Your browser doesn't support javascript.
loading
The geometric mean squared displacement and the Stokes-Einstein scaling in a supercooled liquid.
Saw, Shibu; Harrowell, Peter.
Afiliação
  • Saw S; School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia.
  • Harrowell P; School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia.
J Chem Phys ; 143(24): 244502, 2015 Dec 28.
Article em En | MEDLINE | ID: mdl-26723687
It is proposed that the rate of relaxation in a liquid is better described by the geometric mean of the van Hove distribution function, rather than the standard arithmetic mean used to obtain the mean squared displacement. The difference between the two means is shown to increase significantly with an increase in the non-Gaussian character of the displacement distribution. Preliminary results indicate that the geometric diffusion constant results in a substantial reduction of the deviation from Stokes-Einstein scaling.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Austrália País de publicação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Austrália País de publicação: Estados Unidos