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Anionic oxidative polymerization: the synthesis of poly(phenylenedicyanovinylene) (PPCN2V).
J Am Chem Soc ; 131(1): 20-1, 2009 Jan 14.
Artigo em Inglês | MEDLINE | ID: mdl-19072056
ABSTRACT
A new polymerization technique that allows for the first-ever synthesis of poly(phenylenedicyanovinylene)s (PPCN2Vs) is described. PPCN2Vs, with their high electron affinities and structural versatility, seem ideally suited to address the need for new n-type polymers. Remarkably the polymers presented herein become more photoluminescent, in the thin film, under continuous irradiation.
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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Assunto principal: Polímeros / Polivinil Idioma: Inglês Revista: J Am Chem Soc Ano de publicação: 2009 Tipo de documento: Artigo País de afiliação: Estados Unidos