6-[(2-Methyl-phen-yl)sulfan-yl]-5-propyl-pyrimidine-2,4(1H,3H)-dione.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 7): o768-9, 2014 Jul 01.
Article
em En
| MEDLINE
| ID: mdl-25161558
In the title pyrimidine-2,4-dione derivative, C14H16N2O2S, the dihedral angle between the six-membered rings is 77.81â
(10)°. The mol-ecule is twisted about the Cp-S (p = pyrimidine) bond, with a C-S-C-N torsion angle of -59.01â
(17)°. An intramolecular C-Hâ¯S hydrogen bond generates an S(5) ring motif. In the crystal, bifurcated acceptor N-Hâ¯O and C-Hâ¯O hydrogen bonds generate inversion-related dimers incorporating R 2 (1)(9) and R 2 (2)(8) loops. These dimers are connected into a chain extending along the a-axis direction by a second pair of inversion-related N-Hâ¯O hydrogen bonds, forming another R 2 (2)(8) loop. The crystal structure is further stabilized by weak inter-molecular C-Hâ¯π inter-actions, generating a three-dimensional network.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2014
Tipo de documento:
Article
País de afiliação:
Arábia Saudita
País de publicação:
Estados Unidos