µ-Peroxido-bis-[acetonitrile-bis-(ethyl-enediamine)-cobalt(III)] tetrakis(per-chlorate).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 12): m1631-2, 2010 Nov 24.
Article
em En
| MEDLINE
| ID: mdl-21589305
ABSTRACT
The title compound, [Co(2)(O(2))(CH(3)CN)(2)(C(2)H(8)N(2))(4)](ClO(4))(4), consists of centrosymmetric binuclear cations and perchlorate anions. Two Co(III) atoms, which have a slightly distorted octa-hedral coordination, are connected through a peroxido bridge; the O-O distance is 1.476â
(3)â
Å. Both acetonitrile ligands are situated in a trans position with respect to the O-O bridge. In the crystal, the complex cations are connected by N-Hâ¯O hydrogen bonds between ethyl-endiamine NH groups and O atoms from the perchlorate anions and peroxide O atoms.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2010
Tipo de documento:
Article