene Composite Using Multi-Scale and In-Situ Microscopy.

Silicon nitride-zirconia-graphene composites with high graphene content (5 wt.% and 30 wt.%) were sintered by gas pressure sintering (GPS). The effect of the multilayer graphene (MLG) content on microstructure and fracture mechanism is investigated by multi-scale and in-situ microscopy. Multi-scale microscopy confirms that the phases disperse evenly in the microstructure without obvious agglomeration. The MLG flakes well dispersed between ceramic matrix grains slow down the phase transformation from α to ß-Si3N4, subsequent needle-like growth of ß-Si3N4 rods and the densification due to the reduction in sintering additives particularly in the case with 30 wt.% MLG. The size distribution of Si3N4 phase shifts towards a larger size range with the increase in graphene content from 5 to 30 wt.%, while a higher graphene content (30 wt.%) hinders the growth of the ZrO2 phase. The composite with 30 wt.% MLG has a porosity of 47%, the one with 5 wt.% exhibits a porosity of approximately 30%. Both Si3N4/MLG composites show potential resistance to contact or indentation damage. Crack initiation and propagation, densification of the porous microstructure, and shift of ceramic phases are observed using in-situ transmission electron microscopy. The crack propagates through the ceramic/MLG interface and through both the ceramic and the non-ceramic components in the composite with low graphene content. However, the crack prefers to bypass ceramic phases in the composite with 30 wt.% MLG.