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Microwave-Assisted Rapid Synthesis of Graphene-Supported Single Atomic Metals.
Fei, Huilong; Dong, Juncai; Wan, Chengzhang; Zhao, Zipeng; Xu, Xiang; Lin, Zhaoyang; Wang, Yiliu; Liu, Haotian; Zang, Ketao; Luo, Jun; Zhao, Shenglong; Hu, Wei; Yan, Wensheng; Shakir, Imran; Huang, Yu; Duan, Xiangfeng.
Afiliação
  • Fei H; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Dong J; Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China.
  • Wan C; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Zhao Z; Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Xu X; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Lin Z; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Wang Y; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Liu H; Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Zang K; Center for Electron Microscopy, Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials & Low-Carbon Technologies, School of Materials, Tianjin University of Technology, Tianjin, 300384, China.
  • Luo J; Center for Electron Microscopy, Tianjin Key Laboratory of Advanced Functional Porous Materials, Institute for New Energy Materials & Low-Carbon Technologies, School of Materials, Tianjin University of Technology, Tianjin, 300384, China.
  • Zhao S; School of Chemical Engineering, The University of New South Wales, Sydney, NSW, 2052, Australia.
  • Hu W; National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029, China.
  • Yan W; National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029, China.
  • Shakir I; Sustainable Energy Technologies Centre, College of Engineering, King Saud University, Riyadh, 11451, Saudi Arabia.
  • Huang Y; Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
  • Duan X; Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA, 90095, USA.
Adv Mater ; 30(35): e1802146, 2018 Aug.
Article em En | MEDLINE | ID: mdl-30016001
ABSTRACT
Graphene-supported single atomic metals (G-SAMs) have recently attracted considerable research interest for their intriguing catalytic, electronic, and magnetic properties. The development of effective synthetic methodologies toward G-SAMs with monodispersed metal atoms is vital for exploring their fundamental properties and potential applications. A convenient, rapid, and general strategy to synthesize a series of monodispersed atomic transition metals (for example, Co, Ni, Cu) embedded in nitrogen-doped graphene by two-second microwave (MW) heating the mixture of amine-functionalized graphene oxide and metal salts is reported here. The MW heating is able to simultaneously induce the reduction of graphene oxide, the doping of nitrogen, and the incorporation of metal atoms into the graphene lattices in one simple step. The rapid MW process minimizes metal diffusion and aggregation to ensure exclusive single metal atom dispersion in graphene lattices. Electrochemical studies demonstrate that graphene-supported Co atoms can function as highly active electrocatalysts toward the hydrogen evolution reaction. This MW-assisted method provides a rapid and efficient avenue to supported metal atoms for wide ranges of applications.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Adv Mater Assunto da revista: BIOFISICA / QUIMICA Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Adv Mater Assunto da revista: BIOFISICA / QUIMICA Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos