In situ characterization of cofacial Co(IV) centers in Co<sub>4</sub>O<sub>4</sub> cubane: Modeling the high-valent active site in oxygen-evolving catalysts.

Brodsky, Casey N; Hadt, Ryan G; Hayes, Dugan; Reinhart, Benjamin J; Li, Nancy; Chen, Lin X; Nocera, Daniel G

In situ characterization of cofacial Co(IV) centers in Co₄O₄ cubane: Modeling the high-valent active site in oxygen-evolving catalysts.

Brodsky, Casey N; Hadt, Ryan G; Hayes, Dugan; Reinhart, Benjamin J; Li, Nancy; Chen, Lin X; Nocera, Daniel G.

Afiliação

Brodsky CN; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138.
Hadt RG; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439.
Hayes D; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439.
Reinhart BJ; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439.
Li N; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138.
Chen LX; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439.
Nocera DG; Department of Chemistry, Northwestern University, Evanston, IL 60208.

Proc Natl Acad Sci U S A ; 114(15): 3855-3860, 2017 04 11.

Article em En | MEDLINE | ID: mdl-28348217

Palavras-chave

electrocatalysis; oxygen evolution reaction; renewable energy; solar-to-fuels; water splitting

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE País/Região como assunto: Cuba Idioma: En Revista: Proc Natl Acad Sci U S A Ano de publicação: 2017 Tipo de documento: Article

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