The synthesis and efficient one-pot catalytic "self-breeding" of asymmetrical NC(sp(3))E-hybridised pincer complexes.
Chem Commun (Camb)
; 52(22): 4211-4, 2016 Mar 18.
Article
em En
| MEDLINE
| ID: mdl-26912423
ABSTRACT
Cyclopalladation of the pyridyl-substituted chiral phosphine sulfide (N-P=S) and oxide (N-P=O) compounds afforded the asymmetric N-C(sp(3))*-S and N-C(sp(3))*-O pincer complexes. When applied as catalysts in asymmetric hydrophosphination, the newly developed aliphatic pincer catalyst could be recycled over three runs and obtained in large quantities via a one-pot "self-breeding" catalytic protocol.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2016
Tipo de documento:
Article
País de afiliação:
Singapura