A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N@C80.
J Am Chem Soc
; 124(4): 524-5, 2002 Jan 30.
Article
em En
| MEDLINE
| ID: mdl-11804475
ABSTRACT
The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2002
Tipo de documento:
Article
País de afiliação:
Estados Unidos