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Copper-catalyzed TEMPO oxidative cleavage of 1,3-diketones and ß-keto esters for the synthesis of 1,2-diketones and α-keto esters.
Zhou, Peng-Jun; Li, Cheng-Kun; Zhou, Shao-Fang; Shoberu, Adedamola; Zou, Jian-Ping.
Afiliação
  • Zhou PJ; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai, Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn.
  • Li CK; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai, Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn.
  • Zhou SF; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai, Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn.
  • Shoberu A; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai, Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn.
  • Zou JP; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai, Street, Suzhou, Jiangsu 215123, China. jpzou@suda.edu.cn.
Org Biomol Chem ; 15(12): 2629-2637, 2017 Mar 22.
Article em En | MEDLINE | ID: mdl-28267182
ABSTRACT
A copper-catalyzed efficient and practical method has been developed for the synthesis of 1,2-diketones and α-keto esters. TEMPO was used as a radical initiator and scavenger, oxidizing the cleavage of α-methylene of 1,3-diketones and ß-keto esters to form 1,2-diketones and α-keto esters. This method provided a general way for the formation of 1,2-dicarbonyl compounds.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China