Reversible negative thermal expansion of polymer films.
Phys Rev E Stat Nonlin Soft Matter Phys
; 66(6 Pt 1): 061801, 2002 Dec.
Article
em En
| MEDLINE
| ID: mdl-12513309
ABSTRACT
A basic understanding of the properties of thin polymer films is of fundamental importance for developing applications in nanotechnology. Results of energy and angle dispersive x-ray reflectivity measurements on polymer thin films as a function of temperature exhibit reversible negative thermal expansion below the glass transition temperature T(g). Above T(g), the thickness expansion becomes almost equal to the expected bulk volume expansion. These results could be explained on the basis of evolution of disorder with temperature at the interfaces, chain entanglement and associated entropy changes.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Phys Rev E Stat Nonlin Soft Matter Phys
Assunto da revista:
BIOFISICA
/
FISIOLOGIA
Ano de publicação:
2002
Tipo de documento:
Article
País de afiliação:
Índia