Trends in low temperature and non-thermal technologies for the degradation of persistent organic pollutants.

The daunting effects of persistent organic pollutants on humans, animals, and the environment cannot be overemphasized. Their fate, persistence, long-range transport, and bioavailability have made them an environmental stressor of concern which has attracted the interest of the research community. Concerted efforts have been made by relevant organizations utilizing legislative laws to ban their production and get rid of them completely for the sake of public health. However, they have remained refractive in different compartments of the environment. Their bioavailability is majorly a function of different anthropogenic activities. Landfilling and incineration are among the earliest classical means of environmental remediation of waste; however, they are not sustainable due to the seepage of contaminants in landfills, the release of toxic gases into the atmosphere and energy requirements during incineration. Other advanced waste destruction technologies have been explored for the degradation of these recalcitrant pollutants; although, some are efficient, but are limited by high amounts of energy consumption, the use of organic solvents and hazardous chemicals, high capital and operational cost, and lack of public trust. Thus, this study has systematically reviewed different contaminant degradation technologies, their efficiency, and feasibility. Finally, based on techno-economic feasibility, non-invasiveness, efficiency, and environmental friendliness; radiation technology can be considered a viable alternative for the environmental remediation of contaminants in all environmental matrices at bench-, pilot-, and industrial-scale.

Revolutionizing soil heavy metal remediation: Cutting-edge innovations in plant disposal technology.

Soil contamination with heavy metals has emerged as a global environmental threat, compromising agricultural productivity, ecosystem integrity, and human health. Conventional remediation techniques often fall short due to high costs, operational complexities, and environmental drawbacks. Plant-based disposal technologies, including biochar, phytometallurgy, and phrolysis, have emerged as promising solutions in this regard. Grounded in a novel experimental framework, biochar is studied for its dual role as soil amendment and metal adsorbent, while phytometallurgy is explored for its potential in resource recovery and economic benefits derived from harvested metal-rich plant biomass. Pyrolysis, in turn, is assessed for transforming contaminated biomass into value-added products, thereby minimizing waste. These plant disposal technologies create a circular model of remediation and resource utilization that holds the potential for application in large-scale soil recovery projects, development of environmentally friendly agro-industries, and advancement in sustainable waste management practices. This review mainly discussed cutting-edge plant disposal technologies-biochar application, phytometallurgy, and pyrolysis-as revolutionary approaches to soil heavy metal remediation. The efficacy, cost-effectiveness, and environmental impact of these innovative technologies are especially evaluated in comparison with traditional methods. The success of these applications could signal a paradigm shift in how we approach both environmental remediation and resource recovery, with profound implications for sustainable development and circular economy strategies.

Study on Cu- and Pb-contaminated loess remediation using electrokinetic technology coupled with biological permeable reactive barrier.

Although the electrokinetic (EK) remediation has drawn great attention because of its good maneuverability, the focusing phenomenon near the cathode and low removal efficiency remain to be addressed. In this study, a novel EK reactor was proposed to remediate Cu and Pb contaminated loess where a biological permeable reactive barrier (bio-PRB) was deployed to the middle of the EK reactor. For comparison, three test configurations, namely, CG, TG-1, and TG-2, were available. CG considered the multiple enzyme-induced carbonate precipitation (EICP) treatments, while TG-1 considered both the multiple EICP treatments and pH regulation. TG-2 further considered NH4+ recovery based on TG-1. CG not only improved Cu and Pb removals by the bio-PRB but also depressed the focusing phenomenon. TG-1 causes more Cu2+ and Pb2+ to migrate toward the bio-PRB and aggravates Cu and Pb removals by the bio-PRB, depressing the focusing phenomenon. TG-2 depressed the focusing phenomenon the most because Cu2+ and Pb2+ can combine with not only CO32- but PO43-. The removal efficiency of Cu and Pb is 34% and 36%, respectively. A NH4+ recovery of about 100% is attained.

Emergence of CuInS2 derived photocatalyst for environmental remediation and energy conversion.

Hydrogen production, catalytic organic synthesis, carbon dioxide reduction, environmental purification, and other major fields have all adopted photocatalytic technologies due to their eco-friendliness, ease of use, and reliance on sunlight as the driving force. Photocatalyst is the key component of photocatalytic technology. Thus, it is of utmost importance to produce highly efficient, stable, visible-light-responsive photocatalysts. CIS stands out among other visible-light-response photocatalysts for its advantageous combination of easy synthesis, non-toxicity, high stability, and suitable band structure. In this study, we took a brief glance at the synthesis techniques for CIS after providing a quick introduction to the fundamental semiconductor features, including the crystal and band structures of CIS. Then, we discussed the ways doping, heterojunction creation, p-n heterojunction, type-II heterojunction, and Z-scheme may be used to modify CIS's performance. Subsequently, the applications of CIS towards pollutant degradation, CO2 reduction, water splitting, and other toxic pollutants remediation are reviewed in detail. Finally, several remaining problems with CIS-based photocatalysts are highlighted, along with future potential for constructing more superior photocatalysts.

Microbial remediation of oil-contaminated shorelines: a review.

Frequent marine oil spills have led to increasingly serious oil pollution along shorelines. Microbial remediation has become a research hotspot of intertidal oil pollution remediation because of its high efficiency, low cost, environmental friendliness, and simple operation. Many microorganisms are able to convert oil pollutants into non-toxic substances through their growth and metabolism. Microorganisms use enzymes' catalytic activities to degrade oil pollutants. However, microbial remediation efficiency is affected by the properties of the oil pollutants, microbial community, and environmental conditions. Feasible field microbial remediation technologies for oil spill pollution in the shorelines mainly include the addition of high-efficiency oil degrading bacteria (immobilized bacteria), nutrients, biosurfactants, and enzymes. Limitations to the field application of microbial remediation technology mainly include slow start-up, rapid failure, long remediation time, and uncontrolled environmental impact. Improving the environmental adaptability of microbial remediation technology and developing sustainable microbial remediation technology will be the focus of future research. The feasibility of microbial remediation techniques should also be evaluated comprehensively.

Testing of a novel multi-branch horizontal well remediation technology for in situ remediation of contaminated soil and groundwater.

Soil and groundwater contamination has become a key issue in urban redevelopment. It is particularly difficult to use heavy equipment for the remediation of restricted sites or areas contaminated by factories that are still in operation. In this case, horizontal wells are considered a potentially useful technology as they can potentially remediate contamination areas located below buildings and other surface/subsurface obstacles. This research first introduces the principles and advantages and disadvantages of direct push injection, improved slant well, high-pressure rotary jet technology, horizontal reactive media treatment wells, and horizontal directional drilling well. The key aspects for promising in-situ remediation techniques were summarized as remediation well design, remediation agent injection technology and drill pipe and well wall sealing technology. Based on the requirements for key technologies, a novel multi-branch horizontal well in-situ remediation process was proposed, which integrates vertical/horizontal directional drilling, rotary injection, and expansion sealing techniques, and relevant supporting drilling and injecting equipment were developed. A bench test and field test were conducted to test drilling tool performance, drilling accuracy, and injection radius of influence. The results showed that the developed supporting drilling tool met the process requirements and could complete multi-branch horizontal well remediation engineering construction. The deviation between the measured depth and the design depth of the multi-branch horizontal well constructed using this technology was less than 9%, and the deviation between the depth displayed by the guidance instrument and the measured depth was less than 1%. The injection radius of influence in the test field measured from the monitoring wells was greater than or equal to 5 m. The results of this research can provide an effective method for the remediation of contaminated sites.

Ecological risk identification and assessment of land remediation project based on GIS technology.

A land remediation project involves the removal of potentially toxic chemicals from a polluted site. Lands abandoned by industry are often contaminated with heavy metals like mercury, lead, chemicals, arsenic, and other toxins like dichlorodiphenyltrichloroethane biphenyls from electronic devices, and volatile organic chemicals (VOCs) from lubricants and chemicals. Risk assessment in environmental settings requires modernized systematic methodologies due to the complexity of today's environmental problems. When people eat, drink, or work in polluted environments, they put their health at risk and may even get cancer. Integrating geospatial information systems (GIS) with pollutant dispersion models makes environmental risk assessment and early warning possible. This research thus presents a GIS-based ecological risk identification and assessment model (GIS-ERIAM) for assessing risk for efficient land rehabilitation. Environmental cleanup sites' catalog information is the source of these details. With satellite imagery, GIS makes it simple to keep an eye on the environment and track the abundance of different types of plants and animals The ecological risk assessment (ERA) model can support recognition and prioritize risk management. By integrating direct and indirect environment interactions, the risk conditions of the whole ecology and its elements have been quantified and demonstrated in the study. The numerical outcomes illustrate that the recommended GIS-ERIAM model improves the performance by 98.9%, risk level prediction by 97.3%, risk classification by 96.4%, and detection of soil degradation ratio of 95.6% compared to other existing methods.

Recent advances in structural engineering of photocatalysts for environmental remediation.

Photocatalysis appears to be an appealing approach for environmental remediation including pollutants degradation in water, air, and/or soil, due to the utilization of renewable and sustainable source of energy, i.e., solar energy. However, their broad applications remain lagging due to the challenges in pollutant degradation efficiency, large-scale catalyst production, and stability. In recent decades, massive efforts have been devoted to advance the photocatalysis technology for improved environmental remediation. In this review, the latest progress in this aspect is overviewed, particularly, the strategies for improved light sensitivity, charge separation, and hybrid approaches. We also emphasize the low efficiency and poor stability issues with the current photocatalytic systems. Finally, we provide future suggestions to further enhance the photocatalyst performance and lower its large-scale production cost. This review aims to provide valuable insights into the fundamental science and technical engineering of photocatalysis in environmental remediation.

Patent mining on soil pollution remediation technology from the perspective of technological trajectory.

Recent years have seen a marked growth in soil environmental problems, however, the research & development (R&D) direction of soil pollution remediation technology (SPRT) for addressing related challenges to the global ecosystem is still unclear. Patent is the most effective carrier of technological information. Therefore, this study investigates the status and future direction of SPRT through the analysis and mining of 14,475 patents from 1971 to 2020. In 2006-2020, 14,435 SPRT patents (79% of the total) were published, which is in the development stage. By measuring the proportion of high-value patents, determined by the ratio of the number of patent families containing two or more patents (PF2) to that containing at least one patent (PF1), we found that United States (PF2/PF1 = 0.711), Japan (PF2/PF1 = 0.500), and South Korea (PF2/PF1 = 0.431) hold a monopoly. International patent organizations serve as a bridge for technology transfer. Patent CN101947539-A measured by structural hole index (Effective size = 98.194, Efficiency = 0.926) has the most significant technological influence. Therefore, in order to accomplish the technological transition and improve the soil remediation capacity, more attention should be paid to the microbial-assisted phytoremediation technology related to inorganic pollutants, hyperaccumulators and stabilizers. Additionally, patents CN102834190-A (Effective size = 23.930, Efficiency = 0.855, Constraint = 0.141, Hierarchy = 0.089) and CN105855289 (Effective size = 21.453, Efficiency = 0.795 Constraint = 0.149, Hierarchy = 0.086) are both at the location of structural holes. So, more research should be carried out on green and cost-effective solutions for reducing organic pollutants in soil remediation. The current study identifies opportunities for innovations and breakthroughs in SPRT and offers relevant information on technological development prospects.

Self-regulated immobilization behavior of multiple heavy metals via zeolitization towards a novel hydrothermal technology for soil remediation.

More efficient soil remediation technologies are highly anticipated to treat large quantities of heavy metal-polluted urban sites nowadays. Herein, a novel hydrothermal technology of converting heavy metal-polluted soils into zeolites for in-situ immobilizing heavy metals was proposed. The zeolites (analcime and cancrinite) could be synthesized hydrothermally with certain Na/Si and Al/Si ratios. The formed zeolites could manage to change their species and structure during zeolitization to accommodate different heavy metals in soil according to their size and charge. Since smaller-size Cu2+ was introduced, analcime and some cancrinite possessing small cages could be formed adaptively to immobilize the Cu2+ by replacing Na+ and forming Cu2+-OH and Cu2+-O. Whereas, cancrinite with large channels managed to form to immobilize the larger-size Cd2+ by forming Cd2+-O. Interplanar spacing variation of zeolites also corresponded to their structural change for accommodating different heavy metals. Leaching results showed the amounts of Cu and Cd leached from the synthesized zeolites were reduced to 0.005% and 0.05% respectively, reflecting a more stable immobilization of smaller heavy metals by small cages, in agreement with the results of distribution coefficient (Kd). Negligible effect of pH environment on the leaching rates further confirmed the stable structural immobilization of heavy metals by zeolites.

Development of multifarious carrier materials and impact conditions of immobilised microbial technology for environmental remediation: A review.

Microbial technology is the most sustainable and eco-friendly method of environmental remediation. Immobilised microorganisms were introduced to further advance microbial technology. In immobilisation technology, carrier materials distribute a large number of microorganisms evenly on their surface or inside and protect them from external interference to better treat the targets, thus effectively improving their bioavailability. Although many carrier materials have been developed, there have been relatively few comprehensive reviews. Therefore, this paper summarises the types of carrier materials explored in the last ten years from the perspective of structure, microbial activity, and cost. Among these, carbon materials and biofilms, as environmentally friendly functional materials, have been widely applied for immobilisation because of their abundant sources and favorable growth conditions for microorganisms. The novel covalent organic framework (COF) could also be a new immobilisation material, due to its easy preparation and high performance. Different immobilisation methods were used to determine the relationship between carriers and microorganisms. Co-immobilisation is particularly important because it can compensate for the deficiencies of a single immobilisation method. This paper emphasises that impact conditions also affect the immobilisation effect and function. In addition to temperature and pH, the media conditions during the preparation and reaction of materials also play a role. Additionally, this study mainly reviews the applications and mechanisms of immobilised microorganisms in environmental remediation. Future development of immobilisation technology should focus on the discovery of novel and environmentally friendly carrier materials, as well as the establishment of optimal immobilisation conditions for microorganisms. This review intends to provide references for the development of immobilisation technology in environmental applications and to further the improve understanding of immobilisation technology.

Enhanced remediation of surface-bound hexavalent chromium in soils using the acidic and alkaline fronts of electrokinetic technology.

In the subsurface environment, highly toxic hexavalent chromium (Cr(VI)) control and remediation are essential to avoid further ecological impacts and reduce environmental risks. This paper investigated the enhanced Cr(VI) electrokinetic removal in the soil through the approaching cathode method. Besides, a novel four-step sequential fractionation method was used to reflect the strength of Cr(VI) binding to the soil. The approaching cathode enhanced the electrokinetic delivery of surface-bound Cr(VI) by advancing the alkaline front for Cr(VI) desorption and improving the electric potential flattening of the soil layers. Desorption of Cr(VI) by the alkaline front involved converting the inner-sphere complexes form of Cr(VI) to a weakly adsorbed form susceptible to ionic strength. In addition, the acidic front provided a favorable environment for the photochemical reduction of Cr(VI) by soil species or the added citrate as the electron donors. Improving the potential distribution could regulate the energy consumption of individual soil layers and efficiently operate the electrokinetic transfer of pollutants. The work results have significant scientific and practical significance for applying the in-situ electrokinetic technique in subsurface pollution control.

A review for recent advances on soil washing remediation technologies.

Contaminated soils have caused serious harm to human health and the ecological environment due to the high toxicity of organic and inorganic pollutants, which has attracted extensive attention in recent years. Because of its low cost, simple operation and high efficiency, soil washing technology is widely used to permanently remove various pollutants in contaminated soils and is considered to be the most promising remediation technology. This review summarized the recent developments in the field of soil washing technology and discusses the application of conventional washing agents, advanced emerging washing agents, the recycling of washing effluents and the combination of soil washing and other remediation technologies. Overall, the findings provide a comprehensive understanding of soil washing technology and suggest some potential improvements from a scientific and practical point of view.

Remediation characteristics of surfactant-enhanced air sparging (SEAS) technology on volatile organic compounds contaminated soil with low permeability.

Surfactant-enhanced air sparging (SEAS) is an effective technology for the remediation of volatile organic compounds contamination of medium and high-permeability soil, though applying SEAS to low-permeability soil contamination has rarely been explored. In this study, a series of two-dimensional physical model tests were designed to explore the feasibility and remediation characteristics of SEAS on low-permeability soil. In the test results, the incorporation and increase in surfactant concentration promoted air channel formation in the low-permeability soil, finally reduced the capillary breakthrough pressure and improved the airflow rate. The majority of the exhausted gaseous contaminants were distributed along the horizontal direction, differing from the results observed in medium and high-permeability soils. The exhausted gaseous contaminant concentration changed slightly when the sparging pressure and surfactant concentration increased at relatively low levels and increased as the sparging pressure and surfactant concentration increased further. Increasing the air sparging pressure without surfactant incorporation or with a low surfactant concentration cannot effectively remove the contaminant, while the removal efficiency can be enhanced with further increases in surfactant concentration. The discrete remediation characteristics had been confirmed during SEAS application on low-permeability soil, then the relationships between the ratios of remediation area and remediation extent under different surfactant concentrations and sparging pressures were established for remediation efficiency evaluation. Using this method, the discrete remediation characteristics can be recreated once the surfactant concentration and the sparging pressure were chosen. On the other side, targeted improvements in the remediation area or extent can be achieved by controlling the surfactant concentration and sparging pressure. Through this study, SEAS technology and the proposed evaluation method were successfully implemented in soil with hydraulic conductivity around 9E-7 m/s, which expanded the application scope of SEAS technology for contaminant removal.

Recent advances in soil remediation technology for heavy metal contaminated sites: A critical review.

With the increasing development of industry and urbanization, heavy metal contaminated sites have become progressively conspicuous, particularly by unreasonable emissions from electroplating, nonferrous metals smelting, mine tailing, etc. In recent years, soil remediation technologies for heavy metal contaminated sites have developed rapidly. New and effective remediation technologies have emerged successively, and more successful practical applications have appeared. Therefore, systematical summarization of the current progress is essential. As a result, in this paper, some mainstream soil remediation technologies for heavy metal contaminated sites, including physical remediation (soil thermal desorption and soil replacement), bioremediation (phytoremediation and microbial remediation), chemical remediation (chemical leaching, chemical stabilization, electrokinetic remediation-permeable reactive barrier, and chemical oxidation/reduction), as well as various combined remediation are comprehensively reviewed. The influencing factors, advantages, disadvantages, remediation mechanism, and practical applications are also deeply discussed. Besides, the corresponding remediation strategies are put forward for the remediation of heavily polluted sites such as the chemical industry, smelting, and tailing areas. Overall, this review will be beneficial for the in-depth understanding and provide references for the reasonable selection and development of soil remediation technology for heavy metal contaminated sites.

A Comprehensive Evaluation Method for Soil Remediation Technology Selection: Case Study of Ex Situ Thermal Desorption.

Quantitative evaluation of different contaminated soil remediation technologies in multiple dimensions is beneficial for the optimization and comparative selection of technology. Ex situ thermal desorption is widely used in remediation of organic contaminated soil due to its excellent removal effect and short engineering period. In this study, a comprehensive evaluation method of soil remediation technology, covering 20 indicators in five dimensions, was developed. It includes the steps of constructing an indicator system, accounting for the indicator, normalization, determining weights by analytic hierarchy process, and comprehensive evaluation. Three ex situ thermal desorption technology-direct thermal desorption, indirect thermal desorption, and indirect thermal heap-in China were selected for the model validation. The results showed that the direct thermal desorption had the highest economic and social indicator scores of 0.068 and 0.028, respectively. The indirect thermal desorption had the highest technical and environmental indicator scores of 0.118 and 0.427, respectively. The indirect thermal heap had the highest resource indicator score of 0.175. With balanced performance in five dimensions, the indirect thermal desorption had the highest comprehensive score of 0.707, which is 1.6 and 1.4 times higher than the direct thermal desorption and indirect thermal heap, respectively. The comprehensive evaluation method analyzed and compared the characteristics of the ex situ thermal desorption technology from different perspectives, such as specific indicators, multiple dimensions, and single comprehensive values. It provided a novel evaluation approach for the sustainable development and application of soil remediation technology.

Progress of uranium-contaminated soil bioremediation technology.

With the extensive exploitation of nuclear energy and uranium, the problem of uranium-contaminated soil is becoming increasingly prominent. In recent years, various technologies for remediation of uranium-contaminated soil have emerged, such as bioremediation, physical remediation and chemical remediation. Bioremediation technology has the widespread attention because of its environmental friendliness, low cost and high economic benefits. This paper mainly reviews the evaluation index of uranium-contaminated soil, soil remediation technology and its advantages and disadvantages, introduces especially the research status of soil bioremediation technology in detail, and puts forward some suggestions and prospects for bioremediation of uranium-contaminated soil.

Bioaugmentation as a green technology for hydrocarbon pollution remediation. Problems and prospects.

Environmental pollution mitigation measure involving bioremediation technology is a sustainable intervention for a greener ecosystem biorecovery, especially the obnoxious hydrocarbons, xenobiotics, and other environmental pollutants induced by anthropogenic stressors. Several successful case studies have provided evidence to this paradigm including the putative adoption that the technology is eco-friendly, cost-effective, and shows a high tendency for total contaminants mineralization into innocuous bye-products. The present review reports advances in bioremediation, types, and strategies conventionally adopted in contaminant clean-up. It identified that natural attenuation and biostimulation are faced with notable limitations including the poor remedial outcome under the natural attenuation system and the residual contamination occasion following a biostimulation operation. It remarks that the use of genetically engineered microorganisms shows a potentially promising insight as a prudent remedial approach but is currently challenged by few ethical restrictions and the rural unavailability of the technology. It underscores that bioaugmentation, particularly the use of high cell density assemblages referred to as microbial consortia possess promising remedial prospects thus offers a more sustainable environmental security. The authors, therefore, recommend bioaugmentation for large scale contaminated sites in regions where environmental degradation is commonplace.

[Advances in degradation mechanisms of 1,2,3-trichloropropane and remediation technology of contaminated sites].

1,2,3-trichloropropane (TCP) is an industrially synthesized aliphatic chlorinated hydrocarbon and an intermediate product in the industrial production of epichlorohydrin, which can be used as a precursor for the manufacture of soil fumigant and organic solvents. Due to its biological toxicity, environmental persistence and strong environmental migration ability, 1,2,3-TCP is listed as an emerging organochlorine pollutant in the environment and regulated by many international organizations. Currently, the degradation of 1,2,3-TCP and the remediation of 1,2,3-TCP-contaminated sites receive great attention, but the degradation mechanism of 1,2,3-TCP has not been summarized in depth. This article discussed the origin of 1,2,3-TCP, its environmental impact and ecological effects, and the physical and chemical degradation techniques. This was followed by summarizing the degradation mechanisms of 1,2,3-TCP (e.g., aerobic co-biodegradation, anaerobic biodegradation). Specially, the pathways and mechanisms of microbial biodegradation and transformation of 1,2,3-TCP in anoxic environments (e.g., groundwater) were thoroughly reviewed. The feasibility of using 1,2,3-TCP as an electron acceptor by organohalide-respiring bacteria under anoxic conditions was predicted based on thermodynamic analysis. Last but not least, in situ bioremediation of 1,2,3-TCP contaminated sites was summarized, and prospects for future research were discussed.

Effective remediation of heavy metals in contaminated soil by electrokinetic technology incorporating reactive filter media.

Soil contamination is increasingly a global problem with serious implications for human health. Among different soil decontamination approaches, electrokinetic (EK) remediation is a relatively new technology for treating organic and inorganic contaminants in soil. This research aims to develop an enhanced EK treatment method incorporating a compost-based reactive filter media (RFM) with the advantages of low-cost and strong affinity for heavy metals and test and improve the treatment efficiency for multiple heavy metals in natural soil. A series of EK operations were performed to investigate the performance of EK-RFM under different operating conditions such as the electric current and voltage, processing time, and the amount of RFM. The electric current and treatment time demonstrated a significant positive impact on removing Zn, Cd and Mn ions while changing the amount of RFM had an insignificant impact on the efficiency of heavy metals removal. Overall, 51.6%-72.1% removal of Zn, Cd, and Mn was achieved at 30.00 mA of electric current and 14 days of treatment duration. The energy consumption of the EK process was 0.17 kWh kg-1. The soil organic matter adversely affected the mobilization and migration of heavy metals such as Cu and Pb during EK treatment. The results are valuable in optimizing the design of the EK-RFM system, which will extend its application to field-scale soil decontamination practices.