The role of Frank elasticity in cholesteric elastomers.
Eur Phys J E Soft Matter
; 22(2): 117-22, 2007 Feb.
Article
em En
| MEDLINE
| ID: mdl-17347786
ABSTRACT
The effect of Frank elasticity on deformations of cholesteric elastomers by mechanical stress applied perpendicular to the helix axis is studied by numerical minimization of the free energy. Above a critical strain, a solution with an only oscillating director is found to be stable in comparison to a distorted helix. At the critical strain, the contractions perpendicular to stress change discontinuously. The critical strain is found to increase with increasing Frank elasticity contribution to the free energy density, and to diverge when the conformation anisotropy of the polymer backbone vanishes. The results are compared with recent experiments which indicated that, in case of weak conformation anisotropies, the Frank elasticity contribution to the free energy cannot be neglected.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Polímeros
/
Colesterol
/
Elastômeros
Idioma:
En
Revista:
Eur Phys J E Soft Matter
Assunto da revista:
BIOFISICA
Ano de publicação:
2007
Tipo de documento:
Article
País de afiliação:
Alemanha