Synthesis of Tricyclic Benzazocines by Aza-Prins Reaction.

Katamura, Tomohiro; Shimizu, Tomoaki; Mutoh, Yuichiro; Saito, Shinichi

Katamura, Tomohiro; Shimizu, Tomoaki; Mutoh, Yuichiro; Saito, Shinichi.

Afiliação

Katamura T; Department of Chemistry, Faculty of Science, Tokyo University of Science , Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.
Shimizu T; Department of Chemistry, Faculty of Science, Tokyo University of Science , Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.
Mutoh Y; Department of Chemistry, Faculty of Science, Tokyo University of Science , Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.
Saito S; Department of Chemistry, Faculty of Science, Tokyo University of Science , Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.

Org Lett ; 19(1): 266-269, 2017 01 06.

Article em En | MEDLINE | ID: mdl-27983863

ABSTRACT

ABSTRACT

The aza-Prins reaction of 3-vinyltetrahydroquinolines with aldehydes proceeded smoothly in the presence of hydrogen halides, and the tricyclic benzazocine derivatives were isolated in good to high yields. The reaction would proceed through the formation and cyclization of the iminium ion intermediate.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Japão

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