Conversion of 5-hydroxymethylfurfural to a cyclopentanone derivative by ring rearrangement over supported Au nanoparticles.
Chem Commun (Camb)
; 50(42): 5633-6, 2014 May 30.
Article
em En
| MEDLINE
| ID: mdl-24733311
ABSTRACT
Supported Au nanoparticles showed efficient catalytic performance for the ring rearrangement of 5-hydroxymethylfurfural (HMF) to a cyclopentanone derivative, 3-hydroxymethylcyclopentanone (HCPN), by taking advantage of the selective hydrogenation on Au nanoparticles and the Lewis acid catalysis of metal oxide supports. Among various metal oxide supported Au catalysts, the highest yield of HCPN was obtained by using Au/Nb2O5 (86% yield).
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Ciclopentanos
/
Nanopartículas Metálicas
/
Furaldeído
/
Ouro
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2014
Tipo de documento:
Article
País de afiliação:
Japão