A carbon tetrachloride-free synthesis of N-phenyltrifluoroacetimidoyl chloride.
Carbohydr Res
; 450: 10-11, 2017 Oct 10.
Article
em En
| MEDLINE
| ID: mdl-28822278
ABSTRACT
N-Phenyltrifluoroacetimidoyl chloride (PTFAI-Cl) is a reagent widely used for the preparation of glycosyl N-phenyltrifluoroacetimidates. However, the most commonly applied method requires carbon tetrachloride, a hepatotoxic reagent that has been phased out under the Montreal Protocol. We report a new synthesis of N-phenyltrifluoroacetimidoyl chloride (PTFAI-Cl) using dichlorotriphenylphosphane and triethylamine.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos de Benzil
/
Cloretos
/
Hidrocarbonetos Halogenados
Idioma:
En
Revista:
Carbohydr Res
Ano de publicação:
2017
Tipo de documento:
Article
País de afiliação:
Austrália