Poly[octakis(1H-imidazole-κN(3))octa-µ-oxido-tetra-oxidodicopper(II)tetra-vanadate(V)].
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 4): m362-3, 2012 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-22589759
ABSTRACT
In the title inorganic-organic hybrid compound, [Cu(2)V(4)O(12)(C(3)H(4)N(2))(8)](n), the V(V) ion is tetra-coordinated by four O atoms and the Cu(II) ion is hexa-coordinated by four N atoms from four imidazole ligands and two O atoms from two tetra-hedral vanadate (VO(4)) units in a distorted octa-hedral geometry. The structure consists of two-dimensional sheets constructed from centrosymmetric cyclic [V(4)O(12)](4-) anions covalently bound through O to [Cu(imidazole)(4)](2+) cations. Adjacent sheets are linked by N-Hâ¯O hydrogen bonds and weak C-Hâ¯π inter-actions (Hâ¯centroid distances = 2.59, 2.66, 2.76, 2.91 and 2.98â
Å into a three-dimensional supra-molecular network.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
Tipo de documento:
Article