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M8MgSc(PO4)7:xDy3+ (M = Ca/Sr) Single-Phase Full-Color Phosphor with High Thermal Emission Stability.
Long, Jiaqi; Chu, Fujuan; Wang, Yuzhen; Zhao, Chong; Dong, Wenfeng; Yuan, Xuanyi; Ma, Chaoyang; Wen, Zicheng; Ma, Ran; Du, Miaomiao; Cao, Yongge.
Afiliação
  • Long J; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Chu F; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Wang Y; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Zhao C; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Dong W; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Yuan X; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Ma C; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Wen Z; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Ma R; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Du M; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
  • Cao Y; Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China , Beijing 100872, China.
Inorg Chem ; 56(17): 10381-10386, 2017 Sep 05.
Article em En | MEDLINE | ID: mdl-28836779
ABSTRACT
Two series of phosphors of Ca8MgSc(PO4)7Dy3+ and Sr8MgSc(PO4)7Dy3+ single-phase white-emitting phosphors with high thermal emission stability are synthesized by the high-temperature solid-state reaction. The crystal structure, photoluminescence (PL), PL excitation (PLE), and thermal PL quenching spectra of Ca8MgSc(PO4)7xDy3+ and Sr8MgSc(PO4)7xDy3+ were investigated and compared in detail. Upon excitation at 387 nm, M8MgSc(PO4)7xDy3+ (M = Ca/Sr) showed white emission centered at 480, 571, 660, and 754 nm. The white-emitting Dy-phosphor Ca8MgSc(PO4)7Dy3+ (CMSPDy) had good terminal stability. The emission intensity of Ca8MgSc(PO4)7Dy3+ still remained 95.2% of that at room temperature at 160 °C, and remained 77.3% at 300 °C under 387 nm excitation.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Inorg Chem Ano de publicação: 2017 Tipo de documento: Article País de afiliação: China
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