M8MgSc(PO4)7:xDy3+ (M = Ca/Sr) Single-Phase Full-Color Phosphor with High Thermal Emission Stability.
Inorg Chem
; 56(17): 10381-10386, 2017 Sep 05.
Article
em En
| MEDLINE
| ID: mdl-28836779
ABSTRACT
Two series of phosphors of Ca8MgSc(PO4)7Dy3+ and Sr8MgSc(PO4)7Dy3+ single-phase white-emitting phosphors with high thermal emission stability are synthesized by the high-temperature solid-state reaction. The crystal structure, photoluminescence (PL), PL excitation (PLE), and thermal PL quenching spectra of Ca8MgSc(PO4)7xDy3+ and Sr8MgSc(PO4)7xDy3+ were investigated and compared in detail. Upon excitation at 387 nm, M8MgSc(PO4)7xDy3+ (M = Ca/Sr) showed white emission centered at 480, 571, 660, and 754 nm. The white-emitting Dy-phosphor Ca8MgSc(PO4)7Dy3+ (CMSPDy) had good terminal stability. The emission intensity of Ca8MgSc(PO4)7Dy3+ still remained 95.2% of that at room temperature at 160 °C, and remained 77.3% at 300 °C under 387 nm excitation.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2017
Tipo de documento:
Article
País de afiliação:
China