A novel approach to the simulation of electrochemical mechanisms involving acute reaction fronts at disk and band microelectrodes.
Chemphyschem
; 13(3): 845-59, 2012 Feb.
Article
em En
| MEDLINE
| ID: mdl-22344796
ABSTRACT
A new simulation algorithm is presented for describing the dynamics of diffusion reactions at the most common microelectrode 1D (planar, cylindrical, spherical) and 2D geometries (band, disk) for electrochemical mechanisms of any complexity and involving fast homogeneous reactions of any kind. A series of typical electrochemical mechanisms that create the most severe simulation difficulties is used to establish the exceptional performance and accuracy of this algorithm, which stem from the combination of (quasi)conformal transformation of space and a new method for auto-adaptive grid compression.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemphyschem
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
França