Modeling the elastic deformation of polymer crusts formed by sessile droplet evaporation.
Phys Rev E Stat Nonlin Soft Matter Phys
; 74(2 Pt 1): 021601, 2006 Aug.
Article
em En
| MEDLINE
| ID: mdl-17025440
ABSTRACT
Evaporating droplets of polymer or colloid solution may produce a glassy crust at the liquid-vapor interface, which subsequently deforms as an elastic shell. For sessile droplets, the known radial outward flow of solvent is expected to generate crusts that are thicker near the pinned contact line than the apex. Here we investigate, by nonlinear quasistatic simulation and scaling analysis, the deformation mode and stability properties of elastic caps with a nonuniform thickness profile. By suitably scaling the mean thickness and the contact angle between crust and substrate, we find that data collapse onto a master curve for both buckling pressure and deformation mode, thus allowing us to predict when the deformed shape is a dimple, Mexican hat, and so on. This master curve is parameterized by a dimensionless measure of the nonuniformity of the shell. We also speculate on how overlapping time scales for gelation and deformation may alter our findings.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Prognostic_studies
Idioma:
En
Revista:
Phys Rev E Stat Nonlin Soft Matter Phys
Assunto da revista:
BIOFISICA
/
FISIOLOGIA
Ano de publicação:
2006
Tipo de documento:
Article
País de afiliação:
Japão