Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly.
Inorg Chem
; 55(24): 12737-12751, 2016 Dec 19.
Article
em En
| MEDLINE
| ID: mdl-27989210
ABSTRACT
A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, which was characterized by single-crystal X-ray crystallography.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2016
Tipo de documento:
Article