cis-Dichlorido-tetra-kis-(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 7): m395-6, 2013.
Article
em En
| MEDLINE
| ID: mdl-24046569
ABSTRACT
The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a Cr(III) ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octa-hedron. An isolated Cl(-) counter-anion and a positionally disordered DMSO mol-ecule [occupancy ratio 0.654â
(4)0.346â
(4)] are also present. In the structure, the complex cations inter-act with the Cl(-) counter-anions and the DMSO solvent mol-ecules via weak C-Hâ¯Cl and C-Hâ¯O inter-actions, forming a three-dimensional network.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Iraque
País de publicação:
EEUU
/
ESTADOS UNIDOS
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ESTADOS UNIDOS DA AMERICA
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EUA
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UNITED STATES
/
UNITED STATES OF AMERICA
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US
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USA