Metal-containing trifurcate receptor that recognizes and senses citrate in water.
Org Lett
; 7(13): 2603-6, 2005 Jun 23.
Article
em En
| MEDLINE
| ID: mdl-15957901
ABSTRACT
[reaction see text] The binding tendencies toward carboxylates of a trifurcated receptor containing three copper(II)-cyclam subunits have been investigated in pure water, through the displacement of a fluorescent indicator. The receptor is tailor-made for the recognition of tricarboxylates, e.g., citrate, whose three negatively charged oxygen atoms interact with the three coordinatively unsaturated Cu(II) centers.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Água
/
Citratos
/
Corantes Fluorescentes
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2005
Tipo de documento:
Article
País de afiliação:
Itália