The crystal structure of 6-(4-chloro-phen-yl)-2-(4-methyl-benz-yl)imidazo[2,1-b][1,3,4]thia-diazole-5-carbaldehyde.
Acta Crystallogr E Crystallogr Commun
; 72(Pt 10): 1460-1462, 2016 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-27746941
ABSTRACT
In the title imidazo[2,1-b][1,3,4]thia-diazole derivative, C19H14ClN3OS, the 4-methyl-benzyl and chloro-phenyl rings are inclined to the planar imidazo[2,1-b][1,3,4]thia-diazole moiety (r.m.s. deviation = 0.012â
Å) by 64.5â
(1) and 3.7â
(1)°, respectively. The mol-ecular structure is primarily stabilized by a strong intra-molecular C-Hâ¯O hydrogen bond, leading to the formation of a pseudo-seven-membered S(7) ring motif, and a short intra-molecular C-Hâ¯N contact forming an S(5) ring motif. In the crystal, mol-ecules are linked by pairs of C-Hâ¯S hydrogen bonds, forming inversion dimers. The dimers are linked by C-Hâ¯O and C-Hâ¯π inter-actions, forming chains propagating along [110].
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Ano de publicação:
2016
Tipo de documento:
Article
País de afiliação:
Índia