Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI).

Woodall, Sean D; Swinburne, Adam N; lal Banik, Nidhu; Kerridge, Andrew; Di Pietro, Poppy; Adam, Christian; Kaden, Peter; Natrajan, Louise S

Woodall, Sean D; Swinburne, Adam N; lal Banik, Nidhu; Kerridge, Andrew; Di Pietro, Poppy; Adam, Christian; Kaden, Peter; Natrajan, Louise S.

Afiliação

Woodall SD; The Centre for Radiochemistry Research, The School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. louise.natrajan@manchester.ac.uk.

Chem Commun (Camb) ; 51(25): 5402-5, 2015 Mar 28.

Article em En | MEDLINE | ID: mdl-25531574

ABSTRACT

ABSTRACT

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Reino Unido

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