A comparison of nitrogen-doped sonoelectrochemical and chemical graphene nanosheets as hydrogen peroxide sensors.

ABSTRACT

Nitrogen-doped graphene nanosheet (N-SEGN) with pyrrolic nitrogen and 5-9 vacancy defects has been successfully prepared from a hydrothermal reaction of tetra-2-pyridinylpyrazine and sonoelectrochemistry-exfoliated graphene nanosheet, with point defects. Additionally, based on the same reaction using chemically reduced graphene oxide, nitrogen-doped chemically reduced graphene oxide (N-rGO) with graphitic nitrogen was prepared. The N-SEGN and N-rGO were used as a non-enzymatic H2O2 sensors. The sensitivity of the N-SEGN was 231.3 µA·mM-1·cm-2, much greater than 57.3 µA·mM-1·cm-2 of N-rGO. The N-SEGN showed their potential for being a H2O2 sensor.