Two 17-hydroxy-9(10-->5)-abeo-estr-4-ene-3,10-diones.
Acta Crystallogr C
; 57(Pt 4): 495-6, 2001 Apr.
Article
em En
| MEDLINE
| ID: mdl-11313607
ABSTRACT
(5S,9S,17S)-17-Hydroxy-9(10-->5)-abeo-estr-4-ene-3,10-dione, C(18)H(26)O(3), (II), and (5R,9R,17S)-17-hydroxy-9(10-->5)-abeo-estr-4-ene-3,10-dione, C(18)H(26)O(3), (III), are equimolecular products of the Fe(II)-induced transposition of 10beta-hydroperoxy-17beta-hydroxyestr-4-en-3-one, (I). With respect to reagent molecules, the configuration at C9 is retained for (II) while it is inverted in (III). The conformations of the five- and six-membered rings are compared.
Buscar no Google
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr C
Ano de publicação:
2001
Tipo de documento:
Article
País de afiliação:
Itália