2-Azaallyl Anions, 2-Azaallyl Cations, 2-Azaallyl Radicals, and Azomethine Ylides.

Tang, Shaojian; Zhang, Xia; Sun, Jiayue; Niu, Dawen; Chruma, Jason J

Tang, Shaojian; Zhang, Xia; Sun, Jiayue; Niu, Dawen; Chruma, Jason J.

Afiliação

Tang S; Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of
Zhang X; Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of
Sun J; Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of
Niu D; Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of
Chruma JJ; Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of

Chem Rev ; 118(20): 10393-10457, 2018 10 24.

Article em En | MEDLINE | ID: mdl-30302999

ABSTRACT

ABSTRACT

This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in organic synthesis up through June 2018. Particular attention is paid to both foundational studies and recent advances over the past decade involving semistabilized and nonstabilized 2-azaallyl anions as key intermediates in various carbon-carbon and carbon-heteroatom bond-forming processes. Both transition-metal-catalyzed and transition-metal-free transformations are covered. Azomethine ylides, which have received significant attention elsewhere, are discussed briefly with the primary focus on critical comparisons with 2-azaallyl anions in regard to generation and use.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Rev Ano de publicação: 2018 Tipo de documento: Article