Temperature-sensitive photoluminescence of CdSe quantum dot clusters.
J Phys Chem B
; 109(29): 13899-905, 2005 Jul 28.
Article
em En
| MEDLINE
| ID: mdl-16852744
ABSTRACT
The formation of narrow size dispersed and nanometer size aggregates (clusters) of cadmium selenide (CdSe) quantum dots (QDs) and their temperature-sensitive photoluminescence (PL) spectral properties close to room temperature (298 K) are discussed. CdSe QDs formed stable clusters with an average diameter of approximately 27 nm in the absence of coordinating solvents. Using transmission electron microscopy (TEM) imaging, we identified the association of individual QDs with 2-5 nm diameters into clusters of uniform size. A suspension of these clusters in different solvents exhibited reversible PL intensity changes and PL spectral shifts which were correlated with temperature. Although the PL intensity of CdSe QDs encapsulated in host matrixes and the solid state showed a response to temperature under cryogenic conditions, the current work identified for the first time QD clusters showing temperature-sensitive PL intensity variations and spectral shifts at moderate temperatures above room temperature. Temperature-sensitive reversible PL changes of clusters are discussed with respect to reversible thermal trapping of electrons at inter-QD interfaces and dipole-dipole interactions in clusters. Reversible luminescence intensity variations and spectral shifts of QD clusters show the potential for developing sensors based on QD nanoscale assemblies.
Buscar no Google
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos de Selênio
/
Compostos de Cádmio
/
Pontos Quânticos
/
Luminescência
Tipo de estudo:
Diagnostic_studies
Idioma:
En
Revista:
J Phys Chem B
Assunto da revista:
QUIMICA
Ano de publicação:
2005
Tipo de documento:
Article
País de afiliação:
Japão