Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.

Iali, Wissam; La Paglia, Frédéric; Le Goff, Xavier-Frédéric; Sredojevic, Dusan; Pfeffer, Michel; Djukic, Jean-Pierre

Iali, Wissam; La Paglia, Frédéric; Le Goff, Xavier-Frédéric; Sredojevic, Dusan; Pfeffer, Michel; Djukic, Jean-Pierre.

Afiliação

Iali W; Institut de Chimie de Strasbourg, UMR 7177, Université de Strasbourg, 4 rue Blaise Pascal, F-67000 Strasbourg, France.

Chem Commun (Camb) ; 48(83): 10310-2, 2012 Oct 25.

Article em En | MEDLINE | ID: mdl-22982813

ABSTRACT

ABSTRACT

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild "one pot" conditions.

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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2012 Tipo de documento: Article País de afiliação: França

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