Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex.

Pearson, Tyler J; Fataftah, Majed S; Freedman, Danna E

Pearson, Tyler J; Fataftah, Majed S; Freedman, Danna E.

Afiliação

Pearson TJ; Northwestern University, Department of Chemistry, 2145 Sheridan Rd., Evanston, Il 60208, USA. danna.freedman@northwestern.edu.
Fataftah MS; Northwestern University, Department of Chemistry, 2145 Sheridan Rd., Evanston, Il 60208, USA. danna.freedman@northwestern.edu.
Freedman DE; Northwestern University, Department of Chemistry, 2145 Sheridan Rd., Evanston, Il 60208, USA. danna.freedman@northwestern.edu.

Chem Commun (Camb) ; 52(76): 11394-11397, 2016 Sep 15.

Article em En | MEDLINE | ID: mdl-27711306

ABSTRACT

ABSTRACT

A novel Mn2+Bi3+ heterobimetallic complex, featuring the closest MnBi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.

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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Estados Unidos

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