Rhodamine 6G hexa-chlorido-stannate(IV) acetonitrile disolvate.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 1): m199, 2007 Dec 18.
Article
em En
| MEDLINE
| ID: mdl-21200545
ABSTRACT
In the title compound, bis({6-ethylamino-10-[2-(methoxycarbonyl)phenyl]-2,7-dimethylxanthen-3-ylidene}ethanaminium) hexachloridotin(IV) acetonitrile disolvate, (C(27)H(29)N(2)O(3))(2)[SnCl(6)]·2C(2)H(3)N, the octa-hedral SnCl(6) (2-) anion lies on an inversion center. The xanthene ring system is essentially planar, with an average deviation of 0.020â
Å, and the substituent benzene ring forms a dihedral angle of 85.89â
(2)° with it. The Sn-Cl distances are in the range 2.4237â
(3)-2.4454â
(3)â
Å. There are N-Hâ¯Cl hydrogen bonds between SnCl(6) (2-) ions and rhodamine 6G cations as well as π-π stacking inter-actions between rhodamine 6G cations (inter-planar distance of 3.827â
Å).
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2007
Tipo de documento:
Article
País de publicação:
EEUU
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ESTADOS UNIDOS
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ESTADOS UNIDOS DA AMERICA
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EUA
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UNITED STATES
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UNITED STATES OF AMERICA
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US
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USA