Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives.
ChemistryOpen
; 5(6): 554-565, 2016 Dec.
Article
em En
| MEDLINE
| ID: mdl-28032025
ABSTRACT
The syntheses of tris(organostannyl)methanes HC(SnX n Ph(3-n))3 (1, n=0; 2, n=1, X=I; 3, n=1, X =F; 4, n=1, X=Cl; 5, n=1, X=OAc; 6, n=2, X=I; 7, n=2, X=Cl) and the organostannate complexes Et4N[HC(SnIPh2)3â
F]â
(8), Ph4P[HC(SnClPh2)3â
Cl]â
(9), and [Ph4P]2[HC(SnCl2Ph)3â
2 Cl]â
(10) are reported. The compounds were characterized by 1H, 13C, 19F, and 119Sn NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, and (with the exception of 3) single-crystal X-ray diffraction analysis. From the reaction between 2 and AgClO4 resulted the unprecedented hexanuclear organotin oxocluster [HC{Sn(ClO4)2Ph2}2Sn(OH)2Ph]2â
(11), the molecular structure of which was elucidated by using X-ray crystallography.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ChemistryOpen
Ano de publicação:
2016
Tipo de documento:
Article