Bibliometric analysis of global performance and trends of research on combined sewer overflows (CSOs) from 1990 to 2022.

Combined sewer overflows (CSOs) are one of the main sources of pollution in urban water systems and significantly impede the restoration of water body functionalities within urban rivers and lakes. To understand the research and frontier trends of CSOs comprehensively and systematically, a visual statistical analysis of the literature related to CSOs in the Web of Science core database from 1990 to 2022 was conducted using the bibliometric method using HistCite Pro and VOSviewer. The results reveal a total of 1,209 pertinent publications related to CSOs from 1990 to 2022, and the quantity of CSOs-related publications indicated an increasing trend. Investigations of the distribution and fate of typical pollutants in CSOs and their ecological effects on receiving waters and studies on pollution control technologies (source reduction, process control, and end-of-pipe treatment) are the current focus of CSOs research. CSOs pollution control technologies based on source reduction and the monitoring and control of emerging contaminants are at the forefront of scientific investigations on CSOs. This study systematically and comprehensively summarized current research topics and future research directions of CSOs, thus providing a reference for CSOs control and water environment management research.

Storm-induced nitrogen transport via surface runoff, interflow and groundwater in a pomelo agricultural watershed, southeast China.

The storm-induced export of nitrogen (N) from agricultural watersheds significantly impacts aquatic ecosystems, yet the mechanisms of source supply and transport behind N species remain unclear. Here, we investigated the hydrological factors influencing the timing and magnitude of river N species export in a Chinese pomelo agricultural watershed. We conducted continuous observations of watershed hydrology, N species, and their isotopic ratios along a soil-groundwater-river continuum during two storm events in 2018-2019. We found the export flux of river NO3-N covers ∼80% of the total N flux during storms, and the rest for other N species. Our results further revealed distinct pathways and timing of N transport among different N species, especially between ammonium N (NH4-N) and nitrate N (NO3-N). NH4-N in stormflow predominantly originates from sewage and soil leachate, rapidly transported via surface runoff and interflow. Orchard fertilization (contributed 41-56% based on SIAR analysis) was the major source of river NO3-N, which underwent initial dilution via surface runoff and subsequently became enriched through delayed discharge of soil leachate and groundwater. The variations in timing and magnitude of N transport between storms can be explained by antecedent conditions such as precipitation, soil N pools, and storm size. These findings emphasize the hydrological controls on N export from agricultural watersheds, and highlight the variations in source supply and transport pathways among different N species. The insights gained from this study hold significance for managing agricultural pollution and restoring impaired aquatic systems.

The storm runoff management strategy based on agricultural ditch nutrient loss characteristics in Erhai Lake, China.

Initial flush management is an effective measure to control non-point source pollution (NPSP) in storm runoff. However, determining the parameter of the initial flush in different areas may pose challenges in storm runoff management strategies. To address this issue, Erhai Lake in China, Yunnan-Guizhou Plateau, was selected as an example for the study. Erhai Lake is a typical mesotrophic lake with the profound influence of NPSP. The NPSP control strategy in this area will provide a valuable reference for other lakes. In 2021, 289 storm events and 190 ditchwater samples were detected around Erhai Lake. The average flow in the ditches ranged from 0.004 to 0.147 m3/s, the instant total nitrogen (TN) concentration ranged from 0.28 to 91.43 mg/L, and the instant total phosphorus (TP) concentration ranged from 0.26 to 7.35 mg/L in the storm events. It was found that the concentration of pollutants was lower than expected in the initial flush period. Instead, the event mean concentrations of TN and TP were 9.3 and 2.1 times higher than in the wet seasons, showing high nutrient concentration levels throughout the entire rainfall period. To manage storm runoff effectively, a flow-processes-division method was proposed to analyze the inflow condition and pollutant removal rate in different runoff periods. The peak flow interception strategy was recommended as the optimal stormwater management plan, as it showed the highest inflow conditions and 50% pollutant removal rate. Considering the need to reduce the constant flush of stormwater runoff, it is essential to establish a healthy water cycle system to alleviate NPSP and raise the Erhai water level. The storm runoff management method can serve as a practical tool for lake areas that do not exhibit initial flush characteristics.

Effects of storm runoff on the spatial-temporal variation and stratified water quality in Biliuhe Reservoir, a drinking water reservoir.

Stormflow runoff is an important non-point source of pollution in drinking water reservoirs. Storm runoff is usually very turbid and contains a high concentration of organic matter, therefore affecting water quality when it enters reservoirs. In order to investigate the impact of storm runoff on spatial-temporal variation and stratification of water quality during this rainstorm event, the inflow process of the storm runoff was studied through a combination of field investigation and simulation using the Delft3D-Flow model. Water samples were collected from Biliuhe Reservoir at four different periods: before storm runoff, storm runoff flood peak period, 1 week after storm runoff, and 5 weeks after storm runoff. The results showed that the input of storm runoff resulted in a significant increase in the nitrogen (N) and phosphorus (P) in the reservoir water, especially in the reservoir entrance. The concentrations of total nitrogen (TN) and total phosphorus (TP) gradually decreased after the flood peak period; however, the average concentrations of TN and TP in the entire reservoir remained higher than those before the storm runoff levels for an extended duration. The storm runoff will greatly contribute to the contamination of water quality in a reservoir, and the water quality cannot be quickly restored by self-purification in the short term. During the flood peak period, under the influence of density current, the electrical conductivity (EC) and turbidity increased significantly in the water depth of 10-15 m, so that the reservoir water had obvious stratification between 10 and 15 m. The form of pollutants in storm runoff was mostly in particle phosphorus. Total particulate phosphorus (TPP) concentration was 0.015 ± 0.011 mg/L, accounting for 44.12% of total phosphorus (TP) concentration in storm runoff flood peak period. The process of a rainstorm caused runoff, which carried high levels of turbidity, particulate phosphorus, and organic matter. The storm runoff disrupts the stratification of the reservoir water. In terms of vertical distribution, the turbidity in the reservoir area increased to 73.75 NTU. Therefore, the occurrence of significant turbidity density flow in the reservoir is frequently accompanied by intense rainfall events. Gaining insights into the impact of storm runoff on the vertical distribution of reservoir turbidity can help managers in selecting an appropriate inlet height to mitigate high turbidity outflow.

Spatial analysis of future climate risk to stormwater infrastructure.

Climate change is expected to result in more intense precipitation events that will affect the performance and design requirements of stormwater infrastructure. Such changes will vary spatially, and climate models provide a range of estimates of the effects on events of different intensities and recurrence. Infrastructure performance should be evaluated against the expected range of events, not just rare extremes. We present a national-scale, spatially detailed screening assessment of the potential effects of climatic change on precipitation, stormwater runoff, and associated design requirements. This is accomplished through adjustment relative to multiple future climate scenarios of precipitation intensity-duration-frequency analyses presented in NOAA Atlas 14, which are commonly used in infrastructure design. Future precipitation results are estimated for each Atlas 14 station (these currently omit the Pacific Northwest). Results are interpolated using a geographically conditioned regression kriging approach to provide information about potential climate change impacts in a format more directly useful to local stormwater managers. The intensity of 24-h events with 2-year or greater recurrence is likely to increase in most areas of the United States leading to increased runoff and potential need for increased storage volumes. Changes in more frequent events (e.g., the 90th percentile event) commonly used in design of green infrastructure are relatively less.

Studying the combined influence of microplastics' intrinsic and extrinsic characteristics on their weathering behavior and heavy metal transport in storm runoff.

The weathering and contaminant transport behavior of both primary (PMPs) and secondary microplastics (SMPs) are interrelated to their original physiochemical features and variations within the environment. This study examines the influence of PMPs' intrinsic characteristics (polymer structure and crystallinity) and SMPs' extrinsic features (surface oxidation and external sediments attachment) on the photodegradation kinetics, and subsequently Pb(II) and Zn(II) uptake from stormwater. For this purpose, high density polyethylene (HDPE) and low density polyethylene (LDPE) with different degrees of crystallinities were produced as PMPs, and their photodegradation behaviors were compared with original polymers. Furthermore, the SMPs generated by abrasion and surface oxidation of PMPs and the virgin PMPs underwent accelerated photodegradation, and the changes of their crystallinity, surface chemistry, and morphology were examined. Scanning electron microscopy (SEM) imaging and X-ray photoelectron (XPS) studies revealed the formation of cracks and different oxidized functionalities on MPs surface due to UV photodegradation. The vinyl and carbonyl indices calculated using Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy demonstrated an elevated photodegradation rate for SMPs compared to the PMPs. Moreover, the Differential Scanning Colorimetry (DSC) demonstrated an increasing percentage of crystallinity in all MPs due to the photodegradation. The percent crystallinity of HDPE pellets increased after photodegradation from 49.8 to 62.6 and it increased from 17.2 to 38.9 for LDPE pellets respectively. The greater level of increase in crystallinity for LDPE in comparison to HDPE upon photodegradation was referred to as LDPE's greater amorphous content and branched structure. A greater level of metal uptake was obtained for photodegraded LDPE pellets as 2526 µg/m2 for Pb(II) and 2028 µg/m2 for Zn(II) respectively.

Determining nitrate sources in storm runoff in complex urban environments based on nitrogen and oxygen isotopes.

Urban storm runoff, as the primary transport medium for nutrients entering urban rivers, contributes to urban water contamination. Accurate source identification is critical for controlling water pollution. Although some studies have used nitrate isotopic composition (δ15N-NO3- and δ18O-NO3-) to identify nitrate (NO3--N) in urban storm runoff, the relatively low frequency of collecting samples in surface runoff within a single functional area hinders the understanding of spatial variations and dynamic process of NO3--N sources over the runoff process. This study investigated the nitrogen (N) concentrations and analyzed dynamic changes of NO3--N sources in surface runoff in different urban functional areas, drainage pipeline runoff, and channels during the complete runoff process in Wuxi, east China. The results showed that N concentrations in pipeline runoff and channels were higher than those in surface runoff, indicating that high concentration of N pollutants were accumulated in drainage pipelines. Information of δ15N-NO3- and δ18O-NO3- suggested that the main NO3--N source varied between runoff stages. NO3--N contribution from atmospheric deposition decreased in the order: surface runoff (57%) > residential pipeline runoff (25%) > channels (14%), while the opposite trend was observed for the contributions from sewage, increasing from 10%, 26% to 39%. In urban storm runoff, more sewage, fertilizers, and soil N were carried into the surface runoff after 30% of cumulative runoff ratio and carried into pipeline runoff in the initial 25% of cumulative runoff ratio in the residential area. As the first attempt to identify nitrate sources over the cumulative runoff in different urban functional areas, this work expands our understanding of the primary nitrate source in urban storm runoff. The findings provide important insights for developing strategies to mitigate non-point source water pollution.

[Influence of Storm Runoff on the Spectral Characteristics of Dissolved Organic Matter (DOM) in a Drinking Water Reservoir During the Flood Season].

To explore the influence of storm runoff on reservoir organic matter during the flood season, the Lijiahe Reservoir was selected to analyze variations in the content and components of dissolved organic matter (DOM) during four periods (before runoff, flood peak period, 1 week after runoff, and 6 weeks after runoff) using three-dimensional fluorescence spectroscopy parallel factor analysis (EEMs-PARAFAC) and ultraviolet-visible (UV-Vis) spectra. The results showed that:① the turbidity and DOC content of the reservoir increased significantly during the flood peak period (P<0.01) and gradually decreased thereafter; ② the UV-Vis spectrum characteristics showed that a(254) and a(355) were significantly increased in the flood peak period (P<0.01) while E2/E3 and E3/E4 were significantly decreased (P<0.01), indicating that the concentration, relative molecular weight, and degree of DOM humification in the reservoir were increased by storm runoff; ③ four DOM components were identified as terrestrial humus (C1 and C2), microbial humus (C3), and a tryptophan-like component (C4). The fluorescence intensity of the C1-C3 components increased significantly during the flood peak period (P<0.05), indicating that the increase in the DOM humic-like component was caused by the storm runoff. At the same time, a decrease in the fluorescence intensity of the C1-C4 components was observed after the flood peak period, indicating that DOM continuously settled and degraded after runoff; and ④ Pearson's correlation analyses showed that DOM fluorescence intensity and turbidity were significantly correlated (r>0.467, P<0.05), indicating that the observed decrease in DOM content was related to the sedimentation of suspended solids. A principal component analysis (PCA) showed that the water quality in the reservoir reflected the observed characteristics during the different runoff periods. Overall, this study reveals the effects of the storm runoff on DOM content and its components over the short and long term, providing scientific support for the management of drinking water quality.

Co-designed Land-use Scenarios and their Implications for Storm Runoff and Streamflow in New England.

Landscape and climate changes have the potential to create or exacerbate problems with stormwater management, high flows, and flooding. In New England, four plausible land-use scenarios were co-developed with stakeholders to give insight to the effects on ecosystem services of different trajectories of socio-economic connectedness and natural resource innovation. With respect to water, the service of greatest interest to New England stakeholders is the reduction of stormwater and flooding. To assess the effects of these land-use scenarios, we applied the Soil and Water Assessment Tool to two watersheds under two climates. Differences in land use had minimal effects on the water balance but did affect high flows and the contribution of storm runoff to streamflow. For most scenarios, the effect on high flows was small. For one scenario-envisioned to have global socio-economic connectedness and low levels of natural resource innovation-growth in impervious areas increased the annual maximum daily flow by 10%, similar to the 5-15% increase attributable to climate change. Under modest population growth, land-use decisions have little effect on storm runoff and high flows; however, for the two scenarios characterized by global socio-economic connectedness, differences in choices regarding land use and impervious area have a large impact on the potential for flooding. Results also indicate a potential interaction between climate and land use with a shift to more high flows resulting from heavy rains than from snowmelt. These results can help inform land use and development, especially when combined with assessments of effects on other ecosystem services.

[Migration Characteristics of Manganese During Rainfall Events and Its Impacts on Water Quality in a Drinking Water Source Reservoir].

In view of the problem of excessive manganese concentrations in the Xi'an Jinpen Reservoir during the flood season in 2017, the vertical distribution of manganese in density currents and its occurrence pattern were monitored at multiple monitoring sections along the upstream reaches to the main basin. The influences of density currents plunging into the reservoir on the migration and transformation of Mn were studied, and sedimentation, output, and deposition of manganese in the reservoir water were also specifically estimated during a single, typical storm runoff process. Devices for avoiding high turbidity and high load inflows in rainfall events were proposed. The results showed that significant increases of total manganese were induced by high-turbidity inflows, which largely degraded water quality during rainfall events. From 12 to 14 October, 9.11 tons of total manganese were transported into the reservoir during a single rainfall event, and the pollution conditions were largely remitted by flood discharges with an output of 6.22 tons; thus, the net deposition (manganese) was 1.47 tons. The manganese content and morphological changes along the upper reaches of the reservoir indicated that soil erosion occurred during the continuous rainfall process, and this caused a large amount of particulate pollutants to flow into the water body with the runoff. More than 70% of the total manganese in the water was in the iron-manganese oxide bound state. Correlation analysis was conducted with particles of different particle size ranges, and granular manganese particle sizes were about 2-20 µm. The findings indicate that when flood discharges with turbidity currents occur, this can effectively reduce the load of pollutants and the safety risks of water.

Water quality characterization of storm and irrigation runoff from a container nursery.

Commercial nurseries grow specialty crops for resale using a variety of methods, including containerized production, utilizing soilless substrates, on a semipervious production surface. These "container" nurseries require daily water application and continuous availability of mineral nutrients. These factors can generate significant nutrients [total nitrogen (TN), and total phosphorus (TP)] and sediment [total suspended solids (TSS)] in runoff, potentially contributing to eutrophication of downstream water bodies. Runoff is collected in large ponds known as tailwater recovery basins for treatment and reuse or discharge to receiving streams. We characterized TSS, TN, and TP, electrical conductivity (EC), and pH in runoff from a 5.2 ha production portion of a 200-ha commercial container nursery during storm and irrigation events. Results showed a direct correlation between TN and TP, runoff and TSS, TN and EC, and between flow and pH. The Storm Water Management Model (SWMM) was used to characterize runoff quantity and quality of the site. We found during irrigation events that simulated event mean concentrations (EMCs) of TSS, TN, and TP were 30, 3.1 and 0.35 mg·L-1, respectively. During storm events, TSS, TN and TP EMCs were 880, 3.7, and 0.46 mg·L-1, respectively. EMCs of TN and TP were similar to that of urban runoff; however, the TSS EMC from nursery runoff was 2-4 times greater. The average loading of TSS, TN and TP during storm events was approximately 900, 35 and 50 times higher than those of irrigation events, respectively. Based on a 10-year SWMM simulation (2008-2018) of runoff from the same nursery, annual TSS, TN and TP load per ha during storm events ranged from 9230 to 13,300, 65.8 to 94.0 and 9.00 to 12.9 kg·ha-1·yr-1, respectively. SWMM was able to characterize runoff quality and quantity reasonably well. Thus, it is suitable for characterizing runoff loadings from container nurseries.

Hysteresis analysis of nitrate dynamics in the Neuse River, NC.

Anthropogenic activities have caused N saturation in many terrestrial ecosystems. The transfer of nutrients and sediments to freshwater environments has resulted in water quality impairments including eutrophication, increased turbidity, ecosystem acidification, and loss of biodiversity. Storm events account for the transport of a large proportion of nutrients and sediments found in watersheds on an annual basis. To implement effective water-quality management strategies, the importance of surface and subsurface flow paths during storm events and low flow conditions need to be quantified. The increased availability of optical in-situ sensors makes high-frequency monitoring of catchment fluxes practical. In this study, we present a high-resolution nitrate monitoring record over a 10-year period in the Neuse River Basin near Clayton, North Carolina. The relationship between discharge and nitrate concentration for 365 storm events are categorized into hysteresis classes that indicate different transport mechanisms into the river. Storm events over the entire period of this study are divided between clockwise, counter-clockwise, and complex hysteresis patterns, indicating multiple nitrate flow paths during different seasons and years. Logistic regression of a suite of environmental variables demonstrates that antecedent soil moisture is a significant factor in determining the storm hysteresis class, with the odds of counter-clockwise hysteresis increasing by 10.3% for every 1 percentage point increase in the soil moisture. There is also an overlying seasonal effect, which indicates that dry soil conditions and frequent small storms during summer leads to greater nitrate transport on the rising limb, in contrast to slower, groundwater-driven inputs during the rest of the year.

First flush characteristics of rainfall runoff from a paddy field in the Taihu Lake watershed, China.

Nonpoint storm runoff remains a major threat to surface water quality in China. As a paddy matures, numerous fertilizers are needed, especially in the rainy seasons; the concentration of nitrogen and phosphorus in rainfall runoff from farmland is much higher than at other times, and this poses a great threat to water bodies and is the main reason for water eutrophication, especially in high concentration drainages. To date, most studies regarding the characteristics of pollutants in rainfall runoff have mainly been concentrated on urban runoff and watershed runoff; therefore, it is particularly important to investigate the characteristics of nitrogen and phosphorus loss in rainfall runoff from paddy fields. To study the characteristics of nitrogen and phosphorus loss and whether the first flush effect exists, continuous monitoring of the rainfall runoff process of six rainfall events was conducted in 2013, of which four rainfall events during storm, high, middle, and low intensity rainfalls were analyzed, and runoff and quality parameters, such as suspended solids (SS), total nitrogen (TN), ammonium nitrogen (NH4+-N), nitrate nitrogen (NO3--N), total phosphorus (TP), and phosphate (PO43--P), were analyzed to determine the relationship between runoff and water quality. The paddy field is located north of Wuxi Lake Basin along the Hejia River upstream in Zhoutie town, Yixing city. An analysis of the load distribution during rainfall runoff was conducted. Event mean concentration (EMC) was used to evaluate the pollution situation of the paddy field's rainfall runoff. A curve of the dimensionless normalized cumulative load (L) vs. normalized cumulative flow (F) (L-F curve), the probability of the mass first flush (MFFn), and the pollutants carried by the initial 25% of runoff (FF25) were used to analyze the first flush effect of the paddy field runoff, and different contaminants show different results: the concentration of nitrogen and phosphorus fluctuate and follow a similar trend as runoff changes, NO3--N concentration is lower in the early part of runoff and higher in the later, and TP mainly occurs in the particle state in storm runoff and mainly in the dissolved state when the rainfall intensity is smaller. Nitrogen and phosphorus losses from paddy fields are closely related to the average rainfall intensity and the max rainfall intensity, and the runoff loss of nitrogen and phosphorus is more severe when the rainfall intensity is large. Based on an analysis of multiple methodologies, TN and NH4+-N show a certain degree of a first flush effect, whereas the first flush effect of TP is not obvious. The first flush effect of SS is obvious in larger intensity rainfall and shows a slight secondary flush effect in smaller rainfall events.

Modeling flood reduction effects of low impact development at a watershed scale.

Low impact development (LID) is a land development approach that seeks to mimic a site's pre-development hydrology. This study is a case study that assessed flood reduction capabilities of large-scale adoption of LID practices in an urban watershed in central Illinois using the Personal Computer Storm Water Management Model (PCSWMM). Two flood metrics based on runoff discharge were developed to determine action flood (43 m(3)/s) and major flood (95 m(3)/s). Four land use scenarios for urban growth were evaluated to determine the impacts of urbanization on runoff and flooding. Flood attenuation effects of porous pavement, rain barrel, and rain garden at various application levels were also evaluated as retrofitting technologies in the study watershed over a period of 30 years. Simulation results indicated that increase in urban land use from 50 to 94% between 1992 and 2030 increased average annual runoff and flood events by more than 30%, suggesting that urbanization without sound management would increase flood risks. The various implementation levels of the three LID practices resulted in 3-47% runoff reduction in the study watershed. Flood flow events that include action floods and major floods were also reduced by 0-40%, indicating that LID practices can be used to mitigate flood risk in urban watersheds. The study provides an insight into flood management with LID practices in existing urban areas.

At-grade stabilization structure impact on surface water quality of an agricultural watershed.

Decades of farming and fertilization of farm land in the unglaciated/Driftless Area (DA) of southwestern Wisconsin have resulted in the build-up of P and to some extent, N, in soils. This build-up, combined with steep topography and upper and lower elevation farming (tiered farming), exacerbates problems associated with runoff and nutrient transport in these landscapes. Use of an at-grade stabilization structure (AGSS) as an additional conservation practice to contour strip cropping and no-tillage, proved to be successful in reducing organic and sediment bound N and P within an agricultural watershed located in the DA. The research site was designed as a paired watershed study, in which monitoring stations were installed on the perennial streams draining both control and treatment watersheds. Linear mixed effects statistics were used to determine significant changes in nutrient concentrations before and after installation of an AGSS. Results indicate a significant reduction in storm event total P (TP) concentrations (P = 0.01) within the agricultural watershed after installation of the AGSS, but not total dissolved P (P = 0.23). This indicates that the reduction in P concentration is that of the particulate form. Storm event organic N concentrations were also significantly reduced (P = 0.03) after the AGSS was installed. We conclude that AGSS was successful in reducing the organic and sediment bound N and P concentrations in runoff waters thus reducing their delivery to nearby surface waters.

Improving risk estimates of runoff producing areas: formulating variable source areas as a bivariate process.

Predicting runoff producing areas and their corresponding risks of generating storm runoff is important for developing watershed management strategies to mitigate non-point source pollution. However, few methods for making these predictions have been proposed, especially operational approaches that would be useful in areas where variable source area (VSA) hydrology dominates storm runoff. The objective of this study is to develop a simple approach to estimate spatially-distributed risks of runoff production. By considering the development of overland flow as a bivariate process, we incorporated both rainfall and antecedent soil moisture conditions into a method for predicting VSAs based on the Natural Resource Conservation Service-Curve Number equation. We used base-flow immediately preceding storm events as an index of antecedent soil wetness status. Using nine sub-basins of the Upper Susquehanna River Basin, we demonstrated that our estimated runoff volumes and extent of VSAs agreed with observations. We further demonstrated a method for mapping these areas in a Geographic Information System using a Soil Topographic Index. The proposed methodology provides a new tool for watershed planners for quantifying runoff risks across watersheds, which can be used to target water quality protection strategies.

Effects of storm runoff on the thermal regime and water quality of a deep, stratified reservoir in a temperate monsoon zone, in Northwest China.

Jinpen Reservoir is a deep, stratified reservoir in Shaanxi province, located in a warm temperate zone of Northwest China. Influenced by a temperate monsoon climate, more than 60% of the annual precipitation is concentrated from late summer to autumn (July-September). In recent years, extreme rainfall events occurred more frequently and strongly affected the thermal structure, mixing layer depth and evolution of stratification of Jinpen Reservoir. The reservoir's inflow volume increased sharply after heavy rainfall during the flooding season. Large volumes of inflow induced mixing of stratified water zones in early autumn and disturbed the stratification significantly. A temporary positive effect of such disturbance was the oxygenation of the water close to the bottom of the reservoir, leading to inhibition of the release of nutrients from sediments, especially phosphate. However, the massive inflow induced by storm runoff with increased oxygen-consuming substances led to an increase of the oxygen consumption rate. After the bottom water became anaerobic again, the bottom water quality would deteriorate due to the release of pollutants from sediments. Heavy rainfall events could lead to very high nutrient input into the reservoir due to massive erosion from the surrounding uninhabited steep mountains, and the particulate matter contributed to most nutrient inputs. Reasonably releasing density flow is an effective way to reduce the amounts of particulate associated pollutants entering the reservoir. Significant turbid density flow always followed high rainfall events in Jinpen Reservoir, which not only affected the reservoir water quality but also increased costs of the drinking water treatment plant. Understanding the effects of the storm runoff on the vertical distributions of water quality indicators could help water managers to select the proper position of the intake for the water plant in order to avoid high turbidity outflow.

Origin and fate of copper in a small Mediterranean vineyard catchment: new insights from combined chemical extraction and δ65Cu isotopic composition.

For centuries, many Mediterranean catchments were covered with vineyards in which copper was widely applied to protect grapevines against fungus. In the Mediterranean-type flow regime, brief and intense flood events increase the stream water discharge by up to 10 times and cause soil leaching and storm runoff. Because vineyards are primarily cultivated on steep slopes, high Cu fluxes are discharged by surface water runoff into the rivers. The purpose of this work was to investigate the riverine behavior and transport of anthropogenic Cu by coupling a sequential chemical extraction (SCE) procedure, used to determine Cu partitioning between residual and non-residual fractions, with δ(65)Cu isotopic measurements in each fraction. In the Baillaury catchment, France, we sampled soils (cultivated and abandoned), river bed sediments (BS), suspended particulate matter (SPM), and river water during the flash flood event of February 2009. Copper partitioning using SCE show that most of Cu in abandoned vineyard soil was in the residual phase (>60%) whereas in cultivated soil, BS and SPM, Cu was mostly (>25%) in non-residual fractions, mainly adsorbed onto iron oxide fractions. A small fraction of Cu was associated with organic matter (5 to 10%). Calculated enrichment factors (EF) are higher than 2 and the anthropogenic contribution was estimated between 50 to 85%. Values for δ(65)Cu in bulk samples were similar to bedrock therefore; δ(65)Cu on SCE fractions of superficial soils and SPM allowed for discrimination between Cu origin and distribution. Copper in residual fractions was of natural mineral origin (δ(65)Cu close to local bedrock, +0.07‰). Copper in water soluble fraction of SPM (δ(65)Cu=+0.26‰) was similar to dissolved river Cu (δ(65)Cu=+0.31‰). Copper from fungicide treatment (δ(65)Cu=-0.35‰) was bound to organic matter (δ(65)Cu=-0.20‰) without or with slight isotopic fractioning. A preferential adsorption of (65)Cu onto iron oxides (δ(65)Cu=+0.5‰) is shown.