Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding.

Tireli, Martina; Juribasic Kulcsár, Marina; Cindro, Nikola; Gracin, Davor; Biliskov, Nikola; Borovina, Mladen; Curic, Manda; Halasz, Ivan; Uzarevic, Krunoslav

Tireli, Martina; Juribasic Kulcsár, Marina; Cindro, Nikola; Gracin, Davor; Biliskov, Nikola; Borovina, Mladen; Curic, Manda; Halasz, Ivan; Uzarevic, Krunoslav.

Afiliação

Tireli M; Ruder Boskovic Institute, Bijenicka 54, HR-10000 Zagreb, Croatia. ivan.halasz@irb.hr krunoslav.uzarevic@irb.hr.

Chem Commun (Camb) ; 51(38): 8058-61, 2015 May 11.

Article em En | MEDLINE | ID: mdl-25866133

RESUMO

In situ Raman spectroscopy was employed to study the course of a mechanochemical nucleophilic substitution on a carbonyl group. We describe evidence of base catalysis, akin to catalysis in solution, achieved by liquid-assisted grinding.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2015 Tipo de documento: Article País de publicação: Reino Unido

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