Electron lifetime in a Shockley-type metal-organic interface state.
Phys Rev Lett
; 101(14): 146801, 2008 Oct 03.
Article
em En
| MEDLINE
| ID: mdl-18851554
ABSTRACT
The lifetimes of electrons at the interface between 3,4,9,10-perylene-tetracarboxylic acid dianhydride (PTCDA) and Ag(111) have been studied by means of time- and angle-resolved two-photon photoemission. We observe a dispersing unoccupied state 0.6 eV above the Fermi level with an effective electron mass of 0.39m{e} at the Gamma[over ] point. The short lifetime of 54 fs is indicative of a large penetration of the wave function into the metal. Supported by model calculations this interface state is interpreted as predominantly arising from an upshift of the occupied Shockley surface state of the clean metal due to the interaction with the PTCDA overlayer.
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MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Ano de publicação:
2008
Tipo de documento:
Article
País de afiliação:
Alemanha