AIBN-catalyzed oxidative cleavage of gem-disubstituted alkenes with O2 as an oxidant.

Wang, Guang-Zu; Li, Xing-Long; Dai, Jian-Jun; Xu, Hua-Jian

Wang, Guang-Zu; Li, Xing-Long; Dai, Jian-Jun; Xu, Hua-Jian.

Afiliação

Wang GZ; School of Medical Engineering and Key Laboratory of Advanced Functional Materials and Devices, Hefei University of Technology , Hefei 230009, Anhui Province, P. R. China.

J Org Chem ; 79(15): 7220-5, 2014 Aug 01.

Article em En | MEDLINE | ID: mdl-25033394

ABSTRACT

ABSTRACT

A 2,2-azobis(isobutyronitrile) (AIBN) catalyzed oxidative cleavage of gem-disubstituted alkenes with molecular oxygen as the oxidant has been described. Carbonyl compounds were obtained as the desired products in high yield under mild conditions. Based on previous documents and current experimental results, a relatively reasonable mechanism is proposed.

Assuntos

Alcenos/química; Compostos Azo/química; Nitrilas/química; Oxidantes/química; Oxigênio/química; Catálise; Estrutura Molecular; Estereoisomerismo

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Oxigênio / Compostos Azo / Oxidantes / Alcenos / Nitrilas Idioma: En Revista: J Org Chem Ano de publicação: 2014 Tipo de documento: Article

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google