The effects of unequal ionic sizes for an electrolyte in a charged slit.
J Colloid Interface Sci
; 295(1): 124-34, 2006 Mar 01.
Article
em En
| MEDLINE
| ID: mdl-16168434
ABSTRACT
The modified Gouy-Chapman (MGC) theory has been used to study the electrical double layer near two charged plates immersed in a model electrolyte. The effects of assigning to the cations and anions different distances of closest approach to the charged surfaces are examined. The dependence of overcharging and charge reversal on the system parameters such as concentration, ion size and valence, is investigated both inside and outside the charged slit.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Colloid Interface Sci
Ano de publicação:
2006
Tipo de documento:
Article
País de afiliação:
México